Patent classifications
B01J27/125
METHOD FOR PRODUCING BROMINE PENTAFLUORIDE
There is provided a method for producing high-purity bromine pentafluoride while leaving a less amount of an unreacted fluorine gas. The method for producing bromine pentafluoride includes a reaction step of feeding a bromine-containing compound, which is at least one of a bromine gas and bromine trifluoride, and a fluorine gas to a reactor to give a (fluorine atom):(bromine atom) molar ratio, that is, F/Br of 3.0 or more and 4.7 or less and reacting the bromine-containing compound and the fluorine gas to each other to obtain a reaction mixture containing bromine pentafluoride and bromine trifluoride; and a separation step of separating bromine pentafluoride and bromine trifluoride in the reaction mixture from each other.
Method for degradating thermosetting resin, catalyst composition used therein and resin composition obtained thereby
A degradation method of thermosetting resin is provided. The method includes the following steps, for example, a first resin composition is provided. The resin in the first resin composition includes a carbon-nitrogen bond, an ether bond, an ester bond or a combination thereof. The first resin composition and a catalyst composition are mixed to perform a degradation reaction to form a second resin composition. The catalyst composition includes a transition metal compound and a group IIIA metal compound. The second resin composition includes a resin monomer or an oligomer thereof having functional groups. The functional group includes an amine group, a hydroxyl group, an ester group, an acid group or a combination thereof. A catalyst composition used in the degradation method and a resin composition obtained by the degradation method are also provided.
Catalyst for preparing 2,3,3,3,-tetrafluoropropene by gas-phase hydrodechlorination
Disclosed is a catalyst for preparing 2,3,3,3-tetrafluoropropene by gas-phase hydrodechlorination, which solves the problem of the high costs and easy deactivation of traditional chlorofluorocarbon hydrodechlorination catalysts. The disclosed catalyst is characterized in consisting of an active component and a carrier, wherein the active component is a combination of one or more of the metals: Ni, Mo, W, Co, Cr, Cu, Ce, La, Mn and Fe. The catalyst in the present invention has excellent performance, high activity, good stability and a low reaction temperature, effectively reduces reaction energy consumption, and has industrial application value.
Catalyst for preparing 2,3,3,3,-tetrafluoropropene by gas-phase hydrodechlorination
Disclosed is a catalyst for preparing 2,3,3,3-tetrafluoropropene by gas-phase hydrodechlorination, which solves the problem of the high costs and easy deactivation of traditional chlorofluorocarbon hydrodechlorination catalysts. The disclosed catalyst is characterized in consisting of an active component and a carrier, wherein the active component is a combination of one or more of the metals: Ni, Mo, W, Co, Cr, Cu, Ce, La, Mn and Fe. The catalyst in the present invention has excellent performance, high activity, good stability and a low reaction temperature, effectively reduces reaction energy consumption, and has industrial application value.
Catalyst for producing light aromatics with heavy aromatics, method for preparing the catalyst, and use thereof
A catalyst for producing light aromatics with heavy aromatics, a method for preparing the catalyst, and a use thereof are disclosed. The catalyst comprises a carrier, component (1), and component (2), wherein component (1) comprises one metal element or more metal elements selected from a group consisting of Pt, Pd, Ir, and Rh, and component (2) comprises one metal element or more metal elements selected from a group consisting of IA group, IIA group, IIIA group, IVA group, IB group, IIB group, IIIB group, IVB group, VB group, VIB group, VIIB group, La group, and VIII group other than Pt, Pd, Ir, and Rh. The catalyst can be used for producing light aromatics with heavy aromatics, whereby heavy aromatics hydrogenation selectivity and light aromatics yield can be improved.
Methods of making acrylic acid from lactic acid or its derivatives in liquid phase
Methods for making acrylic acid, acrylic acid derivatives, or mixtures thereof by contacting a feed stream containing lactic acid, lactic acid derivatives, or mixtures thereof with a molten salt catalyst comprising an ionic liquid (IL) and an acid in liquid phase are provided.
METHOD FOR DEGRADATING THERMOSETTING RESIN, CATALYST COMPOSITION USED THEREIN AND RESIN COMPOSITION OBTAINED THEREBY
A degradation method of thermosetting resin is provided. The method includes the following steps, for example, a first resin composition is provided. The resin in the first resin composition includes a carbon-nitrogen bond, an ether bond, an ester bond or a combination thereof. The first resin composition and a catalyst composition are mixed to perform a degradation reaction to form a second resin composition. The catalyst composition includes a transition metal compound and a group IIIA metal compound. The second resin composition includes a resin monomer or an oligomer thereof having functional groups. The functional group includes an amine group, a hydroxyl group, an ester group, an acid group or a combination thereof. A catalyst composition used in the degradation method and a resin composition obtained by the degradation method are also provided.
METHOD FOR PRODUCING DICARBOXYLIC ACID
A method for producing dicarboxylic acid. The method includes: subjecting a raw material system including a cyclic olefin and a lower monocarboxylic acid to an addition reaction in the presence of an addition reaction catalyst to generate an intermediate product system including cyclic carboxylic acid ester; and subjecting the intermediate product system including cyclic carboxylic acid ester to a ring-opening and oxidation reaction in the presence of an oxidant and an oxidation catalyst to generate a corresponding dicarboxylic acid product. The addition reaction in the dicarboxylic acid synthesis route achieves a high single-pass conversion rate, and the selectivity of the corresponding cyclic carboxylic acid ester is high. The addition-oxidation synthesis route achieves faster reaction rates for both the addition reaction and oxidation reaction, and high yield of corresponding dicarboxylic acid product. The addition-oxidation based synthesis route is suitable for continuous, stable and large-scale production of corresponding dicarboxylic acid product.
METHOD FOR PRODUCING DICARBOXYLIC ACID
A method for producing dicarboxylic acid. The method includes: subjecting a raw material system including a cyclic olefin and a lower monocarboxylic acid to an addition reaction in the presence of an addition reaction catalyst to generate an intermediate product system including cyclic carboxylic acid ester; and subjecting the intermediate product system including cyclic carboxylic acid ester to a ring-opening and oxidation reaction in the presence of an oxidant and an oxidation catalyst to generate a corresponding dicarboxylic acid product. The addition reaction in the dicarboxylic acid synthesis route achieves a high single-pass conversion rate, and the selectivity of the corresponding cyclic carboxylic acid ester is high. The addition-oxidation synthesis route achieves faster reaction rates for both the addition reaction and oxidation reaction, and high yield of corresponding dicarboxylic acid product. The addition-oxidation based synthesis route is suitable for continuous, stable and large-scale production of corresponding dicarboxylic acid product.
Regeneration of an ionic liquid catalyst by hydrogenation using a macroporous noble metal catalyst
Provided is a hydro-regeneration catalyst system, comprising: (a) a first graded bed comprising a guard bed material; and (b) a second graded bed, fluidly connected to the first graded bed, comprising a noble metal catalyst on a support having mesopores and macropores; wherein the noble metal catalyst has an average pore diameter of 20 to 1,000 nm (0.02 to 1 μm), a total pore volume of greater than 0.80 cc/g, and a macropore volume of 0.10 to 0.50 cc/g. Also provided is a guard bed system, comprising: (a) a first guard bed comprising a first adsorbent having 10 μm or larger pores with an average pore diameter of 100 to 1,000 μm; and (b) a second guard bed fluidly connected to the first guard bed, comprising a second adsorbent material having mesopores and macropores with a second average pore diameter of 20 to 1,000 nm.