Patent classifications
B01J37/0063
Catalyst composition comprising modified crystalline aluminosilicate for dehydration
Process for preparing a catalyst composition containing a modified crystalline aluminosilicate and a binder, wherein the catalyst composition comprises from 5 to 95% by weight of crystalline aluminosilicate as based on the total weight of the catalyst composition, the process being remarkable in that it comprises a step of steaming said crystalline aluminosilicate: at a temperature ranging from 100 C. to 380 C.; under a gas phase atmosphere containing from 5 wt % to 100 wt % of steam; at a pressure ranging from 2 to 200 bars; at a partial pressure of H.sub.2O ranging from 2 to 200 bars; and said steaming being performed during at least 30 min and up to 144 h;
and in that the process also comprises a step of shaping, or of extruding, the crystalline aluminosilicate with a binder, wherein the binder is selected to comprise at least 85 wt % of silica as based on the total weight of the binder, and less than 1000 ppm by weight as based on the total weight of the binder of aluminium, gallium, boron, iron and/or chromium.
Ni-containing catalyst for the oligomerization of olefins
The present invention relates to an oligomerization catalyst for oligomerization of low-molecular-weight olefins, to the use of said catalyst and to a process for oligomerization of low-molecular-weight olefins using the oligomerization catalyst according to the invention.
Process for producing an oligomerization catalyst
The invention relates to a process for producing an oligomerization catalyst comprising nickel oxide and a silicon-alumina support material, wherein the silica-alumina support material is in the ammonium form. The present invention further relates to a process for oligomerization of C3- to C6-olefins using the oligomerization catalyst produced according to the invention.
Method for producing N-methyl-p-toluidine for use as an additive for aviation gasoline
The invention relates to novel methods for preparing N-methyl-p-toluidine for the use thereof as additive for aviation fuel, and to specific catalysts for these methods.
Synthesis of nanocrystalline beta zeolite, synthesis method and use thereof in catalytic applications
The present invention relates to a new process for synthesising a crystalline material comprising structure Beta zeolite in nanocrystalline form, and which can comprise at least the following steps: (i) preparing a mixture comprising at least one source of water, at least one source of a tetravalent element Y, at least one source of a trivalent element X, at least one source of an alkali cation or alkaline earth metal cation (A), and at least one organic molecule selected from a monocyclic quaternary ammonium R.sub.1R.sub.2CycloN.sup.+, and a quaternary ammonium substituted with a cycloalkyl group R.sub.3R.sub.4R.sub.5R.sub.6N.sup.+. The molar composition of the mixture is: n X.sub.2O.sub.3:YO.sub.2:a A:m OSDA1:z H.sub.2O; ii) crystallising the mixture; and iii) recovering the crystalline material.
Process for dehydration of mono-alcohol(s) using a modified crystalline aluminosilicate
The invention relates to a process for dehydration of a mono-alcohol, or of a mixture of at least two mono-alcohols, having at least 2 carbon atoms and at most 7 carbon atoms into olefins having the same number of carbons, wherein the process uses a catalyst composition that comprises a modified crystalline aluminosilicate has an acidity between 350 and 500 mol/g that comprises, and further wherein the catalyst composition is obtained by a process comprising the steps of providing a crystalline aluminosilicate having a Si/Al framework molar ratio greater than 10; and steaming said crystalline aluminosilicate, or said shaped and/or calcined crystalline aluminosilicate at a temperature ranging from 100 C. to 380 C.; and under a gas phase atmosphere, without liquid, containing from 5 wt % to 100 wt % of steam; at a pressure ranging from 2 to 200 bars; at a partial pressure of H.sub.2O from 2 bars to 200 bars; and said steaming being performed during at least 30 min and up to 144 h.
Oligomerization catalyst and process for the production thereof
The invention relates to an oligomerization catalyst comprising nickel oxide and silica-alumina support material and to a process for oligomerization of C.sub.3- to C.sub.6-olefins using the oligomerization catalyst.
FOUR-WAY CONVERSION CATALYST HAVING IMPROVED FILTER PROPERTIES
A four-way conversion catalyst for treating a gasoline engine exhaust gas has a porous wall flow filter substrate with an inlet end, outlet end, substrate axial length extending between the inlet and outlet end, and passages defined by porous internal walls of the substrate, the passages having inlet passages with an open inlet and closed outlet, and outlet passages having a closed inlet and open outlet. The internal wall pores have a three-way conversion catalytic in-wall coating with an oxygen storage compound and a platinum group metal supported on a refractory metal oxide. On at least a portion of the internal wall surface defining the interface between the internal walls and the passages, the catalyst has a porous on-wall coating from the internal wall surface to the passage. The coating has porous oxidic compound and platinum group metal content of 0 to 0.001 wt. %, of the total coating weight.
CORE-SHELL CATALYST, PREPARATION METHOD THEREFOR AND APPLICATION THEREOF TO CATALYTIC OZONATION
The invention relates to a core-shell structured catalyst comprising a core covered with a shell, the core is made of hematite, tourmaline, germanium, maifanite or kaolin. The invention also provides a method for preparing the catalyst including mixing raw materials of the core with water to form seed-balls with a particle size of 2-4 mm; mixing the seed-balls with raw materials of the shell and water, such that the seed-balls are covered with the raw materials of the shell to form pellets with a particle size of 3-5 mm; processing the pellets at 60-90 C. and then calcining to active the pellets at 450-550 C. to obtain a core-shell structured catalyst. The invention further discloses use of the core-shell structured catalyst in the ozone oxidation reaction. In the invention, a core-shell structured catalyst with good morphology and catalytic performance is prepared, and the production cost of the catalyst is reduced.
CATALYST SYSTEM AND PROCESS FOR PREPARING DIMETHYL ETHER
The invention relates to a catalyst system and process for preparing dimethyl ether from synthesis gas as well as the use of the catalyst system in this process.