The invention relates to a method for converting a gas into methane (CH4) which includes: a step of activating a catalytic material including praseodymium oxide (Pr6O11) associated with nickel oxide (NiO) and alumina (Al2O3), the respective proportions of which are, relative to the total mass of these three compounds:

Pr6O11: 1 wt % to 20 wt %,

NiO: 1 wt % to 20 wt %, and

A12O3: 60 to 98 wt %; and a step of passing a gas including at least one carbon monoxide (CO) over the activated catalytic material.

This invention relates to a polymerization process for forming polymer comprising: contacting (typically in a solution or slurry phase), a monomer and a catalyst system in a reaction zone comprising at least one spiral heat exchanger and recovering polymer, wherein the monomer, the catalyst system and the polymer flow through the at least one spiral heat exchanger in a cross-flow direction relative to spirals of the at least one spiral heat exchanger.

A fluidized gas reactor includes a system for preventing a fluidizing gas comprising a reactant from premature reaction. The fluidized gas reactor includes a reaction chamber including a particle bed; a gas distribution plate having a plurality of openings therethrough, wherein each opening opens into the reaction chamber; and a plurality of vertical fluidizing gas inlet tubes, each of the fluidizing gas inlet tubes being in fluid communication with one of the openings in the gas distribution plate. Each fluidizing gas inlet tube is configured to receive a fluidizing gas and transport the fluidizing gas to the reaction chamber. A fluidizing gas source provides a stream of the fluidizing gas to the fluidizing gas inlet tubes. A coolant system prevents the fluidizing gas from undergoing reaction before entering the reaction chamber. The coolant system has a fluid inlet; a coolant flow path in fluid communication with the fluid inlet, the coolant flow path being configured to cool each fluidizing gas inlet tube; and a fluid outlet in fluid communication with the coolant flow path. Each fluidizing gas inlet tube may include a particle outlet and a valve system, where the valve system allows the fluidizing gas flow to the fluidizing gas inlet tubes to be stopped; and allows recovery of particles from the particle bed while the fluidizing gas flow is stopped.

Fluidized-bed reactor for the gas-phase polymerization of olefins including a gas distribution grid installed in a lower part of the fluidized-bed reactor and a gas recycle line, which is equipped with a compressor and a heat exchanger and which is connected at the upper end with the top of the fluidized-bed reactor, wherein the gas recycle line splits at the lower end in at least two horizontal branches which are connected tangentially with the fluidized-bed reactor below the gas distribution grid and a process for preparing an olefin polymer carried out in the fluidized-bed reactor.

A modified bed particles, related methods and applications in processes involving microwave-assisted catalytic reactions. The bed particles modified to be used as a microwave receptor that is capable to simultaneously sustain heat generation mechanisms under microwave irradiations and physically act as catalyst support. The bed particle comprises a dielectric coating deposited on an external surface of a core, the bed particle being sized for use in a fixed bed reactor or a fluidized bed reactor. The bed particles may further comprise a catalytically active material supported on a surface of the dielectric coating. Irradiating the gas-solid reactor with microwaves enables heating the dielectric coating of the solid bed particles, the dielectric coating locally transferring thermal energy to the surrounding gaseous reactants which are thereby selectively converted into the primary products.

A system for promoting endothermic conversions includes a first and second portion, a first and second supply, a first outlet, and a heat exchanger. The first portion defines a first inner volume containing an oxygen transfer agent. The first supply contains a reducing agent and is fluidly connected to the first inner volume. The first outlet conveys one or more of carbon dioxide, water, and an unsaturated hydrocarbon from the first inner volume. The second portion and the heat exchanger positioned within the second portion define a second inner volume containing reduced oxygen transfer agent. The second supply contains an oxidizing agent fluidly connected to the second inner volume. The heat exchanger also defines a third inner volume segregated from the second inner volume, and the heat exchanger is configured to transfer heat resulting from the oxidation of the reduced oxygen transfer agent to the third inner volume.

A system for the production of a polycrystalline silicon product is disclosed. The system includes a reaction chamber, a susceptor, an induction unit, and a plurality of energy sources. The reaction chamber has a reactor wall, and the susceptor encircles the reactor wall. The induction heater surrounds the susceptor, and has multiple induction coils for producing heat in the susceptor. The coils are grouped into a plurality of zones. The plurality of energy sources supply electric current to the coils. Each energy source is connected with the coils of at least one zone.

A turbulent fluidized-bed reactor, device and method for preparing propylene and C4 hydrocarbons from oxygen-containing compounds. The device includes the turbulent fluidized-bed reactor and a fluidized-bed regenerator for regenerating a catalyst. The method includes: a) feeding a raw material containing the oxygen-containing compounds from n reactor feed distributors to a reaction zone of the turbulent fluidized-bed reactor, and contacting the raw material with a catalyst, to generate a stream containing target product and a spent catalyst containing carbon; b) sending the stream discharged into a product separation system, obtaining propylene, C4 hydrocarbons, light fractions and the like after separation, returning 70 wt. % or more of the light fractions to the reaction zone of the turbulent fluidized-bed reactor from the reactor feed distributor, and reacting ethylene and the oxygen-containing compounds to perform an alkylation reaction in presence of the catalyst, to produce products of propylene and the like.

The present invention provides a method of cooling a regenerated catalyst and a device thereof, which employs low-line-speed operation, wherein a range of the superficial gas velocity is 0.005-0.7 m/s, wherein at least one fluidization wind distributor is provided, wherein the main fluidization wind enters the dense bed layer of the catalyst cooler from the distributor, and the heat removal load of the catalyst cooler and/or the temperature of the cold catalyst is controlled by adjusting the fluidization wind quantity. The method and a device thereof of the present invention has an extensive application range, and can be extensively used for various fluid catalytic cracking processes, including heavy oil catalytic cracking, wax oil catalytic cracking, light hydrocarbon catalytic conversion and the like, or used for other gas-solid fluidization reaction charring processes, including residual oil pretreating, methanol to olefin, methanol to aromatics, fluid coking, flexicoking and the like.

A fast fluidized-bed reactor, device and method for preparing propylene and C4 hydrocarbons from oxygen-containing compounds. The device includes the fast fluidized-bed reactor and a fluidized-bed regenerator for regenerating a catalyst. The method includes: a) feeding a raw material containing the oxygen-containing compounds from reactor feed distributors to a dense phase zone of the fast fluidized-bed reactor, and contacting the raw material with a catalyst, to generate a stream containing target product and a spent catalyst containing carbon; b) sending the stream into a product separation system, obtaining propylene, C4 hydrocarbons, light fractions and the like after separation, returning 70 wt. % or more of the light fractions to the dense phase zone of the fast fluidized-bed reactor from the reactor feed distributor.