This invention relates to a multilayer coating film sequentially comprising, on a substrate, a colored coating film, an effect coating film, and a clear coating film, wherein the multilayer coating film has a lightness L*110 within a range of 60 to 90, the lightness L*110 being based on a spectral reflectance of light illuminated at an angle of 45 degrees with respect to the coating surface and received at an angle of 110 degrees with respect to the specularly reflected light; a 60-degree specular gloss within a range of 105 to 180, a graininess HG within a range of 10 to 40; and a flip-flop value within a range of 1.0 to 1.8.

The hydrophobic and corrosion resistive film of cross-linked poly(hexafluoroisopropyl methacrylate) was prepared by photopolymerization. The starting materials were a monomer of 1,1,1,3,3,3-hexafluoroisopropyl methacrylate, a photoinitiator of hydroxycyclohexyl phenyl ketone, and a cross-linker of poly(ethyleneglycol diacrylate). Photopolymerization was used to start polymerization and to cure the polymer film on an aluminum surface. Drop-casting was used to deposit the fluoropolymer onto an aluminum substrate (AA 3003). The fluoropolymer film has high corrosion protection when measured by potentiodynamic polarization and open circuit potential techniques in an aqueous solution of 3.5% NaCl. Fourier-transform infrared spectroscopy was used to monitor the polymerization process. The dynamic contact angle technique was used to measure the hydrophobicity for the fluorinated polymer coating. Thermal stability of the fluorinated polymer was measured using thermogravimetric analysis. Treatment with strong acid followed by contact angle measurements before and after the treatment confirmed the chemical resistance for the coated aluminum.

A nanosecond laser ablation and chemical thermal decomposition for preparing a super-hydrophobic micro-nano structure on stainless steel. The method solves the defects of long preparation cycle and complex process flow of a super-hydrophobic surface of stainless steel, and does not use fluorine-containing chemical reagents for modification. The method includes: ultrasonically cleaning a stainless steel sample piece in absolute ethanol and air-drying at room temperature; performing primary infrared nanosecond laser ablation on the sample piece to obtain a micro-nano structure; evenly coating a surface of the workpiece with micro-droplets of a stearic acid ethanol solution by using an ultrasonic atomizer; performing secondary infrared nanosecond laser ablation on the sample piece; and ultrasonically cleaning the sample piece with acetone, absolute ethanol, and deionized water respectively for 10 minutes to remove undecomposed stearic acid and slag, thereby obtaining a stainless steel super-hydrophobic surface with stable super-hydrophobic property and good quality.

A method of manufacturing a metal component with an anti-microbial molecular layer may comprise: disposing the metal component in a piranha solution; washing the metal component; and grafting a surface of the metal component with a Si-Quat or hybrid Si-Quat molecular layer.

A method of manufacturing an aircraft metallic faucet with an anti-microbial coating may comprise: disposing the aircraft metallic faucet in a piranha solution; washing the aircraft metallic faucet; and coating a surface of the aircraft metallic faucet with a Si-Quat based coating. A method of manufacturing an aircraft metallic faucet with a hybrid anti-microbial coating with cross-linkers may comprise: disposing the aircraft metallic faucet in a piranha solution; washing the aircraft metallic faucet; coating a surface of the aircraft metallic faucet with a hybrid Si-Quat coating with crosslinkers; and curing the hybrid Si-Quat coating at a temperature between 60° C. (140° F.) and 100° C. (212° F.).

A surface treatment agent including a compound (P) represented by R.sup.1—P(═O) (OR.sup.2) (OR.sup.3) in which R.sup.1 is an alkyl group, an alkoxy group, a fluorinated alkyl group, or an aromatic hydrocarbon group which may have a substituent, and R.sup.2 and R.sup.3 are each independently a hydrogen atom, an alkyl group, a fluorinated alkyl group, or an aromatic hydrocarbon group which may have a substituent; a compound (S) represented by R—SH . . . in which R is an alkyl group having 3 or more carbon atoms, a fluorinated alkyl group having 3 or more carbon atoms, or an aromatic hydrocarbon group which may have a substituent; and a solvent.

A uniform oleophobic or oleo- and hydrophobic film is applied to equipment used in the petroleum industry. The methods can be applied to new equipment or equipment pulled from service, with the application process being performed in a controlled environment or the field. Applicator tools for efficient delivery and application of cleaners, solvents, and films used in the coating process are also described.

A method for rendering material surfaces inert is provided. Exemplary surfaces include ceramic, metal or plastic surfaces. The method is accomplished with functionalized perfluorinated compounds for the formation of hyperhydrophobic structures on the surfaces to create inert surfaces. The inert surfaces produced or can be produced in this way have an extremely low surface energy, are resistant to deposits of substances or cells and have a very low coefficient of friction. Practical uses of the inert surfaces are also provided.

This disclosure relates to a method for obtaining superhydrophobic corrosion-resistant coatings. State-of-the-art approaches involve etching methods with elevated temperatures and/or longer duration which are complex and use high concentration of combination of acids, alkali, and salt solutions in etching process to obtain a roughness which makes it difficult to handle usage of chemicals and controlling process. The method of the present disclosure has addressed this issue by selection of optimum concentrations of combinations of one or more type of acids, oxidizing agents which are safe, easy to handle and provide better control over the process. The method of the present disclosure is easy, inexpensive, and environmentally friendly. The superhydrophobic corrosion-resistant coatings possess water contact angles greater than 151° and coating efficiency more than 85 percent arrived at by using corrosion currents from polarization studies.

A method of attaching heterogeneous materials comprising pretreating the surface of a metal plate with an aromatic compound containing a pyrogallol group to bind the pyrogallol group to the surface of the metal plate and coating the pyrogallol-group-bound metal plate with a polymer resin, thereby greatly improving the adhesive strength between the metal plate and the polymer resin.