This invention is directed to amorphous and crystalline titanosilicate materials that have an unexpected selectivity for cesium and strontium, especially in the presence of high levels of competing ions. The titanosilicates of this invention show very high, unexpected selectivity in the presence of such competing cations such as sodium, calcium, magnesium and potassium, such as present in seawater.

The invention relates to alkenyl(perfluoroalkyl)phosphinic acids, to the preparation and intermediates thereof, to the use thereof as monomers for the preparation of oligomers and/or polymers, to the corresponding oligomers/polymers, to the corresponding support materials comprising the oligomers/polymers, and to the use thereof as ion exchangers, as catalysts or extraction medium and corresponding salts thereof.

An object of the present invention is to provide a porous silica powder suitable for, for example, a gas chromatography support, and the porous silica powder has an average pore diameter of 0.5 to 10 μm as determined by a mercury intrusion method, a volume of pores having a 100 nm or smaller pore diameter of 0.2 cm.sup.3/g or less as determined by a nitrogen gas adsorption method, a specific surface area of 0.5 to 100 m.sup.2/g as determined by a nitrogen gas adsorption method, and a particle size distribution of 10 to 1000 μm.

An adsorbent for halogenated anaesthetics includes: an inorganic material; and an organic material providing a framework for the inorganic material. The inorganic material may be chromium and the organic material may be terephthalic acid. The adsorbent may be formed or configured such that the adsorbent includes coordinatively unsaturated sites or such that the inorganic material may form octahedral structures. The adsorbent is formed or configured to be substantially regenerated at approximately room temperature and to provide selectivity for sevofluorane in water vapor of approximately 1.0. A method of producing an adsorbent includes: selecting an appropriate chemical containing an inorganic material; selecting an organic material to provide a framework for the inorganic material; dissolving the base chemical in water; mixing the organic material with the dissolved base chemical; heating the mixture; filtering the mixture to remove excess organic material; and drying the filtrate.

An adsorbent for halogenated anaesthetics includes: an inorganic material; and an organic material providing a framework for the inorganic material. The inorganic material may be chromium and the organic material may be terephthalic acid. The adsorbent may be formed or configured such that the adsorbent includes coordinatively unsaturated sites or such that the inorganic material may form octahedral structures. The adsorbent is formed or configured to be substantially regenerated at approximately room temperature and to provide selectivity for sevofluorane in water vapor of approximately 1.0. A method of producing an adsorbent includes: selecting an appropriate chemical containing an inorganic material; selecting an organic material to provide a framework for the inorganic material; dissolving the base chemical in water; mixing the organic material with the dissolved base chemical; heating the mixture; filtering the mixture to remove excess organic material; and drying the filtrate.

The present invention is related to a process for manufacturing a sorbent suitable for a use in a circulating dry scrubber device comprising the steps of: providing quicklime and water in an hydrator; slaking said quicklime via a non-wet route in the hydrator; collecting a lime based sorbent at an exit of the hydrator. The process is characterized in that it comprises a further step of adding at least a first additive comprising: a compound comprising silicon, and/or, a compound comprising aluminum, and/or a compound comprising silicon and aluminum before or during said slaking step, at a molar ratio between silicon or aluminum or a combination thereof and the calcium provided to said hydrator equal to or below 0.2 and equal to or above 0.02. In some other aspects, the present invention is related to a sorbent, a premix, and a flue gas treatment process.

The present invention is related to a process for manufacturing a sorbent suitable for a use in a circulating dry scrubber device comprising the steps of: providing quicklime and water in an hydrator; slaking said quicklime via a non-wet route in the hydrator; collecting a lime based sorbent at an exit of the hydrator. The process is characterized in that it comprises a further step of adding at least a first additive comprising: a compound comprising silicon, and/or, a compound comprising aluminum, and/or a compound comprising silicon and aluminum before or during said slaking step, at a molar ratio between silicon or aluminum or a combination thereof and the calcium provided to said hydrator equal to or below 0.2 and equal to or above 0.02. In some other aspects, the present invention is related to a sorbent, a premix, and a flue gas treatment process.

Provided are a carrier for a dry adsorbent for carbon dioxide, including spherical silica whose surface is engraved in the form of nanowires, and a method for preparing the same. Although the carrier for a dry adsorbent for carbon dioxide including spherical silica that has nanowires on the surface thereof has a very non-uniform shape, it serves better as a host structure adsorbing carbon dioxide as compared to the conventional carrier for a carbon dioxide adsorbent, and thus may be used for a host-guest adsorbent applicable to a fluidized bed process. In addition, the method for preparing a carrier for a carbon dioxide adsorbent provides nanowire-coated silicon spheres having an increased surface roughness and an increased surface area, thereby providing increased carbon dioxide capturing efficiency. Further, since the method for forming nanowires is simple, it is easy to carry out mass production without any separate process, thereby providing excellent cost efficiency.

Disclosed is a composite of a particulate and polymer, the composite characterized by less than enough polymer to fully occupy the available excluded volume of the particulate of the composite. The resulting composite is characterized by the particulate partially covered by the polymer leaving a substantial surface area uncovered.

A material for moisture removal and/or water harvesting from air may include a hydrophilic material containing micropores and a low water activity material confined within the micropores of the hydrophilic material. Apparatuses containing such materials and methods for moisture removal and/or water harvesting from air by using such materials are also described.