The current disclosure provides systems and methods for multiple beds undergoing a feed step at the same time with the same feed flow rate and multiple beds undergoing a light reflux step at the same time with the same light reflux flow rate to process a gas stream in a multi-bed, multi-unit vacuum swing adsorption (VSA) process using reasonably sized beds.

Disclosed in certain embodiments are methods of removing water from a gas feed stream comprising hydrocarbons and water during an adsorption step of an adsorption cycle.

The present invention provides a system for the capture and purification CO.sub.2 and a purification unit for said system, wherein said purification unit comprises: a first filter having a first container and a first filler material; a second filter having a second container and a second filler material, downstream of said first filter; a third filter having a third container and a third filler material, downstream of said second filter, said third filter having, additionally, a heating element thermally coupled to said third filler material; and control means of said heating element; wherein said first filler material is silica; wherein said second filler material is zeolite; and wherein said third filler material is a metal-organic framework modified with activated carbon.

A method for separating a gas mixture flow, n which uses a temperature-change adsorption plant having a number of adsorption units which are operated in a first and a second operating mode. The first operating mode comprises guiding a gas mixture flow at least in part through an adsorption chamber of an adsorption unit and subjecting this flow to an adsorptive exchange with at least one adsorbent. The second operating mode comprises guiding a first heat transfer fluid flow at a first temperature through a heat-exchange arrangement of an adsorption unit. The first operating mode also comprises guiding a second heat transfer fluid flow at a second temperature through the heat-exchange arrangement of the respective adsorption unit. The adsorption units are operated in a third operating mode which comprises guiding a third heat transfer fluid flow at a third temperature through the heat-exchange arrangement of the respective adsorption unit.

A method for preparing hydrogen gas includes a decomposition step, a first adsorption step, a second adsorption step, a first regeneration step, a third heat-exchange step, and a second regeneration step.

An activated carbon device for adsorbing solvent from a flow of air is regenerated by feeding heated inert gas to the activated carbon and by applying a reduced pressure to the heated activated carbon.

Provided is a canister that makes it possible to reduce production costs. One aspect of the present disclosure is a canister. The canister includes an outer case including a charge port that takes in an evaporated fuel, a purge port that discharges the evaporated fuel, and an atmosphere port open to the atmosphere, an inner case arranged inside the outer case, the inner case having an inner space to which the atmosphere port is connected, a first adsorption chamber arranged in the inner space of the inner case, and a second adsorption chamber arranged between the first adsorption chamber and the atmosphere port in a flow path of the evaporated fuel in the inner space of the inner case. A cross-sectional area perpendicular to a gas flow direction in the second adsorption chamber and a cross-sectional area perpendicular to a gas flow direction in the first adsorption chamber are different.

A method for operating a temperature swing adsorption plant having three adsorption units which are operated in an adsorption phase, a feed phase, a regeneration phase, a flush phase, and a cooling phase, wherein in the adsorption phase a first gas mixture at a first temperature is guided over an adsorbent in the adsorption units with obtention of a second gas mixture and adsorption onto the adsorbent of components of the first gas mixture, in the regeneration phase the adsorption units are heated and the components adsorbed by the adsorbent during the adsorption mode are at least partially desorbed, and in the flush phase the components which were desorbed during the regeneration mode are at least partially flushed using a third gas mixture with obtention of a fourth gas mixture. In the cooling phase, the adsorption units are at least partially cooled to the first temperature.

The process of the present invention provides high recovery and low capital cost giving it an economic advantage over previously known purification processes. The present process has particular applicability to the purification of synthesis gases comprising at least hydrogen (H.sub.2), carbon monoxide (CO), methane (CH.sub.4), CO.sub.2, and H.sub.2O to obtain a gas stream including at least H.sub.2, CO, and CH.sub.4, that is substantially free of H.sub.2O and CO.sub.2. The process also has applicability to the purification of natural gases inclusive of at least CH.sub.4, N.sub.2, CO.sub.2, and H.sub.2O to produce a gas stream including at least CH.sub.4 and N.sub.2, but which is substantially free of H.sub.2O and CO.sub.2.

An integrated fuel combustion system with gas separation (adsorptive, absorptive, membrane or other suitable gas separation) separates a portion of carbon dioxide from a combustion gas mixture and provides for recycle of separated carbon dioxide to the intake of a fuel combustor for combustion. A process for carbon dioxide separation and recycle includes: admitting combustion gas to a gas separation system; sorbing a portion of carbon dioxide; recovering a flue gas stream depleted in carbon dioxide for release or use; desorbing the carbon dioxide from the gas separation system; admitting an oxidant stream into the gas separation system and forming a mixed oxidant stream; and recycling a portion of the mixed oxidant stream to an inlet of the fuel combustor.