An apparatus for pretreating an ion exchange resin includes at least a stock solution tank for storing a non-aqueous solvent, an ion exchange resin container accommodating an ion exchange resin, and a moisture removal apparatus for removing moisture in the non-aqueous solvent, and at least one solution feed pipe selected from: a circulating solution feed pipe for returning, to the stock solution tank, the non-aqueous solvent that has passed through the ion exchange resin container and the moisture removal apparatus in this order from the stock solution tank; and a circulating solution feed pipe for returning, to the stock solution tank, the non-aqueous solvent that has passed through the moisture removal apparatus and the ion exchange resin container in this order from the stock solution tank.

A new catalytic metal supporting resin production method that can streamline the purification process, and an ultrapure water production method that uses the catalytic metal supporting resin production method are provided. The method for producing a resin includes first filling a single vessel with first anion exchange resin that supports a catalytic metal and second anion exchange resin that does not support a catalytic metal and then purifying together first anion exchange resin and second anion exchange resin that fill the vessel. The ultrapure water production method includes reducing the amount of hydrogen peroxide or dissolved oxygen by causing water being treated that contains hydrogen peroxide or dissolved oxygen to come into contact with an ion exchange resin that contains at least the resin and that is produced by the resin production method.

A new catalytic metal supporting resin production method that can streamline the purification process, and an ultrapure water production method that uses the catalytic metal supporting resin production method are provided. The method for producing a resin includes first filling a single vessel with first anion exchange resin that supports a catalytic metal and second anion exchange resin that does not support a catalytic metal and then purifying together first anion exchange resin and second anion exchange resin that fill the vessel. The ultrapure water production method includes reducing the amount of hydrogen peroxide or dissolved oxygen by causing water being treated that contains hydrogen peroxide or dissolved oxygen to come into contact with an ion exchange resin that contains at least the resin and that is produced by the resin production method.

A chromatographic media for separating bio-polymers, the chromatographic media having cationic exchange properties and anionic exchange properties, the chromatographic media comprising: (a) non-porous substrate particles including an organic polymer, the substrate particles having a neutral hydrophilic layer at a surface of the non-porous substrate particles, in which the neutral hydrophilic layer is configured to reduce a binding of the bio-polymers directly to the non-porous substrate particles compared to a binding of the bio-polymer to the non-porous substrate particles without the neutral hydrophilic layer; (b) a charged first ion exchange layer bound to the substrate particles on top of the hydrophilic layer, the first ion exchange layer comprising first ion exchange groups; and (c) a charged second ion exchange layer bound to the substrate particles on top of the first ion exchange layer.

An ion exchange polymer composition is provided, which includes a primary crosslinker and a secondary crosslinker. The primary crosslinker includes a crosslinked ionic monomer including a quaternary ammonium group. A method for making the ion exchange polymer composition and materials prepared from the ion exchange polymer composition are also provided.

An ion exchange membrane is provided which includes an ion exchange polymer that is partially cross-linked. The partially cross-linked ion exchange polymer will be more stable and will not be washed out over time. The ion exchange polymer may be UV or chemically cross-linked, wherein a cross-linking compound is added to the ion exchange polymer either before or after coupling to a support material. A support material may be made of, or be coated with, a cross-linking compound and the support material may initiate cross-linking proximal to the support material. The support material may be made of a material that chemically bonds with the ionomer.

An ion exchange membrane is provided which includes an ion exchange polymer that is partially cross-linked. The partially cross-linked ion exchange polymer will be more stable and will not be washed out over time. The ion exchange polymer may be UV or chemically cross-linked, wherein a cross-linking compound is added to the ion exchange polymer either before or after coupling to a support material. A support material may be made of, or be coated with, a cross-linking compound and the support material may initiate cross-linking proximal to the support material. The support material may be made of a material that chemically bonds with the ionomer.

A multi-acid monomer disclosed herein has the formula ##STR00001##
wherein R is one or more units of a non-SO.sub.2F or non-SO.sub.2Cl portion of a polymer precursor in sulfonyl fluoride or sulfonyl chloride form, X is a non-sulfonyl halide group of a multi-sulfonyl halide compound having a minimum of two acid giving groups, and Y is remaining sulfonyl halide groups of the multi-sulfonyl halide compound.

Disclosed herein are ozone reactive polymers comprising a structural repeat unit represented by the following formula XLI:

##STR00001##

wherein A is absent or a linking group selected from the group consisting of substituted or unsubstituted alkylene, substituted or unsubstituted heteroalkylene, substituted or unsubstituted cycloalkylene, substituted or unsubstituted heterocycloalkylene, substituted or unsubstituted arylene, substituted or unsubstituted heteroarylene, substituted or unsubstituted arylalkylene, and substituted or unsubstituted heteroarylalkylene; each of R.sub.1 and R.sub.2 is, independently, selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted heteroalkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted heterocycloalkyl, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, substituted or unsubstituted arylalkyl, and substituted or unsubstituted heteroarylalkyl; and wherein the structural repeat unit comprises at least 10% by weight of the polymer.

Disclosed herein are ozone reactive polymers comprising a structural repeat unit represented by the following formula XLI:

##STR00001##

wherein A is absent or a linking group selected from the group consisting of substituted or unsubstituted alkylene, substituted or unsubstituted heteroalkylene, substituted or unsubstituted cycloalkylene, substituted or unsubstituted heterocycloalkylene, substituted or unsubstituted arylene, substituted or unsubstituted heteroarylene, substituted or unsubstituted arylalkylene, and substituted or unsubstituted heteroarylalkylene; each of R.sub.1 and R.sub.2 is, independently, selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted heteroalkyl, substituted or unsubstituted cycloalkyl, substituted or unsubstituted heterocycloalkyl, substituted or unsubstituted aryl, substituted or unsubstituted heteroaryl, substituted or unsubstituted arylalkyl, and substituted or unsubstituted heteroarylalkyl; and wherein the structural repeat unit comprises at least 10% by weight of the polymer.