Entrained metal hydride particle are removed from a flow of hydrogen from a Mg-based hydride storage unit using not only a particle filter but improvements for reducing or eliminating drastic changes in flow. In addition to or alternative to removal of entrained metal hydride particles, methane produced by reaction of hydrogen with steel in a metal hydride system preferably operated above 350 C. is removed downstream of the Mg-based hydride storage unit using an adsorption cartridge, preferably containing activated carbon.

The storing and destocking of hydrogen in a hydride tank (10) comprises purification performed in at least one trap (1, 1A, 1B) filtering the impurities contained in the hydrogen entering the tank to be stored and regeneration of said at least one trap, using the heat carried by the hydrogen exiting the tank after it has been destocked.

Entrained metal hydride particle are removed from a flow of hydrogen from a Mg-based hydride storage unit using not only a particle filter but improvements for reducing or eliminating drastic changes in flow. In addition to or alternative to removal of entrained metal hydride particles, methane produced by reaction of hydrogen with steel in a metal hydride system preferably operated above 350 C. is removed downstream of the Mg-based hydride storage unit using an adsorption cartridge, preferably containing activated carbon.

A carbon composite material, including a plurality of spaced graphene sheets, each respective sheet having opposed generally planar surfaces, and a plurality of functionalized carbonaceous particles. At least some functionalized carbonaceous particles are disposed between any two adjacent graphene sheets, and each respective at least some functionalized carbonaceous particle is attached to both respective any two adjacent graphene sheets. Each respective graphene sheet comprises at least one layer of graphene and at least portions of respective any two adjacent graphene sheets are oriented substantially parallel with one another.

Entrained metal hydride particle are removed from a flow of hydrogen from a Mg-based hydride storage unit using not only a particle filter but improvements for reducing or eliminating drastic changes in flow. In addition to or alternative to removal of entrained metal hydride particles, methane produced by reaction of hydrogen with steel in a metal hydride system preferably operated above 350 C. is removed downstream of the Mg-based hydride storage unit using an adsorption cartridge, preferably containing activated carbon.

Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent.

Embodiments provide a methane microporous carbon adsorbent including a thermally-treated CVD carbon having a shape in the form of a negative replica of a crystalline zeolite has a BET specific surface area, a micropore volume, a micropore to mesopore volume ratio, a stored methane value and a methane delivered value and a sequential carbon synthesis method for forming the methane microporous carbon adsorbent. Introducing an organic precursor gas for a chemical vapor deposition (CVD) period to a crystalline zeolite that is maintained at a CVD temperature forms the carbon-zeolite composite. Introducing a non-reactive gas for a thermal treatment period to the carbon-zeolite composite maintained at a thermal treatment temperature forms the thermally-treated carbon-zeolite composite. Introducing an aqueous strong mineral acid mixture to the thermally-treated carbon-zeolite composite forms the methane microporous carbon adsorbent. The crystalline zeolite includes tri-ethanolamine (TEA) and has a shape that is orthogonal with a mid-edge length in a range of 8 m to 20 m.

Disclosed is a metal-organic framework composite including a host metal-organic framework, and nano metal-organic frameworks embedded in the host metal-organic framework. The host metal-organic framework and the nana metal-organic frameworks include different metals and organic ligands. The metal-organic framework composite has a structure in which the nano metal-organic frameworks are embedded in the host metal-organic framework. Due to this structure, defects are formed at the interfaces between the host metal-organic framework and the nano metal-organic frameworks, enabling the application of the metal-organic framework composite to gas storages with greatly improved gas storage efficiency. The metal-organic framework composite can be used as a gas adsorbent with very high efficiency due to its very large specific surface area. Also disclosed are a method for producing the metal-organic framework composite and a gas storage using the metal-organic framework composite.

The storing and destocking of hydrogen in a hydride tank (10) comprises purification performed in at least one trap (1, 1A, 1B) filtering the impurities contained in the hydrogen entering the tank to be stored and regeneration of said at least one trap, using the heat carried by the hydrogen exiting the tank after it has been destocked.

A process for reducing coke formation during hydrocarbon upgrading reactions using a double-wall reactor comprising the steps of feeding a heated feed water to a shell-side volume of the double-wall reactor to produce a heat transfer stream, the double-wall reactor comprising an exterior wall and an interior wall, a reaction section volume, a heating element configured to heat the heat transfer stream, wherein heat is transferred from the heat transfer stream to the reaction section volume, feeding the hot water return exiting the shell-side volume through a filter; mixing the filtered water stream with a heated hydrocarbon feedstock; feeding the mixed stream to the reaction section volume in a configuration counter-current to the heat transfer stream; reacting the reaction flow stream at a reaction temperature, wherein the heat transferred to the reaction section volume is operable to maintain the reaction temperature above the critical temperature of water.