Durable, porous alumina-carbon nanotube membranes and methods for making them using spark plasma sintering. Methods for removing heavy metals such as cadmium from waste water using alumina-carbon nanotube membranes.

The present invention discloses a FeAl-based metal porous membrane and a preparation method thereof, which relate to the technical field of industrial gas-solid and liquid-solid separation and purification, and mainly address problems in the prior art, such as cracking-prone and peeling of a membrane layer of an existing FeAl-based metal porous membrane during its preparation and use. The preparation method of the present invention comprises the steps of: adding a FeAl-based metal powder and a metal fiber powder into an organic-additive-added water-based solvent, and mixing them into a slurry; casting the slurry, through a casting machine, to form a membrane green body on a metal substrate layer, and letting it dry; and placing the dried membrane green body in a sintering furnace, to remove organic substances and perform high-temperature sintering and predetermined-temperature reaction synthesis.

Disclosed are methods of manufacturing a zeolite membrane, comprising: providing at least one porous substrate; and coating the at least one porous substrate with a membrane. In some embodiments, the method further comprises hydrothermally treating the membrane with a first hydrothermal treatment step with tetrapropylammonium fluoride (TPAF) and a second hydrothermal treatment step with tetraethylammonium hydroxide (TEAOH). In some embodiments, coating the substrate with a membrane comprises surrounding at least a portion of the at least one porous substrate with a precursor gel, the gel comprising a gel phase and a plurality of CHA or MFI crystals; heating the at least one porous substrate and the precursor gel; washing the at least one porous substrate; drying the at least one porous substrate; and calcining the at least one porous substrate.

A preparation method of a high-moisture-permeability fluorine-containing super-oleophobic microporous membrane is provided having the following steps: (1) preparing a white opaque mixture of fluorine-containing polymers: adding the materials in sequence according to a weight ratio of A50%?90%:B3%?25%:C0%?35%:D0 %?3%, and stirring and mixing uniformly in a non-shear manner; A is a blend of a high molecular weight polytetrafluoroethylene dispersion resin and a fluorine-containing ion exchange resin; B is a fluorine-containing alkyl acrylate monomer, or a fluorine-containing alkyl methacrylate monomer, or a mixture thereof; C is a polyurethane acrylate prepolymer, or a fluorine-free alkyl acrylate monomer, or a mixture thereof; D is a high temperature free radical initiator; (2) pouring the white opaque mixture into the blank pressing column barrel, and pressing a blank; (3) calendering into strips; (4) stretching and thermally shaping to form a membrane.

The present disclosure relates to a polyether block polyamide/polydimethylsiloxane (PDMS) composite membrane for gas separation, and a preparation method and use thereof, and belongs to the technical field of membrane separation. In the present disclosure, an amphoteric copolymer PDMS-polyethylene oxide (PEO) (PDMS-b-PEO) is introduced into an intermediate layer to adjust the interfacial binding performance, thereby promoting preparation of an ultra-thin polyether block polyamide composite membrane. Studies have shown that the surface enrichment of PEO segments not only inhibits a dense SiO.sub.x layer formed due to a plasma treatment of a PDMS intermediate layer, but also provides additional hydrophilic sites and interfacial compatibility for the subsequent selective layer. The use of PDMS-b-PEO in an intermediate layer allows the successful preparation of a selective layer with a thickness of about 50 nm.

A high-flux composite nanofiltration (NF) membrane with an electrical double layer (EDL) and a preparation method thereof are provided. The high-flux composite NF membrane includes: a charged support membrane and a charged separation layer, where a charge carried by the support membrane or the separation layer is a positive charge, a negative charge, or an amphiprotic charge. The high-flux composite NF membrane with an EDL solves the technical problem that the composite NF membrane in the prior art has an unsatisfactory retention rate and a limited application range due to a small charge quantity.

The present disclosure relates to the field of materials for uranium extraction from seawater (UES), and in particular, to a photothermal photocatalytic membrane for seawater desalination and uranium extraction and a preparation method therefor. The present disclosure provides a photothermal photocatalytic membrane for seawater desalination and uranium extraction and a preparation method therefor. The preparation method includes: fixing a treated carbon cloth to a glass plate, pouring a casting solution 1 onto the carbon cloth to form a first layer of film, forming a second layer of film using a casting solution 2, and putting the second layer of film into a first coagulation bath and a second coagulation bath in sequence to form the photothermal photocatalytic membrane. The photothermal photocatalytic membrane is supported by the carbon cloth, and a surface of the photothermal photocatalytic membrane is of a micro-nano structure.

The purpose is to produce a molded filter body using graphene having water passage holes with a desired size by an easy process. A method for producing a molded filter body having a layer of graphene 2 as a filter medium, includes the steps of: forming a layer of a support 5 on a surface of graphite 1; forming support water passage holes in the layer of the support 5; peeling the layer of the support 5 from the graphite 1 in a state of attaching the layer of graphene 2 on the surface of the graphite 1 to the layer of the support 5; and holding the layer of graphene 2 by heating at a low temperature for a predetermined time in the air containing oxygen at 160 to 250 C. and forming graphene water passage holes.

The present invention is directed to a method for treating a surface of a filled microporous membrane. The microporous membrane includes a polyolefinic matrix, inorganic filler distributed throughout the matrix, and a network of interconnecting pores throughout the membrane. The method includes sequentially (1) contacting the membrane with a first treatment composition comprising an epoxy-silane which is in intimate contact with the inorganic filler; (2) subjecting the membrane of (1) to conditions sufficient to effect a first reaction between the inorganic filler and the silane groups of the epoxy-silane compound; (3) contacting the membrane of (2) with a second treatment composition comprising polyalkylene polyamine, an amine functional polysaccharide and/or an amino silane; and (4) subjecting the membrane of (3) to conditions sufficient to effect a second reaction. Treated membranes also are provided.

The invention relates to a multilayer metallic or ceramic membrane device, comprising a macroporous carrier layer including pores having a pore diameter of more than 50 nm, and at least one mesoporous intermediate layer disposed thereon, including pores having a pore diameter of 2 nm to 50 nm. The membrane device according to the invention furthermore comprises at least one microporous cover layer disposed on the mesoporous intermediate layer, including pores having an average pore diameter of 0.3 nm to 1.5 nm, comprising graphite oxide or few-layer graphene oxide or graphite or few-layer graphene. In an advantageous embodiment, the cover layer comprises between 5 and 1000 layers of graphene oxide. In an advantageous embodiment, the cover layer can comprise between 5 and 1000 layers of partially reduced graphene oxide or graphene as a result of the at least partial reduction of the graphene oxide. The multilayer, chemically and mechanically stable and temperature-resistant membrane device according to the invention, comprising the functional cover layer thereof including microporous graphene oxide or graphene, is advantageously suitable for use in water separation or purification, or for gas separation.