B01J20/04

Method & Apparatus for Regenerating Sorbent from Carbon Dioxide Absorption
20220379285 · 2022-12-01 ·

A method for the regeneration of effluent from an absorber capturing emissions of carbon dioxide (CO2) from industrial sources. Reducing CO2 emissions from all sources is a key objective of most nations, and every industrial source of CO2 emissions has received extensive scrutiny.

The method involves designing and installing on a source a proprietary thermal regeneration system for a sorbent used in the CO2 capture equipment system, which recirculates the sorbent liquid through an absorption column (absorber). Because sorbents used in these systems are expensive, it would be useful if the spent sorbent following absorption of CO2 is regenerated for re-use in the absorber. The present invention's regeneration method uses thermal swing (changes in temperature of the spent sorbent), and describes the integration of a waste heat recovery process into the thermal swing method. In particular, the method uses a heat transfer agent in a sealed loop circulating the heat transfer agent through a hot industrial source producing the CO2 stream.

Using porous activated asphaltenes as effective adsorbents for the removal of heavy metals in water

A porous activated asphaltene material is described with a method of making and a method of using for the adsorption of a contaminant from a solution. The porous activated asphaltene material may be made by functionalizing solid asphaltene with nitric acid, and then treating the product with a metal hydroxide. The resulting porous activated asphaltene material exhibits a high porosity, and may be cleaned and reused for adsorbing contaminants.

Carbon dioxide capture system

The present system reduces the cost of carbon capture by reducing the over-temperature needed to strip CO.sub.2 from a liquid or fluid solution. The system includes structures that enhance the rate of CO.sub.2 bubble nucleation.

Alumina-based adsorbent containing sodium and doped with an alkali element for capturing acidic molecules

The present invention relates to an adsorbent comprising an alumina support and at least one alkali element, said adsorbent being obtained by introducing at least one alkali element, identical to or different from sodium, onto an alumina support the sodium content of which, expressed as Na.sub.2O equivalent, before the introduction of the alkali element or elements, is comprised between 1000 and 5000 ppm by weight with respect to the total weight of the support. The invention also relates to processes for the preparation of said adsorbent and use thereof in a process for the elimination of acidic molecules such as COS and/or CO.sub.2.

Managing volatiles in nuclear waste vitrification
11508490 · 2022-11-22 ·

Dangerous, toxic, and/or radioactive volatiles are produced from nuclear fission, nuclear decay, and/or as a byproduct from vitrification of radioactive wastes. Such volatiles are treated during and after vitrification of the radioactive waste, to be converted into fixed-chemicals, that are retained in, on, and/or proximate to a cold-cap located vertically above vitrified melt. The cold-cap may have one or more volatile fixing additives (VFAs) for retaining the fixed-chemicals. The VFAs are located in and/or the cold-cap. The vitrification may occur within at least one human-made cavern. The human-made cavern may be located within a deep geologic rock formation. The deep geologic rock formation may be located at least 2,000 feet below a terrestrial surface of the Earth. The human-made cavern may be formed by first drilling a wellbore from the terrestrial surface to the deep geologic rock formation and then underreaming the wellbore into the deep geologic rock formation.

METHOD FOR FORMING A POROUS ACTIVITED ASPHALTENE MATERIAL

A porous activated asphaltene material is described with a method of making and a method of using for the adsorption of a contaminant from a solution. The porous activated asphaltene material may be made by functionalizing solid asphaltene with nitric acid, and then treating the product with a metal hydroxide. The resulting porous activated asphaltene material exhibits a high porosity, and may be cleaned and reused for adsorbing contaminants.

DAIRY PURIFICATION MIXTURE

A method of removing one or more antibiotics from a dairy product, the method involve passing the dairy product comprising an antibiotic in a first amount through a bulk comprising, relative to a total bulk weight, at least 75 wt. % of titanium oxide nanostructures, to provide the dairy product comprising the antibiotic in a second, lesser amount, wherein the nanostructures have lengths at least two-fold in excess of their width and height. Bulk materials useful in this or related methods or applications may have loosely tangled, noodle-like morphologies on sub-100 nm scale, and need not employ graphene and/or polymeric support networks in columns, generally having only titanium oxides without silicon or iron oxides.

Process for producing a calcium phosphate reactant, reactant obtained and use thereof in the purification of liquid effluents

A process for producing a calcium phosphate reactant, according to which: in a first step, use is made of a source of calcium and a source of phosphate ions in water, in a molar ratio that is adjusted so as to obtain a Ca/P molar ratio of between 0.5 and 1.6, and the source of calcium is reacted with the phosphate ions at a pH of between 2 and 8, in order to obtain a suspension (A) of calcium phosphate, and in a second step, added to the suspension (A) are an alkaline compound comprising hydroxide ions in order to set a pH of more than 8 and an additional source of calcium in order to obtain a suspension (B) of calcium phosphate reactant having a Ca/P molar ratio of more than 1.6. A calcium phosphate reactant obtainable by such a process.

Composition containing urea for use in brine formation

A composition for use in brine formation comprising a deliquescent desiccant, urea, and an optional component selected from the group consisting of starch, citric acid, clay, glucose, and a combination thereof. Methods of making and using the composition are provided. The composition may be pressed into tablet form. The composition may be used in a dehumidifying device.

COMPOSITION CONTAINING UREA FOR USE IN BRINE FORMATION

A composition for use in brine formation having a deliquescent desiccant, urea, and an optional component selected from the group consisting of starch, citric acid, clay, glucose, and a combination thereof. Methods of making and using the composition are provided. The composition may be pressed into tablet form. The composition may be used in a dehumidifying device.