A catalyst composition comprising—a support comprising TiO.sub.2,—a composite oxide containing vanadium and antimony, which has a rutile-type structure different from VSbO.sub.4 and V.sub.0.92Sb.sub.0.92O.sub.4 as determined by X-ray diffraction (XRD) analysis with CuKα radiation, and—optionally, one or more selected from the group consisting of oxides of silicon, oxides of vanadium and oxides of antimony, for selective catalytic reduction of nitrogen oxides; to a process for preparing the catalyst composition, to the catalyst composition obtained/obtainable by the process and to use of the same for selective catalytic reduction of nitrogen oxides.

A catalyst composition comprising—a support comprising TiO.sub.2,—a composite oxide containing vanadium and antimony, which has a rutile-type structure different from VSbO.sub.4 and V.sub.0.92Sb.sub.0.92O.sub.4 as determined by X-ray diffraction (XRD) analysis with CuKα radiation, and—optionally, one or more selected from the group consisting of oxides of silicon, oxides of vanadium and oxides of antimony, for selective catalytic reduction of nitrogen oxides; to a process for preparing the catalyst composition, to the catalyst composition obtained/obtainable by the process and to use of the same for selective catalytic reduction of nitrogen oxides.

An object of the present invention is to provide a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutene, which enables a catalyst demonstrating favorable yield to be stably produced. According to the present invention, there is provided a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutane, comprising the steps of: (i) preparing a catalyst raw material mixture containing Mo, V and Nb and satisfying the relationships of 0.1≦a≦1 and 0.01≦b≦1 when atomic ratios of V and Nb to one atom of Mo are defined as a and b, respectively; (ii) drying the catalyst raw material mixture; and (iii) calcining a particle, in which a content of the particle having a particle diameter of 25 μm or less is 20% by mass or less and a mean particle diameter is from 35 to 70 μm, in an inert gas atmosphere.

An object of the present invention is to provide a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutene, which enables a catalyst demonstrating favorable yield to be stably produced. According to the present invention, there is provided a process for producing an oxide catalyst used in a vapor-phase catalytic oxidation or vapor-phase catalytic ammoxidation reaction of propane or isobutane, comprising the steps of: (i) preparing a catalyst raw material mixture containing Mo, V and Nb and satisfying the relationships of 0.1≦a≦1 and 0.01≦b≦1 when atomic ratios of V and Nb to one atom of Mo are defined as a and b, respectively; (ii) drying the catalyst raw material mixture; and (iii) calcining a particle, in which a content of the particle having a particle diameter of 25 μm or less is 20% by mass or less and a mean particle diameter is from 35 to 70 μm, in an inert gas atmosphere.

A bimetal oxysulfide solid-solution catalyst is provided. The bimetal oxysulfide solid-solution catalyst is represented by the following formula:
Cu.sub.xM.sup.(2).sub.yO.sub.zS.sub.γ wherein M.sup.(2) includes monovalent Silver (Ag), divalent Zinc (Zn), Manganese (Mn), Nickel (Ni), Cobalt (Co), and Tin (Sn.sup.II), trivalent Indium (In), Cerium (Ce), Antimony (Sb), and Gallium (Ga), tetravalent Tin (Sn.sup.IV), or pentavalent Molybdenum (Mo), 0<y<0.3, 0.7<x<1.0, 0<z<0.5, and 0.5<γ<1.0. In addition, a manufacturing method of the bimetal oxysulfide solid-solution catalyst and applications of the bimetal oxysulfide solid-solution catalyst are also provided.

A bimetal oxysulfide solid-solution catalyst is provided. The bimetal oxysulfide solid-solution catalyst is represented by the following formula:
Cu.sub.xM.sup.(2).sub.yO.sub.zS.sub.γ wherein M.sup.(2) includes monovalent Silver (Ag), divalent Zinc (Zn), Manganese (Mn), Nickel (Ni), Cobalt (Co), and Tin (Sn.sup.II), trivalent Indium (In), Cerium (Ce), Antimony (Sb), and Gallium (Ga), tetravalent Tin (Sn.sup.IV), or pentavalent Molybdenum (Mo), 0<y<0.3, 0.7<x<1.0, 0<z<0.5, and 0.5<γ<1.0. In addition, a manufacturing method of the bimetal oxysulfide solid-solution catalyst and applications of the bimetal oxysulfide solid-solution catalyst are also provided.

The present invention relates to a catalyst comprising at least one oxide of vanadium, at least one oxide of tungsten, at least one oxide of cerium, at least one oxide of titanium and at least one oxide of antimony, and an exhaust system containing said oxides.

The present invention relates to a catalyst comprising at least one oxide of vanadium, at least one oxide of tungsten, at least one oxide of cerium, at least one oxide of titanium and at least one oxide of antimony, and an exhaust system containing said oxides.

A method for producing a catalyst for unsaturated carboxylic acid synthesis is proposed. The method includes: obtaining a dried product by drying and heat-treating a starting material mixed liquid in which supply source compounds of respective catalyst component elements are integrated; and forming a catalyst precursor by supporting powder to be supported on a carrier in the form of a particle aggregate. The powder to be supported is either the dried product or obtained from the dried product. The method further includes calcining the catalyst precursor to form the catalyst. The mass loss rate of the powder to be supported at 300° C. is less than 5 percent by mass, and the difference between the mass loss rate of the powder at 370° C. and the mass loss rate of the powder at 300° C. is not less than 1 percent by mass and not more than 6 percent by mass.

A method for producing a catalyst for unsaturated carboxylic acid synthesis is proposed. The method includes: obtaining a dried product by drying and heat-treating a starting material mixed liquid in which supply source compounds of respective catalyst component elements are integrated; and forming a catalyst precursor by supporting powder to be supported on a carrier in the form of a particle aggregate. The powder to be supported is either the dried product or obtained from the dried product. The method further includes calcining the catalyst precursor to form the catalyst. The mass loss rate of the powder to be supported at 300° C. is less than 5 percent by mass, and the difference between the mass loss rate of the powder at 370° C. and the mass loss rate of the powder at 300° C. is not less than 1 percent by mass and not more than 6 percent by mass.