Catalysts, catalytic forms and formulations, and catalytic methods are provided. The catalysts and catalytic forms and formulations are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane. Related methods for use and manufacture of the same are also disclosed.

A catalyst for catalytic oxidation of furfural to prepare maleic acid is composed of a carbon nitride doped with a potassium salt. A method for preparing the catalyst includes mixing the potassium salt, a precursor of the carbon nitride and a solvent to obtain a mixture, and drying and calcining the mixture to obtain the catalyst. A use of the catalyst in catalytic oxidation of furfural to prepare maleic acid, wherein the maleic acid is prepared by the step of oxidizing furfural in a solvent in the presence of the catalyst. The invention has the advantages that by using the method provided by the invention to prepare maleic acid, the conversion rate of furfural can be 99% or more and the yield of maleic acid can be up to 70.40%.

A catalyst for catalytic oxidation of furfural to prepare maleic acid is composed of a carbon nitride doped with a potassium salt. A method for preparing the catalyst includes mixing the potassium salt, a precursor of the carbon nitride and a solvent to obtain a mixture, and drying and calcining the mixture to obtain the catalyst. A use of the catalyst in catalytic oxidation of furfural to prepare maleic acid, wherein the maleic acid is prepared by the step of oxidizing furfural in a solvent in the presence of the catalyst. The invention has the advantages that by using the method provided by the invention to prepare maleic acid, the conversion rate of furfural can be 99% or more and the yield of maleic acid can be up to 70.40%.

The present invention relates to a method of preparing a catalyst for oxidative dehydrogenation. More particularly, the present invention provides a method of preparing a catalyst for oxidative dehydrogenation providing superior selectivity and yield for a conjugated diene according to oxidative dehydrogenation by constantly maintaining pH of a coprecipitation solution using a drip-type double precipitation method to adjust an -iron oxide content in a catalyst in a predetermined range.

The present invention relates to a method of preparing a catalyst for oxidative dehydrogenation. More particularly, the present invention provides a method of preparing a catalyst for oxidative dehydrogenation providing superior selectivity and yield for a conjugated diene according to oxidative dehydrogenation by constantly maintaining pH of a coprecipitation solution using a drip-type double precipitation method to adjust an -iron oxide content in a catalyst in a predetermined range.

The present invention relates to a method for preparing carbon nanotubes, the method including: preparing a support including AlO(OH) by primary heat treatment of Al(OH).sub.3; preparing an active carrier by supporting a mixture including a main catalyst precursor and a cocatalyst precursor on the support; drying the active carrier through multi-stage drying including vacuum drying; preparing a supported catalyst by secondary heat treatment of the dried active support; and preparing carbon nanotubes in the presence of the supported catalyst, and the carbon nanotubes prepared by the method as described above can remarkably improve conductivity.

The present invention relates to a method for preparing carbon nanotubes, the method including: preparing a support including AlO(OH) by primary heat treatment of Al(OH).sub.3; preparing an active carrier by supporting a mixture including a main catalyst precursor and a cocatalyst precursor on the support; drying the active carrier through multi-stage drying including vacuum drying; preparing a supported catalyst by secondary heat treatment of the dried active support; and preparing carbon nanotubes in the presence of the supported catalyst, and the carbon nanotubes prepared by the method as described above can remarkably improve conductivity.

The present invention provides a catalyst composition for the production of olefins from lighter alkanes by oxidative dehydrogenation route and methods of making the dehydrogenation catalyst composites.

The present invention provides a catalyst composition for the production of olefins from lighter alkanes by oxidative dehydrogenation route and methods of making the dehydrogenation catalyst composites.

Disclosed is a modified carbonaceous material, which includes hexagonal carbon networks in a layered stacking structure and acidic functional groups bonded to the hexagonal carbon networks and mainly existing at edges of the layered carbonaceous structure. Accordingly, the close proximity of acid moiety at the edges can resemble the center of hydrolysis enzymes, resulting in enhancement of hydrolytic efficiency. Additionally, the acid-functionalized carbonaceous material can also be applied in the capture and storage of carbon dioxide due to its unexpectedly higher capacity for CO.sub.2 molecular.