MODIFIED CARBONACEOUS MATERIAL, CARBON DIOXIDE ADSORBENT AND METHOD FOR CELLULOSE HYDROLYSIS USING THE SAME

Abstract

Disclosed is a modified carbonaceous material, which includes hexagonal carbon networks in a layered stacking structure and acidic functional groups bonded to the hexagonal carbon networks and mainly existing at edges of the layered carbonaceous structure. Accordingly, the close proximity of acid moiety at the edges can resemble the center of hydrolysis enzymes, resulting in enhancement of hydrolytic efficiency. Additionally, the acid-functionalized carbonaceous material can also be applied in the capture and storage of carbon dioxide due to its unexpectedly higher capacity for CO.sub.2 molecular.

Claims

1. A modified carbonaceous material, comprising hexagonal carbon networks in a layered stacking structure and acidic functional groups bonded to the hexagonal carbon networks, wherein all or plural ones of the acidic functional groups are covalently linked to in-plane sp.sup.2 carbons at edges of the hexagonal carbon networks, the plural ones of the acidic functional groups at the sp.sup.2 carbons of the hexagonal carbon networks being greater in quantity than others covalently linked to sp.sup.3 carbons of the hexagonal carbon networks.

2. The modified carbonaceous material of claim 1, wherein the acidic functional groups include at least one of sulfonic, carboxyl, lactone and phenolic hydroxyl groups.

3. The modified carbonaceous material of claim 1, wherein the modified carbonaceous material is a nonporous material.

4. The modified carbonaceous material of claim 1, wherein the modified carbonaceous material is prepared by modifying a pitch-based material with the acidic functional groups.

5. The modified carbonaceous material of claim 1, wherein the modified carbonaceous material is a pitch-based material treated with sulfuric acid, nitric acid or hypochlorite salt.

6. The modified carbonaceous material of claim 5, wherein the pitch-based material is further subjected to hydrothermal treatment after treated with the sulfuric acid.

7. The modified carbonaceous material of claim 1, wherein the modified carbonaceous material has substantially no sp.sup.3 carbon peak in a .sup.13C CP/MAS NMR spectrum thereof.

8. The modified carbonaceous material of claim 1, wherein the modified carbonaceous material has an I.sub.D/I.sub.G ratio of not larger than 1 as measured by Raman spectroscopy.

9. The modified carbonaceous material of claim 1, wherein the modified carbonaceous material has a C1s/O1s ratio of not less than 3 as measured by X-ray photoelectron spectroscopy.

10. The modified carbonaceous material of claim 1, wherein the modified carbonaceous material has a total acid site density of 1.5 mmol/g or more.

11. The modified carbonaceous material of claim 1, wherein the modified carbonaceous material has an interlayer spacing in a range of from 0.34 nm to 0.37 nm as measured by X-ray diffraction.

12. The modified carbonaceous material of claim 2, wherein the modified carbonaceous material comprises the sulfonic groups in a density of 0.8 mmol/g or more, the phenolic hydroxyl groups in a density of 0.5 mmol/g or more, the carboxyl groups in a density of 0.1 mmol/g or more, and the lactone groups in a density of 0.4 mmol/g or more.

13. The modified carbonaceous material of claim 2, wherein the modified carbonaceous material comprises the phenolic hydroxyl groups in a density of 0.3 mmol/g or more, the carboxyl groups in a density of 0.2 mmol/g or more, and the lactone groups in a density of 0.3 mmol/g or more.

14. A CO.sub.2-capturing acid-functionalized adsorbent, comprising hexagonal carbon networks in a layered stacking structure and acidic functional groups bonded to the hexagonal carbon networks, wherein the hexagonal carbon networks substantially consist of aromatic carbons, and substantially all of the acidic functional groups are covalently linked to in-plane sp.sup.2 carbons at edges of the hexagonal carbon networks.

