A flue gas can be cooled for carbon capture purposes with the use of a gas-to-gas exchanger, using air as the cooling media, downstream of a heat recovery process, and optionally upstream of a quenching process; the use of an amine chilling process to reduce the required flue gas cooling duties upstream of the CO.sub.2 absorber; the use of a gas-to-gas exchanger, using the absorber overhead as the cooling media, downstream of a heat recovery process, and optionally upstream of the quenching process; and/or the use of a quenching process in which heated water and condensate is cooled by an external cooling loop utilizing treated flue gas condensate in an evaporative cooling process.

An apparatus (10, 110, 210, 310) for the separation and recovery of CO.sub.2, from air, by a cyclic adsorption/desorption process using a loose particulate sorbent for gas adsorption. The apparatus has a plurality of adjacent, parallel, spaced-apart layers (24, 124, 224, 324), each having a stiff frame supporting a flexible, gas-permeable fabric enclosure for the sorbent. The gas inlet (14, 114, 214, 314) and outlet (18, 118, 216, 316) of the apparatus are on its axially opposite sides, and each layer (24, 124, 224, 324) extending axially within the apparatus. The recovered CO.sub.2 can be either supplied to an enclosed space, recycled to an enclosed space, from which the CO.sub.2 had been separated, or vented to the exterior of the latter enclosed space.

The present disclosure provides for collection and separation systems, collection and separation methods, isotope analsis systems, methods of processing samples to analyze .sup.15N, .sup.13C, and S.sup.34, and the like. In an aspect, the present disclosure provides for a system that includes a collection system in gaseous communication with a first device, wherein the collection system is configured to isolate two or more gases of a gaseous sample and configured to introduce each to a second device independently of one another.

A process for selective capture of CO.sub.2 from gaseous mixture comprising of: (a) spraying a bio-amine cluster; (b) capturing CO.sub.2 through bio-amine cluster; and (c) desorption of CO.sub.2 through solar assisted electro de-amination, wherein the bio-amine cluster is comprises of: an amine cluster comprising of a quaternary Isobutylamine (IB) with amine terminated Poly(L-lactide) as the chelating agent; a cluster stabilizing agent; a cluster micelle stabilizing agent; and a carbonic anhydrase (CA) functionalized matrix in 0.05-0.2 wt % of total wt % of bio-amine cluster and wherein the CA is obtained from a source selected from the group consisting of Bacillus thermoleovorans, Pseudomonas fragi, Bacillus stearothermophilus and Arthrobacter sp. and a process for production of bio-amine cluster.

This present invention describes methods and systems for integrating liquid-phase, electrochemical and chemical processes into power generation, petrochemical, metal, cement and other industrial process plants, in such a manner as to capture and recycle all input carbon into cost-competitive hydrogen, oxygen and hydrocarbons. These integrated systems will recover internally generated losses in chemical potential (AG Gibbs Free or Available Energy) as well as waste heat (ΔH—Enthalpy), and sometimes electricity, to assist in driving these electrochemical and chemical processes, which will increase the total useful output of the process plants, thereby increasing thermal, carbon and economic efficiency.

A solvent composition for carbon capture according to a preferred embodiment comprises at least two of the following: diethylaminoethanol (DEAE), hexamethylenediamine (HMDA), and polyethylenimine (PEI). Another embodiment includes a method of performing carbon capture using the carbon capture solvent compositions described herein. Another embodiment provides an apparatus for performing carbon capture using the carbon capture compositions described herein and/or the carbon capture methods described herein.

The present invention relates to a system, and the method of application thereof, for washing and decontamination comprising nebulizing means (8) of a mixture of at least one first gas and at least one first liquid, and pressurizing means (1) of said first gas, wherein said pressurizing means (1) are in fluid communication with a first pressure-regulating valve (3) and with a second pressure-regulating valve (4), the first pressure-regulating valve (3) being in fluid communication with a first pressurized tank (5) through first inlet means (31) of said first gas, the first pressurized tank (5) being configured to contain the first liquid, and comprising first outlet means (30) of said first liquid to the nebulizing means (8) through a first valve (6), at a first pressure that is greater than atmospheric pressure, and wherein the second pressure-regulating valve (4) is in fluid communication with said nebulizing means (8), and is configured to pressurize the gas at a second pressure that is greater than atmospheric pressure.

An efficient ammonia desulphurization and oxidation apparatus includes a desulphurization tower, where spray layers in multiple stages and a tower reactor are sequentially arranged in the desulphurization tower; a first gas-liquid distribution plate, a second gas-liquid distribution plate, and a third gas-liquid distribution plate are sequentially arranged in the tower reactor; an ammonia distribution zone is formed between the first and second gas-liquid distribution plates, and an ammonia water distributor is further arranged between the first gas-liquid distribution plate and the second gas-liquid distribution plate in the ammonia distribution zone; an absorption zone is formed between the second and third gas-liquid distribution plates; an oxidation zone is formed between the third gas-liquid distribution plate and a bottom of the tower; in the oxidation zone, oxidizing air distributors in multiple stages are arranged at a lower side of the third gas-liquid plate.

A carbon dioxide and exhaust gas capture device that is a device being unique in the world and being able to truly suppress carbon dioxide is provides and has a cold water tank set, a photosynthetic tank set, and a terrestrial plant tank set. The cold water tank set reduces temperature of exhaust gas and filters toxic gases and pollutant particles. The photosynthetic tank set and the terrestrial plant tank set further photosynthesize the exhaust gas with organisms that derive energy from photosynthesis and terrestrial plants to produce oxygen. Moreover, the carbon dioxide and exhaust gas capture device requires low cost, has high efficiency, produces zero pollution during the process, has a long service life, and has high added value.

Disclosed herein are methods of electrochemically enhanced amine-based CO.sub.2 capture and systems for performing the methods of amine-based CO.sub.2 capture. The present methods and systems advantageously may be carried out at ambient temperatures and allow for reusing the amine through multiple cycles.