The present invention refers to processes for catalytic reversible alkene-nitrile interconversion through controllable HCN-free transfer hydrocyanation.

The present invention refers to processes for catalytic reversible alkene-nitrile interconversion through controllable HCN-free transfer hydrocyanation.

Processes are provided for making an alkylate gasoline blending component, comprising: a. feeding an olefin feed comprising greater than 80 wppm of a sulfur contaminant comprising mercaptans, alkyl sulfides, and alkyl disulfides to a chloroaluminate ionic liquid catalyst, wherein a level of the sulfur contaminant accumulates in the chloroaluminate ionic liquid catalyst to make a sulfur-contaminated ionic liquid catalyst comprising 300 to 20,000 wppm of a sulfur; and b. alkylating the olefin feed with an isoparaffin using the sulfur-contaminated ionic liquid catalyst to make the alkylate gasoline blending component having a final boiling point below 221? C. An alkylation process exclusively utilizing coker LPG olefins is also provided.

Catalysts for oxidative sulfur removal and methods of making and using thereof are described herein. The catalysts contain one or more reactive metal salts dispersed on one or more substrates. Suitable reactive metal salts include those salts containing multivariable metals having variable valence or oxidation states and having catalytic activity with sulfur compounds present in gaseous fuel streams. In some embodiments, the catalyst contains one or more compounds that function as an oxygen sponge under the reaction conditions for oxidative sulfur removal. The catalysts can be used to oxidatively remove sulfur-containing compounds from fuel streams, particularly gaseous fuel streams having high sulfur content. Due to the reduced catalyst cost, anticipated long catalyst life and reduced adsorbent consumption, the catalysts described herein are expected to provide a 20-60% reduction in annual desulfurization cost for biogas with sulfur contents ranges from 1000-5000 ppmv compared with the best adsorbent approach.

Catalysts for oxidative sulfur removal and methods of making and using thereof are described herein. The catalysts contain one or more reactive metal salts dispersed on one or more substrates. Suitable reactive metal salts include those salts containing multivariable metals having variable valence or oxidation states and having catalytic activity with sulfur compounds present in gaseous fuel streams. In some embodiments, the catalyst contains one or more compounds that function as an oxygen sponge under the reaction conditions for oxidative sulfur removal. The catalysts can be used to oxidatively remove sulfur-containing compounds from fuel streams, particularly gaseous fuel streams having high sulfur content. Due to the reduced catalyst cost, anticipated long catalyst life and reduced adsorbent consumption, the catalysts described herein are expected to provide a 20-60% reduction in annual desulfurization cost for biogas with sulfur contents ranges from 1000-5000 ppmv compared with the best adsorbent approach.

The present disclosure provides a macroporous noble metal catalyst and processes employing such catalysts for the regeneration of deactivated ionic liquid catalyst containing conjunct polymer.

A process for injecting an immiscible liquid stream comprising a co-catalyst for a hydrocarbon conversion into a larger liquid stream that is an ionic liquid catalyst for the hydrocarbon conversion, comprising: a. feeding the immiscible liquid stream towards one or more injection quills in an additive delivery system comprising a transfer drum; b. transferring the immiscible liquid stream from the additive delivery system to the one or more injection quills in a solvent flushing system, fluidly connected downstream from the additive delivery system, wherein the solvent flushing system injects a solvent into one or more additive addition lines in the solvent flushing system; and c. continuously injecting the immiscible liquid stream into the larger liquid stream in an additive injection and mixing system comprising the one or more injection quills.

Disclosed herein are methods for synthesizing low valence, titanium-aluminum complexes from half-metallocene titanium compounds and alkylaluminum compounds. The titanium-aluminum complexes can be used as components in catalyst systems for the polymerization of olefins.

Disclosed herein are methods for synthesizing low valence, titanium-aluminum complexes from half-metallocene titanium compounds and alkylaluminum compounds. The titanium-aluminum complexes can be used as components in catalyst systems for the polymerization of olefins.

The invention relates to a silicon-based anode material for a lithium-ion battery, a preparation method therefor, and a battery. The silicon-based negative electrode material is prepared by the compounding of 90 wt %-99.9 wt % of a silicon-based material and 0.1 wt %-10 wt % of carbon nanotubes and/or carbon nanofibers which grow on the surface of the silicon-based material in situ.