15. The CO.sub.2-capturing acid-functionalized adsorbent of claim 14, wherein the CO.sub.2-capturing acid-functionalized adsorbent is in a nonporous structure.

16. The CO.sub.2-capturing acid-functionalized adsorbent of claim 14, wherein the acidic functional groups include sulfonic, carboxyl, lactone and phenolic hydroxyl groups.

17. The CO.sub.2-capturing acid-functionalized adsorbent of claim 14, wherein the CO.sub.2-capturing acid-functionalized adsorbent is prepared by modifying a pitch-based material with the acidic functional groups.

18. The CO.sub.2-capturing acid-functionalized adsorbent of claim 14, wherein the CO.sub.2-capturing acid-functionalized adsorbent has an I.sub.D/I.sub.G ratio of not larger than 1 as measured by Raman spectroscopy.

19. The CO.sub.2-capturing acid-functionalized adsorbent of claim 14, wherein the CO.sub.2-capturing acid-functionalized adsorbent has a C1s/O1s ratio of not less than 3 as measured by X-ray photoelectron spectroscopy.

20. The CO.sub.2-capturing acid-functionalized adsorbent of claim 14, wherein the CO.sub.2-capturing acid-functionalized adsorbent has a total acid site density of 1.5 mmol/g or more.

21. The CO.sub.2-capturing acid-functionalized adsorbent of claim 14, wherein the CO.sub.2-capturing acid-functionalized adsorbent has an interlayer spacing in a range of from 0.34 nm to 0.37 nm as measured by X-ray diffraction.

22. The CO.sub.2-capturing acid-functionalized adsorbent of claim 16, wherein the CO.sub.2-capturing acid-functionalized adsorbent comprises the sulfonic groups in a density of 0.8 mmol/g or more, the phenolic hydroxyl groups in a density of 0.5 mmol/g or more, the carboxyl groups in a density of 0.1 mmol/g or more, and the lactone groups in a density of 0.4 mmol/g or more.

23. A method for cellulose hydrolysis, comprising: mixing the modified carbonaceous material of claim 1 and a cellulose in an aqueous solution; and hydrolyzing the cellulose at a predetermined temperature in the presence of the modified carbonaceous material as a catalyst.

Description

BRIEF DESCRIPTION OF THE DRAWINGS

[0018] FIGS. 1 and 2 show nitrogen gas sorption isotherms of MP-based materials;

[0019] FIG. 3 shows carbon dioxide gas sorption isotherms of MP-based materials;

[0020] FIG. 4 shows FTIR spectra of MP-based materials;

[0021] FIG. 5 shows solid-state NMR analysis of MP-based materials;

[0022] FIG. 6 shows XPS analysis of MP-based materials;

[0023] FIG. 7 shows Raman analysis of MP-based materials;

[0024] FIG. 8 shows the total production of crystalline celluslose hydrolysis with functional MP-based materials for 2 hours;

[0025] FIG. 9 shows the total production of crystalline celluslose hydrolysis with functional MP-based materials for 3 hours;

[0026] FIG. 10 shows the total production of crystalline celluslose hydrolysis with functional MP-based materials for 4 hours;

[0027] FIG. 11 shows the total production of amorphous celluslose hydrolysis with functional MP-based materials for 3 hours;

[0028] FIG. 12 shows the total production of amorphous celluslose hydrolysis with functional MP-based materials for 4 hours;

[0029] FIG. 13 shows the total production of pre-hydrolytic celluslose hydrolysis with functional MP-based materials for 3 hours;

[0030] FIG. 14 shows the leaching test of amorphous cellulose with functional MP-based materials at 180 C. for 3 hours; and

[0031] FIG. 15 shows cellulose hydrolysis efficiency for functional MP-based materials, H.sub.2SO.sub.4, Amberlyst 15, Nafion 50 and MCNHSO.sub.3.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

ExamplesPreparation of Functionalized Mesophase Pitch

[0032] Mesophase pitch (softening point: 275-295 C., Mitsubishi Gas Chemical, Japan) was ground and meshed in 230 mesh screens, to a particle size of 63 microns prior to further treatment and reactions.

