The invention relates to devices, systems, and methods for precision recharging of sorbent materials in a sorbent module. The devices, systems, and methods use manufacturing characteristics of the sorbent module to set recharge parameters used in recharging the sorbent material.

An activated carbon device for adsorbing solvent from a flow of air is regenerated by feeding heated inert gas to the activated carbon and by applying a reduced pressure to the heated activated carbon.

Magnetic nanoparticle coated porous materials for recovering a contaminant from contaminated water are provided. In embodiments, such a material comprises a porous substrate having a solid matrix defining a plurality of pores distributed through the solid matrix and further comprising a coating comprising magnetic nanoparticles on surfaces of the solid matrix.

Provided is a system and method for extracting organic solutes from water with a filter media. The system and method allow for regenerating the filter media following treatment of a water supply containing one or more organic solutes to allow the media to be reused for subsequent water treatment operations. The system and method also allows for regeneration of the displacement fluid for reuse in the regeneration of the media with recovery of at least one or more organic solutes from the displacement fluid. Additionally, the system and method allows for substantially continuous treatment of a water supply and regeneration of a filter media.

Methods of contacting a fluid comprising a light hydrocarbon with a metal-organic framework adsorbent having bis(pyrazolyl) ethanediimine ligands and internal pores; adsorbing the fluid in at least a portion of the internal pores of the metal-organic framework thereby creating an adsorbed fluid; storing the adsorbed fluid in the internal pores of the metal-organic framework; and releasing the adsorbed fluid from the internal pores of the metal-organic framework, wherein the metal-organic framework adsorbent undertakes a reversible phase transition upon adsorbing the fluid. Systems of a metal-organic framework having bis(pyrazolyl) ethanediimine ligands and internal pores, wherein the metal-organic framework undertakes a reversible phase transition upon adsorption and desorption of a light hydrocarbon fluid; wherein the fluid is stored in the internal pores of the metal-organic framework.

A method for reducing the concentration of amines in a wash liquid stream exiting a wash section in an acid gas scrubbing process includes introducing the wash liquid stream exiting the wash section of the acid gas scrubbing process to an adsorbent material, wherein the wash liquid stream has a first concentration of amines. The wash liquid stream having the first concentration of amines is flowed through the adsorbent material, and the adsorbent material retains at least a portion of the amines thereby providing a wash liquid stream having a second, reduced concentration of amines. The wash stream with reduced concentration of amines is recycled back to the wash section to remove amines more effectively from the acid gas being scrubbed. The adsorbent material can be regenerated for reuse. Amine recovered from the regenerated adsorbent material can be recycled to the process for reuse.

Aspects of the present disclosure relate to a method of regenerating a hydrophobic interaction chromatography column to which a load mass has been applied, the method comprising passing one or more column volumes of an alkaline solution through hydrophobic interaction media within the column, wherein the alkaline solution exhibits a pH of between about 10 and about 14, and a conductivity of between 0.5 mS/cm and about 10 mS/cm, wherein material bound to the hydrophobic interaction media is removed. In some cases, the alkaline solution may include sodium hydroxide at a concentration of between, e.g., about 0.1 mM and 10 mM.

A composite film framework that includes a support; a metal oxide layer on the support; and a metal organic framework film on the metal oxide layer 2, wherein a metal atom is shared by a metal oxide in the metal oxide layer and a metal organic framework in the metal organic framework film at an interface between the metal oxide layer and the metal organic framework film.

Water harvesting systems and methods of making and using such water harvesting systems, for capturing water from surrounding air using configurations that reduce overall energy costs and improves water harvesting cycle efficiency in the water harvesting system. In particular embodiments, the water harvesting system can be configured for dehumidification-humidification of air, and a method in the water harvesting system for dehumidification-humidification to control moisture level in the air conditioned by the water harvesting system. The systems and methods use sorbent materials, such as metal-organic frameworks, to adsorb water from the air. The systems and methods desorb this water in the form of water vapor, and the water vapor can be condensed into liquid water and collected to dehumidify air conditioned by the water harvesting system. The collected liquid water can be sprayed to humidify air conditioned by the water harvesting system.

Yttria containing hybrid organic-inorganic sol-gels may be used in coatings for capillary microextraction, optionally hyphenated to online HPLC analysis. The sol-gel reaction mixture can use an yttrium trialkoxyalkoxide, such as yttrium trimethoxyethoxide, and a [bis(hydroxyalkyl)-amino-alkyl]-terminated polydialkyl/arylsiloxane, such as [bis(hydroxyethyl)-amine] (BHEA)-terminated polydimethylsiloxane, that can undergo hydrolysis and polycondensation, to form coating materials. Capillaries coated with such sol-gels can have improved extraction efficiency compared, e.g., to pure yttria-based coatings. The CME-HPLC can analyze water samples containing analytes of varied polarity, with excellent extraction of amides, phenols, alcohols, ketones, aldehydes, and polyaromatic hydrocarbons and detection limits ranging from 0.18 to 7.35 ng/mL (S/N=3). Such capillaries can exhibit solvent stability at pH 0 to 14, RSD % between 0.6 to 6.8% (n=3), at a preparative reproducibility RSD between 4.1 and 9.9%.