Patent classifications
B01J23/18
Method for preparing 1,1,1,2,2-pentafluoropropane
A method hydrofluorinates an olefin of the formula: RCX=CYZ to produce a hydrofluoroalkane of formula RCXFCHYZ or RCXHCFYZ, where X, Y, and Z are independently the same or different and are selected from the group consisting of H, F, Cl, Br, and C.sub.1-C.sub.6 alkyl which is partially or fully substituted with chloro or fluoro or bromo; and R is a C.sub.1-C.sub.6 alkyl which is unsubstituted or substituted with chloro or fluoro or bromo. The method includes reacting the olefin with HF in the vapor phase, in the presence of SbF.sub.5, at a temperature ranging from about −30° C. to about 65° C. and compositions formed by the process.
Method for preparing 1,1,1,2,2-pentafluoropropane
A method hydrofluorinates an olefin of the formula: RCX=CYZ to produce a hydrofluoroalkane of formula RCXFCHYZ or RCXHCFYZ, where X, Y, and Z are independently the same or different and are selected from the group consisting of H, F, Cl, Br, and C.sub.1-C.sub.6 alkyl which is partially or fully substituted with chloro or fluoro or bromo; and R is a C.sub.1-C.sub.6 alkyl which is unsubstituted or substituted with chloro or fluoro or bromo. The method includes reacting the olefin with HF in the vapor phase, in the presence of SbF.sub.5, at a temperature ranging from about −30° C. to about 65° C. and compositions formed by the process.
Method for producing oxide catalyst, and method for producing unsaturated nitrile and unsaturated acid
The present invention provides a method for producing an oxide catalyst containing antimony, comprising a step (A) of obtaining the oxide catalyst using antimony particles containing a diantimony trioxide as a source of the antimony, wherein an abundance of a pentavalent antimony in a surface layer of the antimony particle to be measured in XPS analysis is less than 70 atom %, and the antimony particle has an average particle size of 1.2 μm or less.
Method for producing oxide catalyst, and method for producing unsaturated nitrile and unsaturated acid
The present invention provides a method for producing an oxide catalyst containing antimony, comprising a step (A) of obtaining the oxide catalyst using antimony particles containing a diantimony trioxide as a source of the antimony, wherein an abundance of a pentavalent antimony in a surface layer of the antimony particle to be measured in XPS analysis is less than 70 atom %, and the antimony particle has an average particle size of 1.2 μm or less.
BISMUTH IODIDE OXIDE / ZINC OXIDE COMPOSITE AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF IN PIEZOELECTRIC PHOTOCATALYTIC REMOVAL OF ORGANIC POLLUTANTS
A bismuth iodide oxide/zinc oxide composite material, a preparation method therefor and an application thereof in piezoelectric photocatalytic removal of organic pollutants. The conductive substrate spin-coated with a zinc oxide seed solution is annealed and added to the precursor solution for reaction to obtain a zinc oxide nanorod array (ZnO NRs); the zinc oxide nanorod array is added into a bismuth iodide precursor solution for reaction to obtain the bismuth iodide oxide/zinc oxide composite material (BiOI/ZnO NAs). The composite material is put into an aqueous solution containing bisphenol A, adsorption is performed in the dark for half an hour, and then ultrasound and visible light are used together to remove organic pollutants in the water. After piezoelectric photocatalytic degradation of 90 minutes, bisphenol A in the aqueous solution is almost completely degraded.
Coating material, system based on Li/Bi catalysts
Disclosed herein is a coating material system containing (A) at least one polyhydroxy group-containing compound, (B) at least one polyisocyanate-containing compound, and (C) at least one catalyst comprising lithium (Li) and bismuth (Bi) as metal components and where the molar ratio of lithium to bismuth is at least 7:1 [mol/mol], in which i) components (A), (B), and (C) are present separately from one another, or ii) are mixed wholly or at least partly with one another. Methods for producing and using the coating material system are also disclosed herein.
Coating material, system based on Li/Bi catalysts
Disclosed herein is a coating material system containing (A) at least one polyhydroxy group-containing compound, (B) at least one polyisocyanate-containing compound, and (C) at least one catalyst comprising lithium (Li) and bismuth (Bi) as metal components and where the molar ratio of lithium to bismuth is at least 7:1 [mol/mol], in which i) components (A), (B), and (C) are present separately from one another, or ii) are mixed wholly or at least partly with one another. Methods for producing and using the coating material system are also disclosed herein.
REDUCTANT INJECTION SYSTEM AND METHOD FOR SELECTIVE CATALYTIC REDUCTION REACTION
The present disclosure relates to reductant injection system and method for a selective catalytic reduction reaction whereby urea is injected directly to an exhaust line where a denitrification reaction occurs without using an additional urea decomposition reactor and, thus, conversion from urea to ammonia can occur very fast.
REDUCTANT INJECTION SYSTEM AND METHOD FOR SELECTIVE CATALYTIC REDUCTION REACTION
The present disclosure relates to reductant injection system and method for a selective catalytic reduction reaction whereby urea is injected directly to an exhaust line where a denitrification reaction occurs without using an additional urea decomposition reactor and, thus, conversion from urea to ammonia can occur very fast.
Electrodeposition system
An electrocoat system for electrodeposition is described. The system includes an inorganic bismuth-containing compound or a mixture of inorganic and organic bismuth-containing compounds. The system demonstrates a high degree of crosslinking and produces a cured coating with optimal crosslinking and corrosion resistance.