[MPSO.SUB.3.H]

[0033] The functional mesophase pitch material (SO.sub.3H-MP) was synthesized by using concentrated H.sub.2SO.sub.4 (95-97% of SO.sub.3) solution as an oxidizing agent. The mesophase pitch (1.2 g) was sulfonated by heating in concentrated sulfuric acid at 80 C. for 20 hours and subsequently at 150 C. for 7 hours under a dry nitrogen atmosphere. After the reaction, the functional MPs were collected via filtration and washed with copious amounts of water. The materials were treated for Soxhlet extraction with 500 mL of water for a period of 8 hours, and this extraction procedure was repeated two times. Finally, the modified material was placed in a freeze dryer to dry.

[MP-SO.SUB.3.HHT]

[0034] MP-SO.sub.3H-HT was produced by three repetitions of hydrothermal treatment of MP-SO.sub.3H. MP-SO.sub.3H (0.5 g) was placed in an autoclave with 30 mL of water at 200 C. for 8 hours. After hydrothermal treatment, the material was collected by filtration and washed by the Soxhlet extraction procedure. The same step was repeated for two times to synthesize MP-SO.sub.3HHT.

[MPCOOH]

[0035] To synthesize MPCOOH, 500 mg of MPs were placed in a 100 mL round-bottom flask with 50 mL of varying concentrations (7.9M, 7M, 6M, 5M, 4M or 1M) of nitric acid. The solution was then refluxed at 105 C. for 1.5 or 3 hours. After the reaction, the functional MPs were collected via filtration and washed with copious amounts of water. The resulting materials were treated for Soxhlet extraction with 500 mL of water for a period of 8 hours, repeated two times. Finally, the modified material was placed in a freeze dryer to dry. Among the various reaction conditions, 6M for 1.5 hours was considered to be a condition for the optimization of carboxylic acid groups. Thus, the MPCOOH synthesized under the reaction conduction of 6M for 1.5 hours was subjected to the following analysis.

[0036] Additionally, MPCOOH can also be prepared by modification of pre-treated materials: MPs (300 mg) was calcined under different gases (the nitrogen and air) at a 250 C. or 280 C. for 2, 4 or 6 hours, followed by adding 30 mL of nitric acid (7.9M, 7M, 6M, 5M, 4M or 1M) at 105 C. for 1.5 hours or 3 hours.

[MPOxy]

[0037] To synthesize MP-Oxy, 500 mg of MPs were placed in a 500 mL round-bottom flask with 250 mL of 5% sodium hypochlorite, and the pH adjusted to about 4-5 with 37% concentrated hydrochloric acid at 30 C. for 12, 18 or 24 hours. After the reaction, the functional MPs were collected via filtration and washed with copious amounts of water. The resulting materials were treated for Soxhlet extraction with 500 mL of water for a period of 8 hours, repeated two times. Among the MP-Oxy materials synthesized under the various reaction times, the one treated for 24 hours was selected for subsequent analysis. Optionally, after acid modification, hydrothermal treatment may be performed once for repairing the structure of the MP-Oxy material to obtain MP-Oxy-HT.

Comparative ExamplePreparation of MCNHSO.SUB.3

[0038] The functional msoporous carbon nanoparticle material (HSO.sub.3-MCN) was synthesized by using fuming H.sub.2SO.sub.4 (20% of SO.sub.3) solution as an oxidizing agent. MCN materials (1.2 g) were treated in fuming sulfuric acid solution (80 mL) in a round-bottom flask (50 mL), and the mixture was heated under nitrogen at 80 C. for 24 h. After reaction, the as-synthesized functional MCN were collected via filtration and washed with copious amounts of water. The as-synthesized MCN material (1.2 g) was Soxhlet extracted with 250 mL water for a period of 3 h, and this extraction procedure was repeated four consecutive times.

