B01J20/3021

METHOD FOR OBTAINING SUPERABSORBENT POLYMERS VIA ALKALINE HYDROLYSIS WITH PRESSURIZED WATER VAPOUR, USING POLYACRYLONITRILE AND ACRYLIC FIBRES AND FABRICS
20230108608 · 2023-04-06 ·

A method for producing superabsorbent polymers from polyacrylonitrile (PAN) virgin or recycled from acrylic fibre manufacturing waste and discarded fabrics subjecting the PAN to alkaline hydrolysis with pressurized water vapour of up to 5 kgf/cm.sup.2 and a PAN:OH.sup.− molar ratio of 1:0.5 to 0.95, to obtain a cross-linked poly(acrylic acid-co-acrylamide) salt without using mechanical agitation, graphitizing agents with starch or cross-linking agents, and without precipitating the superabsorbent polymer obtained from the reaction medium with solvents or through pH adjustment with acids, the polymer obtained with recycled PAN leaves the autoclave already having a moisture content of 20% to 35% and a swelling capacity of >150 g H.sub.2O/g.

METHOD FOR PREPARING SUPER ABSORBENT POLYMER

The present disclosure relates to a method for preparing a super absorbent polymer. More specifically, it relates to a method for preparing a super absorbent polymer capable of preparing a super absorbent polymer in which the residual monomer content and the extractable content are simultaneously reduced by adding a reducing agent capable of a redox reaction with a thermal polymerization initiator before drying the hydrogel polymer.

Absorbent and method of making and use of the same
11648532 · 2023-05-16 ·

An absorbent compound and method of making the same, where the absorbent compound includes an amine oxide that comprises about 30% to about 55% of the absorbent compound and a polymer that comprises about 30% to about 55% of the absorbent compound.

SPECIAL PIG MANURE CHARCOAL MODIFIED BY AMINO GRAFTING, PREPARATION METHOD THEREOF, AND ITS APPLICATION IN THE REUSE OF NITROGEN FROM FARMLAND DRAINAGE

A preparation method of charcoal-based fertilizer is provided. Particularly, a special pig manure charcoal modified by amino grafting, a preparation method thereof, and its application in the reuse of nitrogen from farmland drainage are provided. The preparation method includes the following steps: 1) drying raw pig manure to a moisture content of 80%-85% and carrying out pickling, drying, and crushing successively to obtain a dried pig manure powder; 2) conducting liquid nitrogen pretreatment and high-temperature charcoalization to obtain an expanded pig manure charcoal; 3) performing carboxylation treatment to obtain a carboxylated pig manure charcoal; 4) amino grafting: adding an ammonia liquor to the carboxylated pig manure charcoal obtained in step 3), stirring for 20-24 h in an oil bath at 200-240° C.; washing and filtering; and drying and grinding to obtain the special pig manure charcoal modified by amino grafting.

HYDROCARBON ADSORBENT AND METHOD FOR ADSORBING HYDROCARBONS
20230148413 · 2023-05-11 · ·

A hydrocarbon adsorbent having a high hydrocarbon desorption start temperature and a method for adsorbing hydrocarbons that uses the hydrocarbon adsorbent are provided. The hydrocarbon adsorbent includes an alkali metal and a zeolite having a ring structure that includes at least 10 members is used. In the hydrocarbon adsorbent, a content of the alkali metal is 1 to 40 mass % based on a total mass of the hydrocarbon adsorbent, a content of the zeolite having a ring structure that includes at least 10 members is 99 to 60 mass % based on the total mass of the hydrocarbon adsorbent, and at least a portion of the alkali metal is in a state of being ion-exchangeable.

Method for sulfonating and oxidizing sawdust to form a sorbent

A method for producing a modified sawdust sorbent. The method involves sulfonating sawdust with sulfuric acid and oxidizing the sulfonated sawdust with hydrogen peroxide. The method yields a modified sawdust sorbent containing sulfonated and oxidized cellulose. The modified sawdust sorbent has a higher surface area, higher organic dye adsorption capacity, and more rapid organic dye adsorption rate than unmodified sawdust. A method of using the modified sawdust sorbent for organic dye removal from water is included.

Method for preparing biochar from phosphoric acid-modified <i>Enteromorpha prolifera</i>, and use of biochar in removal of cadmium

The disclosure discloses a method for preparing biochar from Enteromorpha prolifera and use of the biochar. The method includes: subjecting Enteromorpha prolifera to lyophilization, then impregnating lyophilized Enteromorpha prolifera with phosphoric acid, and drying to a constant weight; grinding a dried mixture in a mortar, and then subjecting a ground sample to activation treatment in a tube furnace at 400° C. to 1,000° C. under a nitrogen atmosphere; and boiling an obtained solid product with concentrated hydrochloric acid, then washing with ultrapure water, and drying to a constant weight to obtain Enteromorpha prolifera biochar. The biochar is used in adsorption of cadmium. The method for removing cadmium using Enteromorpha prolifera biochar provided by the disclosure exhibits an extremely high adsorption and removal capacity for cadmium, with an adsorption capacity of biochar up to 250 mg/g or more.

Lanthanum-iron-loaded carbon nanotube film for environmental restoration, preparation and application thereof

A preparation method of a lanthanum-iron-loaded carbon nanotube film for environmental restoration is provided, it belongs to the technical field of composite materials. The preparation method includes: mixing carbon nanotubes with a lanthanum-iron mixed solution to obtain a suspension, then obtaining a first reaction solution by a constant temperature oscillation reaction; adding alkali liquor into the first reaction solution to obtain a second reaction solution by an oscillation reaction; carrying out a solid-liquid separation on the second reaction solution, adding the obtained solid after drying into an organic solution, and obtaining a third reaction solution by ultrasonic mixing; centrifuging the third reaction solution to obtain a supernatant; obtaining a lanthanum-iron-loaded carbon nanotube film by suction filtration. Compared with powdered adsorbent and single adsorbent, the material prepared by the preparation method has advantages of strong stability, high adsorption efficiency, good regeneration effect, high recycling efficiency, and low production.

LARGE COHESIVE ENERGY ADSORBENT FOR FLUORIDE REMOVAL, PREPARATION AND APPLICATION THEREOF
20230134129 · 2023-05-04 ·

The present disclosure provides a method for preparing a high cohesive energy adsorbent for fluoride removal, which includes the following steps: S1. adding NaHF.sub.2—NiF.Math.6H.sub.2O additive to SiCO ceramic powder, and sintering at a temperature of 310-330° C. for 18-22h to obtain a sintered substance; S2. grinding the sintered substance to obtain particles with a size of 2-3 mm, and mixing the particles with polyacrylonitrile to form a composite polymer; and S3. molding the composite polymer by a vacuum baking process at a temperature of 75-85° C., then performing ball milling and sieving to obtain the high cohesive energy adsorbent for fluoride removal. The high cohesive energy adsorbent for fluoride removal may be used in the adsorption and separation of the C.sub.2F.sub.6—CHF.sub.3—CClF.sub.3 mixture system, and the contents of CHF.sub.3 and CClF.sub.3 are lowered to less than 10ppmv.

SULFUR-DOPED CARBONACEOUS POROUS MATERIALS
20230201796 · 2023-06-29 ·

The present invention relates to novel sulfur-doped carbonaceous porous materials. The present invention also relates to processes for the preparation of these materials and to the use of these materials in applications such as gas adsorption, mercury and gold capture, gas storage and as catalysts or catalyst supports.