A porous activated asphaltene material is described with a method of making and a method of using for the adsorption of a contaminant from a solution. The porous activated asphaltene material may be made by functionalizing solid asphaltene with nitric acid, and then treating the product with a metal hydroxide. The resulting porous activated asphaltene material exhibits a high porosity, and may be cleaned and reused for adsorbing contaminants.

A system for the treatment of a liquid plastic-derived oil having a pretreating section that includes a pretreating system having one or more reactors that may receive the liquid plastic-derived oil having one or more contaminants and a first contamination level. The one or more reactors includes a sorbent material having a faujasite (FAU) crystal framework type zeolitic molecular sieve and that may remove a first portion of the one or more contaminants from the liquid plastic-derived oil and generate a treated liquid plastic-derived oil having a second contamination level that is less than the first contamination level. The liquid plastic-derived oil is derived from a solid plastic waste (SPW), and the first portion of the one or more contaminants includes a halogen.

A system for the treatment of a liquid plastic-derived oil having a pretreating section that includes a pretreating system having one or more reactors that may receive the liquid plastic-derived oil having one or more contaminants and a first contamination level. The one or more reactors includes a sorbent material having a faujasite (FAU) crystal framework type zeolitic molecular sieve and that may remove a first portion of the one or more contaminants from the liquid plastic-derived oil and generate a treated liquid plastic-derived oil having a second contamination level that is less than the first contamination level. The liquid plastic-derived oil is derived from a solid plastic waste (SPW), and the first portion of the one or more contaminants includes a halogen.

An ink for three dimensional printing a ceramic material includes metal oxide nanoparticles and a polymer resin, where a concentration of the metal oxide nanoparticles is at least about 50 wt % of a total mass of the ink. A method of forming a porous ceramic material includes obtaining an ink, where the ink comprises a mixture of metal oxide nanoparticles and a polymer, forming a body from the ink, curing the formed body, heating the formed body for removing the polymer and for forming a porous ceramic material from the metal oxide nanoparticles. The forming the body includes an additive manufacturing process with the ink.

A method of treating a metal carbonate salt includes hydrolyzing a metal halide salt to form a hydrohalic acid and a hydroxide salt of the metal in the metal halide salt. The metal includes an alkaline earth metal or an alkali metal. The method includes reacting the hydrohalic acid with the metal carbonate salt, wherein the metal carbonate salt is a carbonate salt of the alkaline earth metal or alkali metal, to form CO.sub.2 and the metal halide salt. At least some of the metal halide salt formed from the reacting of the hydrohalic acid with the metal carbonate salt is recycled as at least some of the metal halide salt in the hydrolyzing of the metal halide salt to form the hydrohalic acid and the hydroxide salt.

The present disclosure provides a desulfurization and sulfur recovery method for sulfur dioxide flue gas, and belongs to the technical field of non-ferrous metal smelting. The method includes the following steps: desulfurizing the sulfur dioxide flue gas by taking slagging flux limestone or quicklime for smelting or converting process as a desulfurizer, and adsorbing SO.sub.2 in the gas to obtain gypsum residue, calcium sulfite, and the desulfurized flue gas, where SO.sub.2 in the sulfur dioxide flue gas before desulfurization is less than 1 vol %; and recycling the gypsum residue and the calcium sulfite to the smelting or converting furnace for slagging, resolving the SO.sub.2 into smelting off-gas, producing sulfuric acid in acid plant.

Zein based sorbents and methods of making zein based sorbents are disclosed. A method of making the sorbents involves the use of zein nanoparticles, the creation of an emulsion, use of a cross-linking agent, the creation of a polymeric zein solution, and hydrophobization. Certain versions include iron oxide nanoparticles and the use of magnetic properties. The zein based sorbents may have cross linking and hydrophobic functionalization. Methods of cleaning up bodies of water are also disclosed using the zein based sorbents including cyclical use of the sorbent and burning of the sorbent.

The present disclosure relates to systems and methods of making ammonia using stable ammonia absorbents. The system and method for producing ammonia, comprises a reactor comprising a catalyst that converts at least a portion of nitrogen feed gas and at least a portion of hydrogen feed gas to ammonia (NH3) forming a reaction mixture comprising the ammonia, unreacted nitrogen, and unreacted hydrogen. An absorber configured to selectively absorb ammonia from the reaction mixture at a temperature of about 180 deg. C. to 330 deg. C. and a pressure of about 1-20 bar, the absorber comprising a solid absorbent. Preferably the solid absorbent is at least one metal halide and a solid support. The unabsorbed ammonium, the unreacted nitrogen, and unreacted hydrogen gas are recycled to the reactor.

A first process and sorbent for removing ammonia from a gaseous environment, the sorbent comprised of graphene oxide having supported thereon at least one compound selected from metal salts, metal oxides and acids, each of which is capable of adsorbing ammonia. A second process and sorbent system for removing ammonia and a volatile organic compound from a gaseous environment; the sorbent system comprised of two graphene-based materials: (a) the aforementioned graphene oxide, and (b) a nitrogen and oxygen-functionalized graphene. The sorbents are regenerable under a pressure gradient with little or no application of heat. The processes are operable through multiple adsorption-desorption cycles and are applicable to purifying and revitalizing air contaminated with ammonia and organic compounds as may be found in spacesuits, aerospace cabins, underwater vehicles, and other confined-entry environments.

Disclosed are systems and methods of rapidly cooling thermal loads by providing a burst mode cooling system for rapid cooling. The burst mode cooling system may include a complex compound sorber configured to rapidly absorb ammonia. The system may be used to provide pulses of cooling to directed energy systems, such as lasers and other systems that generate bursts of heat in operation.