Nitrogen Gas and Carbon Dioxide Gas Sorption Isotherms

[0039] Nitrogen gas (N.sub.2) and carbon dioxide gas (CO.sub.2) sorption isotherms of samples were analyzed using Micromeritics 3Flex analyzer under a 110.sup.6 mmHg vacuum level. The isotherms of N.sub.2 sorption were analyzed at relative pressure (P/P.sub.0) between 0.05 and 0.995 and at liquid nitrogen temperatures (77 K), and the Brunauer-Emmett-Teller (BET) specific surface area was derived at the range of relative pressure (P/P.sub.0) between 0.05 and 0.3. The CO.sub.2 sorption isotherms were analyzed at relative pressure (P/P.sub.0) between 0.0003 and 0.03 and at 273 K (P.sub.0=26,142 mmHg) and 298 K (P.sub.0=48,273 mmHg). The analysis temperature for CO.sub.2 was achieved using Micromeritics ISO controller within 0.1 C. Samples (50 mg) were initially degassed using Micromeritics Smart VacPrep degasser at 393 K for 12 hours, under a 110.sup.3 mmHg vacuum level. The free space of sample tubes were determined using helium gas (He) with a purity of 99.996%. The nitrogen gas (N.sub.2) sorption isotherms of samples were shown in FIGS. 1 and 2, whereas the carbon dioxide gas (CO.sub.2) sorption isotherms of samples were shown in FIG. 3.

[0040] The results showed that the surface areas of all materials were relatively lower than other porous materials (surface area: 55.2 m.sup.2/g for MP-HSO.sub.3, 25.2 m.sup.2/g for MP-HSO.sub.3HT, 2.18 m.sup.2/g for MPCOOH, 1.56 m.sup.2/g for MP-Oxy). This indicated that functional MPs were nonporous materials. Surprisingly, in the linear gas molecule (CO.sub.2) physical sorption study at 273K, MPSO.sub.3H and MPSO.sub.3HHT exhibited high CO.sub.2 adsorption capacity (2.46 mmol/g for MPSO.sub.3H, 2.23 mmol/g for MPSO.sub.3H-HT) with the isotherm exhibited type (II). The CO.sub.2 physically adsorption in considerable quantity observed in MPSO.sub.3H and MPSO.sub.3H-HT is surprising because it contradicts the concept of CO.sub.2 sequestration by using the materials with the high surface or possessing base functionality.

Identification of Acid Sites Density

[0041] Acid site determination was carried out based on Boehm's method, and elemental analysis was used to analyze the sulfur and expressed as a sulfonic. In order to determine functional groups such as carboxyl, lactone and phenolic hydroxyl groups, Boehm selective neutralization of each functionality used different base solutions: sodium hydroxide (NaOH) for all of three functionalities; sodium carbonate (Na.sub.2CO.sub.3) for carboxyl and lactone; sodium bicarbonate (NaHCO.sub.3) only for carboxylic acid. All acid and base solutions (HCl, NaOH, Na.sub.2CO.sub.3, and NaHCO.sub.3, KHP) were prepared in the concentration of 0.01M. Since NaOH concentration is easily changed due to exposure with CO.sub.2 in the air, potassium hydrogen phthalate was used to cross-check the concentration of the prepared sodium hydroxide. The obtained concentration value was used as the sodium hydroxide concentration. Afterward, HCl was titrated with NaOH to determine HCl concentration. Finally, Na.sub.2CO.sub.3 and NaHCO.sub.3 concentrations were checked by using HCl. Phenolphthalein was used as an indicator for NaOH solution, and bromocresol green as an indicator for Na.sub.2CO.sub.3 and NaHCO.sub.3 solutions, respectively.

