The present invention relates to novel sulfur-doped carbonaceous porous materials. The present invention also relates to processes for the preparation of these materials and to the use of these materials in applications such as gas adsorption, mercury and gold capture, gas storage and as catalysts or catalyst supports.

This disclosure provides a method of making a high-fixed-carbon material comprising pyrolyzing biomass to generate intermediate solids and a pyrolysis vapor; condensing the pyrolysis vapor to generate pyrolysis liquid; blending the pyrolysis liquid with the intermediate solids, to generate a mixture; and further pyrolyzing the mixture to generate a high-fixed-carbon material. A process can comprise: pyrolyzing a biomass-comprising feedstock in a first pyrolysis reactor to generate a first biogenic reagent and a first pyrolysis vapor; introducing the first pyrolysis vapor to a condensing system to generate a condenser liquid; contacting the first biogenic reagent with the condenser liquid, thereby generating an intermediate material; further pyrolyzing the intermediate material in a second pyrolysis reactor to generate a second biogenic reagent and a second pyrolysis vapor; and recovering the second biogenic reagent as a high-yield biocarbon composition. The process can further comprise pelletizing the intermediate material. Many process and system configurations are disclosed.

Provided is a purifying material capable of highly efficiently removing contaminant components from wastewater. A water purifying material having a composition of 30 to 40% total iron, 1 to 5% titanium, 0.1 to 1% magnesium, and 0.1 to 0.8% silica (silicon), and a method for manufacturing the water purifying material including: adding caustic soda to a solution containing 200 to 100 mg/L of bivalent iron, 20 to 100 mg/L of titanium ions, 5 to 50 mg/L of magnesium, and 3 to 30 mg/L of silica under conditions of 30 to 50° C. and pH 6.8 to 7.2 to carry out neutralization and reaction; separating and collecting an obtained solid at 100° C. or less; and drying the collected solid.

A plurality of carbonation plots are positioned in communication with atmospheric carbon dioxide to facilitate sequestration thereof via ambient weathering. The carbonation plots include a composition rich in metal oxides, which are positioned within the environment, such as on non-arable land, and exposed to the environment to react with carbon dioxide in the air and form metal carbonates. After about one year of exposure, the composition is recollected and calcined to produce a carbon dioxide stream and replenish the metal oxides, which can be redistributed in the carbonation plots to sequester additional carbon dioxide. The systems and methods of the present disclosure enable capture and redistribution of carbon dioxide for industrial-scale uses for very abundant quarry minerals and enable large-scale low-cost carbon capture projects for municipalities or corporations. CO.sub.2 removal from air via these methods and systems have a similar or lower cost than CO.sub.2 removal using DAC with synthetic sorbents or solvents.

Provided herein are methods of making an adsorbent bed useful as a micro-reactor, or a catalytic and/or separation device. The adsorbent bed comprises a metal-organic framework composite. In the present methods, one or more metal-organic frameworks in powder form are mixed in a liquid to produce a metal-organic framework suspension or other type of metal-organic framework coating. A monolith is coated with the suspension or coating to provide the metal-organic framework composite having at least one metal-organic framework coating layer deposited on and bounded to the monolith. The metal-organic framework composite produced has a BET surface area of about 1 m.sup.2/g to about 300 m.sup.2/g and/or a comparative BET surface area of about 40% to about 100% relative to the metal-organic framework monolith, and pore size between about 1 nm and about 50 nm.

A molybdenum sulfide powder according to the invention contains molybdenum disulfide having a 3R crystal structure. A heavy-metal adsorbent according to the invention contains molybdenum sulfide particles, and the molybdenum sulfide particles have a median diameter Dso of 10 nm to 1,000 nm obtained by a dynamic light scattering type particle diameter distribution measuring device. A photothermal conversion material according to the invention contains a material containing molybdenum sulfide particles and generates heat by absorbing light energy.

The present invention relates to a neutralizing absorbent for decontaminating a leaked chemical substance, a method of preparing the same, and a neutralizer filled with the same. The neutralizing absorbent for decontaminating a leaked chemical substance according to the present invention includes an inorganic adsorbent, which is commonly usable in neutralizing absorption of acidic, basic, and/or organic chemical substances, at 40 to 60 wt %, a thickener at 20 to 30 wt %, a surfactant at 20 to 30 wt %, and a color change indicator, and is formulated in a solid state. The neutralizing absorbent is effective in promptly and safely taking an initial action regardless of the type, nature, and characteristics of acidic, basic, and/or organic chemical substances leaked in the leakage accident of the chemical substance, and accordingly, is useful in preventing secondary accidents. Also, when the neutralizing absorbent is used, there are no concerns about the spread of contamination due to water generated by an acid-base reaction, concerns about the additional occurrence of secondary contamination due to a decontaminating agent can be minimized by using a non-toxic chemical absorbent, and a decontamination process can be visually checked in real time regardless of the type, nature, and characteristics of the leaked chemical substance. Furthermore, when a neutralizer filled with the neutralizing absorbent for decontaminating a leaked chemical substance according to the present invention is used, the leaked chemical substance can be more safely and effectively decontaminated during an initial action.

A zeolitic material having the ITH framework structure type.A process for the preparation of a zeolitic material having the ITH framework structure type, the process comprising: (1) preparing a mixture comprising one or more specific organotemplates as structure direct-ing agents, one or more sources of YO2, optionally one or more sources of X2O3, seed crystals, and a solvent system, wherein Y is tetravalent element and X is a trivalent ele-ment,(2) heating the mixture obtained in (1) for crystallizing a zeolitic material having the ITH framework structure type comprising YO2 and optionally X2O3 in its framework structure; wherein the one or more organotemplates comprise a specific polymeric cation.

The present disclosure provides a method of preparing a carbonaceous material capable of fixing arsenic and an application thereof. Through biomass pretreatment, biomass pyrolysis and arsenite fixation, a biochar activated by potassium carbonate and an arsenic-containing wastewater containing sulfur-containing substances are mixed and deoxidized, and an anaerobic culture is carried out, to fix arsenic by the biochar activated by potassium carbonate. The present disclosure solves the problems that arsenic is released from the soil and groundwater under anaerobic conditions, the ability of conventional passivatingagents to fix arsenic under anaerobic conditions is weakened, and the conventional carbonaceous materials not only cannot fix arsenic, but also accelerate the release of anaerobic arsenic.

A method of synthesizing a medium for fast, selective oil-water separation and/or oil absorption comprises providing a toluene solution containing a polymer or a polymer mixture; immersing porous wool-like structure (PW) in the toluene solution for a period of time; and removing the immersed PW from the toluene solution, and heat-treating the immersed PW to obtain the medium comprising polymer-modified PW, wherein the polymer or the polymer mixture is adapted such that the medium is a superwetting material that is superhydrophobic and superoleophilic under water or salty water.