The present invention relates to a preparation method of La(OH).sub.3 nanorod/walnut shell biochar composite material (LN-WB), comprising the following steps: putting walnut shell powder into a crucible and pyrolyzing and carbonizing in a muffle furnace at 350° C. to 450° C.; after the pyrolysis is completed, grinding and sieving the obtained biochar, and then repeatedly washing with deionized water; drying the washed biochar for later use; putting an appropriate amount of biochar into the deionized water to form a turbid solution; simultaneously dropwise adding LaCl.sub.3 and NaOH to the above turbid solution by using a peristaltic pump; and allowing the obtained mixture to stand at room temperature for 20 to 30 h, washing and drying for later use. The present invention successfully prepares a La(OH).sub.3 nanoparticle-loaded biochar composite material through a simple synthesis technology.

The present invention relates to the use of particulate mineral material comprising modified heulandite group zeolite for removing heavy metal cations from a liquid medium, wherein at least a part of the exchangeable cations in the heulandite group zeolite is replaced by ammonium cations.

The present invention provides a covalent-organic framework (COF) body, populations of such bodies, a method for manufacturing a covalent-organic framework (COF) body, and (a) a gas storage system or a gas separation system comprising a gas storage vessel and a population of such COF bodies. The COF body comprises a plurality of primary COF particles, some or all of the primary COF particles being agglomerated as COF agglomerates. The average diameter of the primary COF particles is between nm and 120 nm, and the average diameter of the agglomerates is larger than the average diameter of the primary COF particles and between 15 nm and 250 nm. By careful control over particle size distribution during the formation of the COF material, it is possible (b) to form COF materials into high bulk density shapes and forms which are industrially useful and practical without losing sorbent performance.

The present invention relates to a carbon dioxide adsorbent based on a hydrophobic silane-coated amine-functionalized MOF/alumina composite and, more specifically, to a carbon dioxide adsorbent based on a hydrophobic silane-coated amine-functionalized MOF/alumina composite, capable of maintaining structural stability by means of the moisture present in exhaust gas, and thus can effectively capture carbon dioxide in a real fluidized bed. According to the present invention, provided are a carbon dioxide adsorbent and a preparation method therefor, the carbon dioxide adsorbent being capable of maintaining structural stability by means of the moisture present in exhaust gas since the surface of a porous metal-organic framework/alumina oxide composite is coated with hydrophobic silane.

The present disclosure relates to a super absorbent polymer film and a preparation method of the same. Specifically, it relates to a new type of super absorbent polymer film, which is thin and exhibits excellent absorption performance and high tensile strength. In addition, the super absorbent polymer film of the present disclosure is free from scattering or leaking, and does not require an auxiliary substance such as pulp, so that products can be made thinner and the manufacturing process and costs may be reduced.

A method for preparing the ferrous sulfide-containing passivator includes: dissolving a sulfide in an alkaline solution to form a mixed solution with a pH of 12-13; adding sodium silicate to the mixed solution and stirring for 0.5-1 hour at 20-40° C.; adding an aqueous solution of ferrous salt to the mixed solution containing sodium silicate, and allowing to react at 40-60° C. for 2-3 hours; where, with decrease of the pH of the mixed solution, sodium silicate is converted into silica nanoparticles, and the ferrous salt reacts with the sulfide to form ferrous sulfide; and further adding an aqueous solution of an organic modifier, and allowing to react at 40-60° C. for 1-2 hours to form a passivator slurry including surface-modified ferrous sulfide doped with silicon dioxide; filtering the passivator slurry to form a passivator.

A modified natural sulfide ore material, a preparation method, and a use thereof are disclosed. A natural sulfide ore and a copper salt are used as raw materials. The natural sulfide ore is modified through mechanical grinding for activation, drying, and the like to synthesize a sulfide ore composite. The copper salt is subjected to a reaction to increase metal sites, produce fine microcrystalline particles, and change the crystal structure, such that active sites can be fully exposed. When contacting mercury in a gas phase and/or a liquid phase, the modified natural sulfide ore material can convert the mercury into a stable compound to realize the immobilization and removal of the mercury, which has advantages such as large mercury adsorption capacity, high adsorption rate, wide application temperature range, low cost, abundant raw material reserves, simple operation, and environmentally-friendly mercury removal products without secondary pollution and shows promising industrial application prospects.

The present disclosure discloses a cellulose nanocrystal-supported sodium alginate adsorbent and use thereof in enriching organic phosphorus in wastewater, belonging to the technical field of environmental engineering. Cellulose nanocrystals are prepared from papermaking deinking sludge through chemical conditioning, drying, crushing, chemical oxidation and microwave assisted separation, and then supported on alginate under weakly acidic conditions to provide the cellulose nanocrystals with the ability to enrich organic phosphorus in wastewater. By using this method, the content of organic phosphorus in the wastewater can be significantly reduced, the total phosphorus in the effluent can be reduced, and the wastewater treatment effluent can satisfy the discharge standard. The enriched organic phosphorus can be recycled as a phosphorus resource through incineration. In addition, the papermaking deinking sludge is made into the product with a high added value, so the applicability of the papermaking deinking sludge is broadened. The present disclosure has high feasibility.

A composition of matter having a porous cross-linked polymer network, quaternary ammonium ions in the cross-linked polymer network, and at least one counter ion in the cross-linked polymer network that is at least one of hydroxide or a counter ion capable of forming hydroxide upon reaction with water. A method to produce a porous material includes polymerizing a compound containing quaternary ammonium and a cross-linker using controlled polymerization and ion exchange in the presence of at least one of hydroxide or a counter ion capable of forming hydroxide upon reaction with water. A method to capture CO.sub.2, includes employing a sorbent comprising a quaternary ammonium ions in a porous cross-linked polymer network in an environment to adsorb CO.sub.2.

Compositions are provided for efficient uranium extraction, for example from wastewater, seawater, or other water sources. The compositions can include a functionalized porous organic polymer functionalized with one or more uranium binding moieties, e.g. having a plurality of amidoxime or amidrazone groups covalently attached thereto. The compositions can include covalent organic frameworks, porous aromatic frameworks, and various porous organic polymers, especially those having a hierarchical pore size distribution over a range of pore sizes. The compositions can have functional groups such as amidoxime or an amidrazone covalently attached thereto. The hierarchical pore size distribution can be determined based upon at least 60% of the pore sizes in the range of pore sizes having a pore volume of at least 0.01 cm.sup.3 g.sup.−1 in the pore size distribution at 77 K. Methods of making the compositions and methods of using the compositions are also provided.