[0042] Boehm titration was conducted in the following manner: 50 mg of material (MP-based) was added to 20 mL of each base solution (NaOH, Na.sub.2CO.sub.3, and NaHCO.sub.3) in a 50 mL tube. All three samples were vortexed for 2 hours and then filtered to recover the solution. Afterwards, the recovered solutions from each base was titrated with HCl. Acid sites were determined from the corresponding titrated base solution with HCl. Carboxylic acid, combination of carboxyl and lactone, and total acid sites were calculated by using NaHCO.sub.3, Na.sub.2CO.sub.3 and NaOH, respectively. Phenol density was calculated from the difference between the density determined by NaOH and Na.sub.2CO.sub.3.The following equation was used to calculate the acid sites of each group:

[00001]$\mathrm{Acid}.Math..Math.\mathrm{site}=\frac{\left(M_{\mathrm{Base}}20.Math..Math.\mathrm{mL}\right)-\left(M_{\mathrm{HCl}}v\right)}{\mathrm{catalyst}.Math..Math.\mathrm{amount}.Math..Math.\left(g\right)}.$

[0043] The results of the study showed that the MPHSO.sub.3HT had lower total acid site (2.25 mmol/g) than that of MPHSO.sub.3 (3.12 mmol/g) because the functional groups of MP-HSO.sub.3HT were removed via hydrothermal treatment. Additionally, the total acid site of MPCOOH (2.00 mmol/g) was lower than that of MPHSO.sub.3 or MPHSO.sub.3HT, indicating that the oxidation of nitric acid was not as good as sulfuric acid, and the total acidity of MP-Oxy (1.96 mmol/g) was the lowest among all materials.

[0044] The distribution of acid sites of untreated MP and functionalized MPs is shown in Table 1.

TABLE-US-00001 TABLE 1 Sulfonic Carboxyl Lactones Phenols Group .sup.a Group Group Group sample (mmol/g) (mmol/g) (mmol/g) (mmol/g) MP 0.0965 0.02275 0.089 MP-HSO.sub.3 1.50 0.27 0.84 0.56 MP-HSO.sub.3-HT 0.88 0.12 0.50 0.77 MP-COOH 1.28 0.35 0.37 MP-Oxy 0.28 0.88 0.76 .sup.a Sulfur content was determined by elemental analysis

Powder X-Ray Diffraction (PXRD)

[0045] The powder XRD spectra were recorded in this experiment by a Bruker D8 Advance spectrometer operating at a voltage of 40 kW and a current of 40 mA generated with Cu K radiation (=1.5418 ). The scan angle is 10 to 90 with the scan rate of 6/minute.

[0046] The XRD pattern of the MP-based materials show a peak at a 20 angle of 24-25, which can be interpreted as the (002) plane of the amorphous carbon structure. Compared to strong intensity peak of the unmodified MP, the modified materials showed broad, weak peaks at the same angle, indicating that the crystal phase was weakened by the oxidation treatment and the stacking of layered structures was random.

[0047] Additionally, the d-spacing (distance of its interlayer structure) of all materials calculated by Bragg's law 2d(hkl)sin =n was shown as follows: 0.366 nm (MPHSO.sub.3), 0.366 nm (MPHSO.sub.3HT), 0.343 nm (MPCOOH), and 0.345 nm (MP-Oxy).

Fourier-Transform Infrared Spectroscopy (FTIR)

[0048] The FTIR spectra of functionalized MP materials were shown in FIG. 4. The bands at 1027 cm.sup.1 and 1151 cm.sup.1 on MPSO.sub.3H and MPSO.sub.3HHT are assigned to asymmetric and symmetric stretching of SO and SO of sulfonic groups SO.sub.3H. The band at 1326 cm.sup.1 is assigned to the CO stretching. The band at 1521-1596 cm.sup.1 are attributable to CC stretching mode of graphitic structure. The band at 1712 cm.sup.1 is assigned to the CO stretching mode of carboxylic acid groups. Furthermore, the broad band between 2850-3045 cm.sup.1 is assigned to the CH stretching modes, and the band attributed to the OH groups of the carboxylic acid and phenolic acid is located at 3300-3400 cm.sup.1.

