Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

Disclosed is an oxidation process to produce a crude carboxylic acid product carboxylic acid product. The process comprises oxidizing a feed stream comprising at least one oxidizable compound to generate a crude carboxylic acid slurry comprising furan-2,5-dicarboxylic acid (FDCA) and compositions thereof. Also disclosed is a process to produce a dry purified carboxylic acid product by utilizing various purification methods on the crude carboxylic acid.

This application is in the field of technologies for desulfurization and demercaptanization of raw gaseous hydrocarbons (including natural gas, tail gas, technological gas, etc., including gaseous media). It can be used for simultaneous dehydration and desulfurization/demercaptanization of any kind of raw gaseous hydrocarbons.

This application is in the field of technologies for desulfurization and demercaptanization of raw gaseous hydrocarbons (including natural gas, tail gas, technological gas, etc., including gaseous media). It can be used for simultaneous dehydration and desulfurization/demercaptanization of any kind of raw gaseous hydrocarbons.

The present invention relates to a process for modifying the fluorine distribution in a hydrocarbon compound in the presence of a catalyst, characterized by the use, as catalyst, of a solid composition comprising at least one component containing chromium oxyfluoride or fluoride of empirical formula Cr.sub.xM.sub.(1-x)O.sub.rF.sub.s, where 2r+s is greater than or equal to 2.9 and less than 6, M is a metal chosen from columns 2 to 12 of the Periodic Table of the Elements, x has a value from 0.9 to 1, s is greater than 0 and less than or equal to 6 and r is greater than or equal to 0 and less than 3, the said solid composition having a crystallinity of less than 20% by weight. The present invention also relates to the solid composition per se.

The present invention relates to a process for modifying the fluorine distribution in a hydrocarbon compound in the presence of a catalyst, characterized by the use, as catalyst, of a solid composition comprising at least one component containing chromium oxyfluoride or fluoride of empirical formula Cr.sub.xM.sub.(1-x)O.sub.rF.sub.s, where 2r+s is greater than or equal to 2.9 and less than 6, M is a metal chosen from columns 2 to 12 of the Periodic Table of the Elements, x has a value from 0.9 to 1, s is greater than 0 and less than or equal to 6 and r is greater than or equal to 0 and less than 3, the said solid composition having a crystallinity of less than 20% by weight. The present invention also relates to the solid composition per se.

This application is in the field of technologies for desulfurization and demercaptanization of raw gaseous hydrocarbons (including natural gas, tail gas, technological gas, etc, including gaseous media). It can be used for simultaneous dehydration and desulfurization/demercaptanization of any kind of raw gaseous hydrocarbons.

Disclosed in the present disclosure is a method for preparing 2,3,3,3-tetrafluoropropene. The method includes a two-step method for preparing 2,3,3,3-tetrafluoropropene, a method for co-producing 2,3,3,3-tetrafluoropropene and 1-chloro-2,3,3,3-tetrafluoropropene, and a method for co-producing 2,3,3,3-tetrafluoropropene and 1-chloro-3,3,3-trifluoropropene. The two-step method for preparing 2,3,3,3-tetrafluoropropene includes: A1, a telomerization step: subjecting chlorofluoromethane and trifluoroethylene to a pressure telomerization reaction under the action of a telomerization catalyst to prepare 3-chloro-1,1,1,2-tetrafluoropropane, wherein the telomerization catalyst is a Lewis acid catalyst or a mixed catalyst of a Lewis acid catalyst and dichloromethane; and A2, a dehydrochlorination step: subjecting the 3-chloro-1,1,1,2-tetrafluoropropane to dehydrochlorination under the catalytic action of activated carbon to obtain 2,3,3,3-tetrafluoropropene. The method for preparing 2,3,3,3-tetrafluoropropene has the advantages of a simple process, high product selectivity, mild reaction conditions and the like.

Disclosed in the present disclosure is a method for preparing 2,3,3,3-tetrafluoropropene. The method includes a two-step method for preparing 2,3,3,3-tetrafluoropropene, a method for co-producing 2,3,3,3-tetrafluoropropene and 1-chloro-2,3,3,3-tetrafluoropropene, and a method for co-producing 2,3,3,3-tetrafluoropropene and 1-chloro-3,3,3-trifluoropropene. The two-step method for preparing 2,3,3,3-tetrafluoropropene includes: A1, a telomerization step: subjecting chlorofluoromethane and trifluoroethylene to a pressure telomerization reaction under the action of a telomerization catalyst to prepare 3-chloro-1,1,1,2-tetrafluoropropane, wherein the telomerization catalyst is a Lewis acid catalyst or a mixed catalyst of a Lewis acid catalyst and dichloromethane; and A2, a dehydrochlorination step: subjecting the 3-chloro-1,1,1,2-tetrafluoropropane to dehydrochlorination under the catalytic action of activated carbon to obtain 2,3,3,3-tetrafluoropropene. The method for preparing 2,3,3,3-tetrafluoropropene has the advantages of a simple process, high product selectivity, mild reaction conditions and the like.

A reactive resin composition is described, with a resin component, which contains a radical-polymerizable compound, and an initiator system, which contains an -halocarboxylic acid and a catalyst system, which comprises a nitrogen-containing ligand and Cu(0) or an inorganic Cu(I) compound, as is the use of the same for construction purposes.