Provided are a composition and a manufacturing method of a solid CO.sub.2 sorbent having excellent physical properties and chemical reaction characteristics, particularly having an excellent mid-temperature range activity for a fluidized bed process, for use in collecting a CO.sub.2 source (pre-combustion or pre-utilization) in syngas application fields such as integrated coal gasification combined cycle (IGCC) power systems, synthetic natural gas (SNG) and synthetic liquid fuel (CTL).

Methods of preparing organosilica materials using a starting material mixture comprising at least one compound of Formula [(RO).sub.2SiCH.sub.2].sub.3 (Ia) and at least one compound of Formula [RROSiCH.sub.2].sub.3 (Ib), wherein each R independently represents an RO, an R group, or an (RO).sub.3SiCH.sub.2 group, at least one R being (RO).sub.3SiCH.sub.2; and R represents a C.sub.1-C.sub.4 alkyl group, in the absence of a structure directing agent and/or porogen are provided herein. Processes of using the organosilica materials, e.g., for gas separation, etc., are also provided herein.

A porous porphyrin polymer and a method of recovering precious metal elements using the same are described. A porous porphyrin polymer represented by Formula 1 has high selectivity for precious metal elements and a high ability to adsorb precious metal elements, and can be applied to the recovery of precious metal elements either from metal leachates of waste electronic products or from river water or seawater.

The present invention generally relates to compounds, systems, and methods for adsorption of CO.sub.2 onto nanoclusters.

The disclosure provides an agarose-cellulose nanocomposite porous gel microsphere, a preparation method, and an application. In the disclosure, agarose and nanocellulose are compounded to form a unique network structure by using an industrially scalable method, that is, a reversed-phase emulsification method. The maximum flow rate and pressure resistance of the porous gel microsphere are significantly improved. In addition, after the composite porous gel microsphere is modified with a specific ligand, the dynamic binding capacity of the separation target is improved, and the modified composite porous gel microsphere can be used for large-scale separation and purification of biological macromolecules. The disclosure adapts to the development trend of high rigidity, high flow rate, and high loading capacity of the chromatography medium, and is expected to be used as the next-generation chromatography medium with this performance.

A method of preparing an adsorbent can include pyrolyzing sugarcane bagasse to provide a bagasse char, activating the bagasse char, dissolving polyolefin waste in an organic solvent to obtain a solution, dispersing the bagasse char in the solution to provide a mixture, extracting the organic solvent from the mixture to provide a composite, and annealing the composite to provide the adsorbent. The adsorbent can be porous.

The invention relates to a process for the manufacture of a porous composite material for use in a gas/solid reaction system. The process includes combining at least one active ingredient, organic binder and an inorganic binder to form a mixture, adding water to form green pellets, partially drying and curing the pellets to form a composite material formed from cured pellets having a crushing strength of 4000 g/pellet-20000 g/pellet, suitable for use in a gas/solid reaction system.

A method of separating a metal organic framework (MOF) from a solution and associated apparatus. The method comprises: providing a MOF containing solution; contacting the MOF containing solution with an acoustic reflector surface such that, any high frequency ultrasound applied within the MOF containing solution reflects off the acoustic reflector surface; and applying a high frequency ultrasound of at least 20 kHz to the MOF containing solution. The MOF material is substantially separated from solution as aggregated sediment that settles out of solution.

A method of forming a gas treatment element for use in a gas treatment apparatus, such as a desiccant dryer, is disclosed. The element is formed by casting a sheet material by phase inversion of a dope mixture including a solvent, an adsorbent material such as a desiccant and a polymer binder. Layers of the sheet material are located adjacent one another and this is most readily achieved by rolling the sheet material to form the gas treatment element.

A water-absorbent carrier for moist heat sterilization can be used in a narrow space and does not have a risk of generating foreign matter. The water-absorbent carrier is obtained by embedding a water-absorbent substance in a synthetic resin. The water-absorbent carrier can be manufactured by impregnating the water-absorbent substance with a water-soluble substance, drying the water-absorbent substance, embedding the water-absorbent substance in a thermoplastic synthetic resin, and washing the water-absorbent substance to remove the water-soluble substance. Alternatively, the water-absorbent carrier can be manufactured by dispersing a water-insoluble synthetic resin in a dispersion medium, mixing the water-absorbent substance in the dispersion medium, pouring the mixture into a mold, and volatilizing the dispersion medium. A medical article to be sterilized includes the water-absorbent carrier packaged in a closed space. Moist heat sterilization (autoclave sterilization) of the medical article can be performed at a moist heat temperature exceeding 100 C.