.SUP.13.C Solid-State NMR (SSNMR)

[0049] The .sup.13C DP-mass rotation (.sup.13C DP-MAS) spectrum was shown in FIG. 5. There were two prominent peaks centered at a chemical shift of 22 ppm and 125 ppm for the MP spectrum, which indicated that two major chemical compositions, aliphatic carbon and aromatic carbon. In the MPSO.sub.3H and MPSO.sub.3HHT spectra, the aliphatic carbon peak was obviously not observed, while the aromatic carbon peak shifted a bit downfield with a new peak centered at chemical shift 180 ppm, which could represent the oxidized group, such as carboxylic acid. The chemical shift of the aromatic carbon adjacent to sulfonic acid may have merged around 130 ppm, becoming indistinguishable amongst other aromatic carbons. In addition to the above performance, MPCOOH and MP-Oxy can also be found to still have aliphatic carbon peaks, with MP-Oxy having a new peak at a chemical shift of 57 ppm. According to the literature, it is an O-alkyl-C group. The results above confirmed that modification of the acidic functional groups mostly occur on the edge of the materials, while MPCOOH and MP-Oxy have a little acidic functional groups modified on the benzene ring.

X-Ray Photoelectron Spectroscopy (XPS)

[0050] The analysis of XPS was shown in FIG. 6. The calculation of the C/O ratio was given by: [(Integrated area of C1.sub.S)/(sensitive factors of C1.sub.S)/(Integrated area of O1.sub.S)/(sensitive factors of O1.sub.S)]. The analysis results indicated that the C/O ratio of the unfunctionalized material MP was 4.89, while the C/O ratio of the functional materials MPSO.sub.3H, MPSO.sub.3H-HT, MPCOOH, and MP-Oxy were 5.85, 4.75, 3.72, and 3.32, respectively. The higher ratio of MPSO.sub.3H was attributed to that most of the functional groups were modified on the edge. For MPSO.sub.3HHT, as the hydroxyl group replaced the sulfonated group after hydrothermal treatment, the ratio of MPSO.sub.3HHT decreased. The functional groups of MPCOOH and MP-Oxy were not only modified at the edge of the material but also partially modified on the benzene ring, resulting in lower C/O ratio.

Raman Spectroscopy

[0051] In the analysis of Raman spectroscopy, the D band and the G band were observed at 1360 cm.sup.1 and 1585 cm.sup.1, respectively, as shown in FIG. 7. The D band at 1360 cm.sup.1 represents out of plane vibrations attributed to the presence of structural defects (sp.sup.3), and the G band at 1585 cm.sup.1 is assigned to in-plane vibrations of sp.sup.2 bonded carbon atoms. The analysis results showed that the ID/IG ratio of the non-functional material MP was 0.83, while the ID/IG ratios of MPSO.sub.3H (0.74) and MPSO.sub.3HHT (0.88) were lower than those of MPCOOH (0.96) and MP-Oxy (0.97). Therefore, it can be confirmed that MPSO.sub.3H and MPSO.sub.3H-HT had more functional groups on the edge compared to MPCOOH and MP-Oxy.

