Structured adsorbent beds comprising a high cell density substrate, such as greater than about 1040 cpsi, and a coating comprising adsorbent particles, such as DDR and a binder, such as SiO.sub.2 are provided herein. Methods of preparing the structured adsorbent bed and gas separation processes using the structured adsorbent bed are also provided herein.

A chromatographic material including a substrate having a surface and having a polymeric layer covalently bound to the surface; the polymeric layer comprising polymer molecules covalently attached to the surface of the substrate, each polymer molecule being attached to the surface via multiple siloxane bonds and each polymer molecule being connected to one or more functionalizing compounds that each comprise a functional group, wherein the polymeric layer is formed by covalently attaching polymer molecules to the surface of the substrate via multiple siloxane bonds, each polymer molecule containing multiple first reactive groups, and reacting the first reactive groups of the attached polymer molecules with at least one functionalizing compound that comprises a second reactive group that is reactive with the first reactive groups and that further comprises a functional group. Preferred conditions of reacting the polymer with the substrate include elevated temperature and reduced pressure.

A preparation method of a bacterial cellulose-defective molybdenum disulfide (BC-MoS.sub.2-x) heterojunction material for treating radioactive wastewater is provided, including: preparing bacterial cellulose by the in situ growth technology of Acetobacter xylinum, and freeze-drying to obtain dried bacterial cellulose; carbonizing the dried bacterial cellulose to obtain carbonized bacterial cellulose; dispersing the carbonized bacterial cellulose into deionized water under an ultrasonic treatment; then adding thiourea and Na.sub.2MoO.sub.4.2H.sub.2O, dissolving under an ultrasonic treatment to obtain a reaction mixture, subjecting the reaction mixture to a hydrothermal reaction to obtain a BC-MoS.sub.2 heterojunction; and calcining the BC-MoS.sub.2 heterojunction in a tube furnace with an Ar/H.sub.2 atmosphere to obtain the BC-MoS.sub.2-x heterojunction.

A solidified porous carbon material uses a plant-derived material as a raw material, a bulk density of the solidified porous carbon material is in the range of 0.2 to 0.4 grams/cm.sup.3, preferably, 0.3 to 0.4 grams/cm.sup.3. A value of a cumulative pore volume in the range of 0.05 to 5 μm in pore size based on a mercury press-in method is in the range of 0.4 to 1.2 cm.sup.3, preferably, 0.5 to 1.0 cm.sup.3 per 1 gram of the solidified porous carbon material.

Provided is an adsorbent for removal of iodide ions and iodate ions, which exhibits excellent adsorption performance of iodide ions and iodate ions. An adsorbent according to the present invention comprises cerium(IV) hydroxide and a poorly soluble silver compound. It is preferable that the content of cerium(IV) hydroxide is 50% by mass or more and 99% by mass or less, and the content of the poorly soluble silver compound is 1% by mass or more and 50% by mass or less. It is also preferable that the poorly soluble silver compound is at least one selected from silver zeolite, silver phosphate, silver chloride, and silver carbonate.

An object of the present invention is to provide ferrite particles for a filtering medium excellent in filtration ability having a small apparent density, capable of various properties maintained in the controllable state and filling a specified volume with a small amount, and a filtering medium made from the ferrite particles. In order to achieve the object, ferrite particles provided an outer shell structure containing Ti oxide for a filtering medium, and a filtering medium made from the ferrite particles are employed.

A method for surface treatment of acrylate-based superabsorbents may include preparing a treatment solution including water, an organic solvent, and a silane compound; applying the treatment solution to a plurality of acrylate-based superabsorbents to form a mixture; and fabricating modified acrylate-based superabsorbents by subjecting the mixture to heating or microwave irradiation.

A method and system for manufacturing and using a self-supporting structure in processing unit for adsorption or catalytic processes. The self-supporting structure has greater than 50% by weight of the active material in the self-supporting structure to provide an open-celled structure providing access to the active material. The self-supporting structures, which may be disposed in a processing unit, may be used in swing adsorption processes and other processes to enhance the recovery of hydrocarbons.

The present disclosure provides a method for preparing a high cohesive energy adsorbent for fluoride removal, which includes the following steps: S1. adding NaHF.sub.2—NiF.Math.6H.sub.2O additive to SiCO ceramic powder, and sintering at a temperature of 310-330° C. for 18-22h to obtain a sintered substance; S2. grinding the sintered substance to obtain particles with a size of 2-3 mm, and mixing the particles with polyacrylonitrile to form a composite polymer; and S3. molding the composite polymer by a vacuum baking process at a temperature of 75-85° C., then performing ball milling and sieving to obtain the high cohesive energy adsorbent for fluoride removal. The high cohesive energy adsorbent for fluoride removal may be used in the adsorption and separation of the C.sub.2F.sub.6—CHF.sub.3—CClF.sub.3 mixture system, and the contents of CHF.sub.3 and CClF.sub.3 are lowered to less than 10ppmv.

Methods making a metal-organic framework extrudate in an extruder comprising the steps of: (a) mixing a metal-organic framework material with an extrusion aid to form a metal-organic framework extrudate mixture; and (b) extruding the metal-organic framework mixture in the extruder to produce the metal-organic framework extrudate where the pressure within the extruder is reduced between about 10% to about 55% when compared to pressure within the extruder when extruding the metal-organic framework material without the extrusion aid. The extrusion aid can be a liquid extrusion aid, a solid extrusion aid and/or a polymeric extrusion aid.