B01J27/26

Electrodes Employing Aptamer-Based Recognition for Colorimetric Visualization
20220341901 · 2022-10-27 · ·

An electrochemical aptamer-based (E-AB) sensor is disclosed. The sensor is a closed bipolar electrode having a first end and a second end. The first end comprises an electrochromic material. The second end comprises an electrocatalyst and an oligonucleotide aptamer tethered to the second end. Further, the oligonucleotide aptamer is labelled with a redox indicator.

High-activity double-metal-cyanide catalyst

A high-activity double-metal-cyanide catalyst, a method for fabricating the same, and applications of the same are disclosed. An organic complexing ligand, which is formed via mixing fatty alcohols and alicyclic carbonates, is used to generate a high-activity double-metal-cyanide catalyst. The high-activity double-metal-cyanide catalyst includes at least one double-metal-cyanide compound, at least one organic complexing ligand, and an optional functionalized compound. The double-metal-cyanide catalyst of the present invention has a higher activity than the conventional double-metal-cyanide catalysts. The polyols generated by the present invention has an insignificant amount of high-molecular-weight compounds.

SYNTHESIS METHOD OF g-C3N4/C COMPOSITE MATERIAL BASED ON HOLLYHOCK STALK
20230201811 · 2023-06-29 ·

The present disclosure provides a synthesis method of a g-C.sub.3N.sub.4/C composite material based on a hollyhock stalk, including the following steps: (1) pretreatment of hollyhock stalks; and (2) fabrication of the g-C.sub.3N.sub.4/C composite material. In this method, with the hollyhock stalk as a carbon skeleton, g-C.sub.3N.sub.4 is spread on a template surface to form a laminated layer, and a composite system with a special structure is constructed. Compared with pure phase g-C.sub.3N.sub.4, the composite material substantially increases specific surface area and has a clear interface; the carbon skeleton not only functions as a rigid support, but also increases the electron transfer efficiency of the composite material, thereby improving the separation efficiency of photogenerated carriers and the utilization rate of visible light. Raw materials used in the method are inexpensive and environmentally friendly, which can be used for industrial production and bulk production of eco-friendly materials for harnessing environmental organic pollutants.

SYNTHESIS METHOD OF g-C3N4/C COMPOSITE MATERIAL BASED ON HOLLYHOCK STALK
20230201811 · 2023-06-29 ·

The present disclosure provides a synthesis method of a g-C.sub.3N.sub.4/C composite material based on a hollyhock stalk, including the following steps: (1) pretreatment of hollyhock stalks; and (2) fabrication of the g-C.sub.3N.sub.4/C composite material. In this method, with the hollyhock stalk as a carbon skeleton, g-C.sub.3N.sub.4 is spread on a template surface to form a laminated layer, and a composite system with a special structure is constructed. Compared with pure phase g-C.sub.3N.sub.4, the composite material substantially increases specific surface area and has a clear interface; the carbon skeleton not only functions as a rigid support, but also increases the electron transfer efficiency of the composite material, thereby improving the separation efficiency of photogenerated carriers and the utilization rate of visible light. Raw materials used in the method are inexpensive and environmentally friendly, which can be used for industrial production and bulk production of eco-friendly materials for harnessing environmental organic pollutants.

Heterogeneous hydrocyanation

The present invention relates to an improved process for addition of hydrogen cyanide across olefins and, in particular, to the use of a specific aluminum oxide to catalyze the reaction. The aluminum oxide catalyst must have total alkali metal and/or alkaline earth metal content, measured in the form of alkali metal oxide and/or alkaline earth metal oxide, of less than 3,000 ppm by weight.

Heterogeneous hydrocyanation

The present invention relates to an improved process for addition of hydrogen cyanide across olefins and, in particular, to the use of a specific aluminum oxide to catalyze the reaction. The aluminum oxide catalyst must have total alkali metal and/or alkaline earth metal content, measured in the form of alkali metal oxide and/or alkaline earth metal oxide, of less than 3,000 ppm by weight.

METHOD FOR PREPARING REACTIVE SEALANT RESIN

Disclosed by the present invention is a method for preparing a reactive sealant resin, the method comprising: (1) under the action of an alkali catalyst, polymerizing a hydroxyl-containing initiator with an epoxy compound to obtain a polyether polyol; (2) adding an alkoxide reagent and a halogenated end-capping agent containing a double bond to the polyether polyol obtained in step (1) for reaction, so as to obtain a crude double-bonded polyether product, and refining the crude product to obtain a modified polyether product; and (3) subjecting the modified polyether and hydrogen-containing silane to silane end-capping reaction under the action of a hydrosilylation catalyst, so as to obtain the target product, i.e., a reactive sealant resin. The resin has excellent properties as well as good adhesion and paintability.

PROCESS FOR THE PREPARATION OF EUGENOL POLYETHERS THAT CAN BE HYDROSILYLATED AND EUGENOL POLYETHERSILOXANES AND USE THEREOF

The present invention relates to a process for producing hydrosilylatable, eugenol-based polyethers, to the conversion thereof into polyether siloxanes and also to the products that may be produced by this process and to the use of said products as surfactants.

PROCESS FOR THE PREPARATION OF EUGENOL POLYETHERS THAT CAN BE HYDROSILYLATED AND EUGENOL POLYETHERSILOXANES AND USE THEREOF

The present invention relates to a process for producing hydrosilylatable, eugenol-based polyethers, to the conversion thereof into polyether siloxanes and also to the products that may be produced by this process and to the use of said products as surfactants.

DUAL CATALYST SYSTEM FOR HIGH PRIMARY HYDROXYL POLYOLS

A method of producing a high primary hydroxyl group content and a high number average molecular weight polyol includes preparing a mixture that includes a double metal cyanide catalyst and a low molecular weight polyether polyol having a number average molecular weight of less than 1,000 g/mol, the polyether polyol is derived from propylene oxide, ethylene oxide, or butylene oxide, setting the mixture to having a first temperature, adding at least one selected from propylene oxide, ethylene oxide, and butylene oxide to the mixture at the first temperature, allowing the mixture to react to form a reacted mixture, adding a Lewis acid catalyst to the reacted mixture, setting the reaction mixture including the second catalyst to have a second temperature that is less than the first temperature, and adding additional at least one selected from propylene oxide, ethylene oxide, and butylene oxide to the reacted mixture at the second temperature such that a resultant polyol having a primary hydroxyl group content of at least 60% and a number average molecular weight greater than 2,500 g/mol is formed.