Preparation of Amorphous Cellulose and Pre-Hydrolytic Cellulose

[0052] Amorphous cellulose was synthesized by rinsing 5 g of commercial microcrystalline cellulose (Avicel PH-101) in 40 mL of concentrated HCl first, followed by the addition of 160 mL of cold HCl (pre-chilled in dry ice bath for 1.5 hours) for cellulose dissolution. The -glucan/HCl solution was added into 1 L of cold acetone for the reprecipitation of a fluffy white solid directly, or after dissolution for 2 hours at room temperature (pre-hydrolytic cellulose). It was then separated by ultra-centrifuge at 4 C. at 15,000 rpm for 15 minutes, repeated three times. During the centrifuge processing, the solids were washed with cold acetone and stored at a low temperature environment to decrease the possibility that the hydrolysis of cellulose will produce unusably short -glucan chains. The separated solid was dispersed in 1.5 L of cold DI water first, and then the white powder was filtrated out with PTFE filter paper and washed with cold DI water to achieve a neutral pH value. Furthermore, the synthesized amorphous cellulose was purified by Soxhlet extraction set-up with DI water for 24 hours and then freeze-dried for 3 days.

Hydrolysis of Cellulose

[0053] Cellulose Hydrolysis: Microcrystalline cellulose (Avicel PH-101), amorphous cellulose or pre-hydrolytic cellulose (50 mg) were selected for hydrolytic depolymerization, with either (i) heterogeneous catalysts of MP or functional MPs (5 mg), MCNHSO.sub.3 (5 mg), commercially strong acidity resin of Amberlyst 15 (5 mg) or Nafion 50 (a bead around 40 mg) in DI water solution (2 mL) or (ii) homogeneous sulfuric acid aqueous solution (7.5 mN, 2 mL) The resulting suspension was placed in specialized high-pressure glass tubes (outer diameter: 1.9 cm, length: 6.0 cm), which contained a stir bar. The tubes were placed in a pre-heated heating block treated at 130, 150 or 180 C. for 2, 3, 4, 12, 24, or 48 hours, at autogenous pressure, under 400 rpm stirring. After the reaction, the tube was taken off the heating block for cooling. Spent mixture and filtrate were separately collected using SPE filtration assembly (200 mg/3 mL SPE column, Silica), and the filtrated mixture was subsequently washed with 75 C. water (8 mL) to completely remove residual saccharides or derivatives into pre-weighted 15 mL polypropylene tubes. The volume of filtrate (Vfiltrate) was derived from the division of the tube mass difference before and after filtration and the density of the water (1 g/cm.sup.3) (Vfiltrate=(MfullMempty)/(1 g/cm.sup.3); Empty: empty tube mass; Mfull: tube mass after filtration). The concentration of filtrate was characterized by HPLC to evaluate the products generated from reactions and the weight percentage of cellulose converted. For control experiments, the reaction conditions were the same as aforementioned except that no catalyst was introduced.

[0054] The hydrolytic depolymerization results of three different types of cellulose, crystalline cellulose, amorphous cellulose, and pre-hydrolytic cellulose (50 mg) along with functionalized MP, MPSO.sub.3H, MPSO.sub.3HHT, MPCOOH, and MP-Oxy (5 mg) were presented in FIGS. 8-13. The materials were reacted with three kinds of celluloses in a 2 mL aqueous solution at 180 C. for 2, 3 and 4 hours. The results showed that after the hydrolysis, three products were obtained: cellobiose, glucose, and HMF, with glucose being the main product after hydrolysis. As a result, it was found that MPCOOH had a lower glucose yield due to its relatively low acid sites density, while the MPSO.sub.3H and MPSO.sub.3H-HT had higher acid sites with strongly acidic functional groups concentrated on the edge of materials, thus promoting cleavage of the glycosidic bonds. In particular, MPSO.sub.3H reacts with pre-hydrolytic cellulose at 180 C. for 3 hours, obtaining the highest glucose yield of 44%. Only the MP-Oxy had a higher glucose yield as the reaction time increased.

Leaching Test

[0055] First, 3 mL of DI water was added into 7.5 mg of MP-based catalysts in a reaction tube, and the tube was heating at 180 C. for 3 hours. After the reaction, the solution was filtered by the 0.22 m PTFE syringe filter, and 2 mL of the clear filtrate was added into 50 mg of cellulose in another reaction tube. The second reaction tube was processed at the corresponding temperature and time as the first reaction tube.

