A permanently porous vanadium(II)-containing metal-organic framework (MOF) withvanadium(II) centers and methods for synthesis of such MOF frameworks are provided. Methods for using such compounds to selectively react with N.sup.2 over CH.sub.4 are provided. In the synthetic methods, a vanadium source, such as VY.sub.2(tmeda).sub.2, where Y is a halogen and tmeda is N,N,N,N-tetramethylethane-1,2-diamine and a H.sub.2(ligand) are reacted in the presence of acid in a solvent at between 110 C. and 130 C. to form an intermediate product. The intermediate product is collected and washed with a washing agent, such as DMF and acetonitrile, and the vanadium(II) based MOF is activated by heating the washed intermediate product to at least 160 C. under dynamic vacuum.

The present invention relates to the field of solid materials for the adsorption of lithium. In particular, the present invention relates to a new method for the preparation of a crystallized and shaped solid material, preferably in extruded form, of formula LiX.sub.x.2Al(OH).sub.3,nH.sub.2O, wherein n is between 0.01 and 10, x is 1 when X is an anion selected from among chloride, hydroxide and nitrate anions, and x is 0.5 when X is an anion selected from among sulfate and carbonate anions, comprising a boehmite precipitation step a) under specific temperature and pH conditions, at least one basic mixing shaping step, wherein the method also comprises a final hydrothermal treatment step, all to increase the lithium adsorption capacity and the kinetics of adsorption of the materials obtained, compared with the materials of the prior art when it is used in a method for lithium extraction from saline solutions.

A moisture and hydrogen adsorption getter is provided. The moisture and hydrogen adsorption getter includes a silicon substrate including a concave portion and a convex portion, a silicon oxide layer conformally provided along a surface of the concave portion and a surface of the convex portion and configured to adsorb moisture, and a hydrogen adsorption pattern disposed on the silicon oxide layer. A portion of the silicon oxide layer is exposed between portions of the hydrogen adsorption pattern.

Provided is a method of producing a catalyst or adsorbent carrier and a catalyst or adsorbent carrier which can enhance a catalyst or adsorbent function, and prevent fall-off of catalyst particles or adsorbent particles. The surface of a metal base material made of aluminum or an aluminum alloy is subjected to an etching process using an etchant containing iron chloride and an oxide to convert the surface to an uneven and rough surface. The uneven and rough surface of the metal base material is subjected to an anodizing process to form a porous coating along the uneven and rough surface. A large number of catalyst or adsorbent particles are thus carried on the surface of the metal base material on which the porous coating is formed along the uneven and rough surface.

Described herein is a process for producing a zeolitic material having an MWW framework structure containing YO.sub.2 and B.sub.2O.sub.3, in which Y stands for a tetravalent element. The process includes the steps of (i) preparing a mixture containing one or more sources for YO.sub.2, one or more sources for B.sub.2O.sub.3, one or more organotemplates, and seed crystals, (ii) crystallizing the mixture obtained in (i) for obtaining a layered precursor of the MWW framework structure, and (iii) calcining the layered precursor obtained in (ii) for obtaining the zeolitic material having an MWW framework structure. Also disclosed herein are synthetic boron-containing zeolites obtain by the process and uses thereof.

The present invention relates to the field of solid materials for the adsorption of lithium. In particular, the present invention relates to a novel process for preparing a solid crystalline material formed preferably in extrudate form, of formula (LiCl).sub.x.2Al(OH).sub.3,nH.sub.2O with n being between 0.01 and 10, x being between 0.4 and 1, comprising a step a) to precipitate boehmite under specific conditions of temperature and pH, a step to place the precipitate obtained in contact with a specific quantity of LiCl, at least one forming step preferably via extrusion, said process also comprising a final hydrothermal treatment step, all allowing an increase in lithium adsorption capacity and in the adsorption kinetics of the materials obtained compared to prior art materials, when used in a process to extract lithium from saline solutions.

Filter media for treating contaminated water is produced from aluminum-based water treatment residuals (Al-WTR) commonly produced as a byproduct of water treatment plants. By processing the residuals into small granules, a superior green sorbent product is obtained with the functionality to adsorb contaminants, such as metals and certain nutrients in water. Biopolymers can be incorporated into the filter media to further enhance functionality and hydraulic characters.

A magnetic polymer adsorption material, preparation method and use thereof, which relate to the field of magnetic polymer materials. The preparation method comprises: (1) preparing magnetic nanoparticles; (2) dissolving the magnetic nanoparticles in a pore-forming agent, adding N-vinylpyrrolidone, divinylbenzene and an initiator respectively, and mixing uniformly; (3) adding an emulsifier and a dispersant into an aqueous solution; adding a part of the oil phase solution prepared in step (2) at the temperature below 60 C., and adding the rest of the oil phase solution when the temperature rises to 60 C. or above, reacting with stirring, precipitating and filtering the reacted solution, washing and drying the precipitate, and finally obtaining the magnetic polymer adsorption material. The material has the particle size of 2-100 m, the magnetization of 5-19.5 emu/g and the specific surface area of 210-950 m.sup.2/g, and can be applied to the adsorption of inorganic and organic matters in solutions, the controlled release of inorganic and organic matters, and the separation of different substances.

The present invention relates to the field of solid materials for adsorption of lithium. In particular, the present invention relates to a novel method for preparing a crystallized and shaped solid material, preferably as extrudates, of formula LiX.sub.x.2Al(OH).sub.3, nH.sub.2O with n being comprised between 0.01 and 10, x being equal to 1 when X is an anion selected from among chloride, hydroxide and nitrate anions, and x being equal to 0.5 when X is an anion selected from among sulfate and carbonate anions, comprising a step a) for precipitation of boehmite under specific temperature and pH conditions, at least one shaping step, preferably by extrusion, said method also comprising a final hydrothermal treatment step, the whole giving the possibility of increasing the adsorption capacity for lithium as well as the adsorption kinetics of the materials obtained as compared with the materials of the prior art when the latter is used in a method for extracting the lithium from saline solutions.

A method for preparing a nano-enabled activated carbon block, a nano-enabled activated carbon block produced by the method, a household water filtration system comprising the nano-enabled activated carbon block, and a method for filtering tap water using the household water filtration system are provided. The method includes contacting a solution including a metal(lic) precursor (e.g. a titanium compound and/or an iron compound and/or a zirconium compound) with activated carbon particles such that the solution fills pores of the activated carbon particles. The method further includes causing a metal (hydr)oxide (e.g. titanium dioxide and/or zirconium dioxide and/or iron oxide) to precipitate from the solution thereby causing metal oxide nanoparticles to become deposited within pores of the activated carbon particles. The method also includes preparing a nano-enabled activated carbon block from the activated carbon particles having metal oxide nanoparticles deposited within the pores thereof.