[0056] The results of leaching tests of amorphous cellulose with different catalysts at 180 C. for 3 hours were shown in FIG. 14. It can be seen that the glucose yields caused by leaching for MPSO.sub.3H, MPSO.sub.3HHT and MPCOOH were 2.3%, 0.5% and 0.3%, respectively. The very low glucose production contribution by acidic leaching of these materials indicated that the cellulose hydrolysis was mainly caused from acidic functionalities on the edge of functional MP-based materials, whereas the glucose production caused by the acidic leaching of the MP-Oxy material was as high as 39%.

Comparison of Cellulose Hydrolysis Efficiency with Other Catalysts

[0057] The hydrolytic efficiencies of cellulose using MP-based catalysts were compared with other materials such as commercially strong acidic resin of Amberlyst 15 hydrogen form (5 mg) or Nafion NR50 (a bead around 40 mg), the sulfonated mesoporous carbon nanoparticle (MCNSO.sub.3H) and even homogeneous sulfuric acid aqueous solution (7.5 mN, 2 mL), as shown in FIG. 15. The results indicated that the Amberlyst 15 as a catalyst for hydrolysis with the amorphous cellulose at 180 C. for 3 hours resulted in a glucose yield of about 9.5%, while that of Nafion 50 as a catalyst is only about 5.9%. Although these commercial heterogeneous catalysts had strong acid groups on the surface could lead to high hydrolytic efficiency of cellulose, the location of these acidic groups on the surface might be very distant. Thus, the glucose production was 3-fold higher for functional MPs, although the leaching test of Amberlyst 15 and Nafion 50 gave the glucose yield of 2.5% and 0.4%, respectively. On the other hand, the heterogeneous catalyst MCNSO.sub.3H was used as a catalyst to obtain a glucose yield of 6.9%. The low glucose yield could be attributed to the lower acid surface coverage within porous channels, even leading to a glucose yield caused by material leaching of 0.6%. As for homogeneous sulfuric acid aqueous solution, which had equivalent acid amounts as MPSO.sub.3H, the hydrolytic efficiency of the homogeneous reaction was half lower than MPSO.sub.3H. Presumably, in the same aqueous solution, the MPSO.sub.3H had a high surface coverage of acidic that could make cellulose more efficient to break the glycosidic bond.

[0058] In the above examples, a series of mesophase pitch (MP)-based materials were synthesized with high surface coverage of acidic functionalities by chemical oxidation methods, including MPSO.sub.3H (treated with sulfuric acid), MPSO.sub.3H-HT (hydrothermal treated MPSO.sub.3H), MPCOOH (treated with nitric acid) and MP-Oxy (treated with sodium hypochlorite). Results of acid-base back titration indicated MPSO.sub.3H had the highest acid sites density (3.1 mmol/g), with major sulfonic acid of 1.5 mmol/g and lactones of 0.84 mmol/g. After hydrothermal treatments, the sulfonic groups decreased for MPSO.sub.3HHT with more phenols generated. Specific surface areas of functional MP were lower than 56 m.sup.2/g by nitrogen sorption, indicating that these materials had nonporous structures. Nearby weak acid molecules on MP were similar to the enzyme for cellulose hydrolysis, which had the proximity of carboxylic groups in the active center, and might be a replacement catalyst for cellulose hydrolysis. Surprisingly, the highest CO.sub.2 adsorption amounts (2.46 mmol/g) were observed for MPSO.sub.3H, which might have great potential in CO.sub.2 sequestration and thus can serve as CO.sub.2-capturing nonporous acid-functionalized sorbent.

[0059] The above examples are intended for illustrating the embodiments of the subject invention and the technical features thereof, but not for restricting the scope of protection of the subject invention. Many other possible modifications and variations can be made without departing from the spirit and scope of the invention as hereinafter claimed. The scope of the subject invention is based on the claims as appended.