An example of a three-dimensional printing kit includes a particulate build material including from about 80 wt % to 100 wt % metal particles based on a total weight of the particulate build material. The three-dimensional printing kit further includes a binder fluid including water and polymer particles in an amount ranging from about 1 wt % to about 40 wt % based on a total weight of the binder fluid. The polymer particles have from about 1% to about 10% of a phosphate functional group.

An example of a three-dimensional printing kit includes a particulate build material including from about 80 wt % to 100 wt % metal particles based on a total weight of the particulate build material. The three-dimensional printing kit further includes a binder fluid including water and polymer particles in an amount ranging from about 1 wt % to about 40 wt % based on a total weight of the binder fluid. The polymer particles have from about 1% to about 10% of a phosphate functional group.

A binder for an injection moulding composition including: from 40 to 55 volume percent of a polymeric base, from 35 to 45 volume percent of a mixture of waxes or a mixture of wax and palm oil, and at least 5 volume percent of at least one surfactant, wherein the polymeric base is formed of copolymers of ethylene and methacrylic or acrylic acid, copolymers of ethylene and propylene and/or maleic anhydride-grafted polypropylene, and polymers soluble in isopropyl alcohol, propyl alcohol and/or turpentine, and chosen from the group including a cellulose acetate butyrate, a polyvinyl butyral and a copolyamide, the respective quantities of the binder components being such that their sum is equal to 100 volume percent of the binder.

A binder for an injection moulding composition including: from 40 to 55 volume percent of a polymeric base, from 35 to 45 volume percent of a mixture of waxes or a mixture of wax and palm oil, and at least 5 volume percent of at least one surfactant, wherein the polymeric base is formed of copolymers of ethylene and methacrylic or acrylic acid, copolymers of ethylene and propylene and/or maleic anhydride-grafted polypropylene, and polymers soluble in isopropyl alcohol, propyl alcohol and/or turpentine, and chosen from the group including a cellulose acetate butyrate, a polyvinyl butyral and a copolyamide, the respective quantities of the binder components being such that their sum is equal to 100 volume percent of the binder.

A preparation method of cemented carbide with FeCoCu medium-entropy alloy as binding phase is provided. The preparation method includes: 1) preparing FeCoCu precursor powders by solution combustion synthesis; 2) preparing FeCoCu medium-entropy alloy powders by mechanical alloying; 3) evenly mixing the FeCoCu medium-entropy alloy powders with ultra-fine WC powders and a binder to obtain mixed powders and pressing the mixed powders into a shaped green body; 4) preparing a WC-FeCoCu cemented carbide by microwave sintering after removing the binder from the shaped green body. The preparation method reduces sintering temperature and time and obtains a new-type cemented carbide with fine grains, high hardness and good toughness while reducing the cost.

A preparation method of cemented carbide with FeCoCu medium-entropy alloy as binding phase is provided. The preparation method includes: 1) preparing FeCoCu precursor powders by solution combustion synthesis; 2) preparing FeCoCu medium-entropy alloy powders by mechanical alloying; 3) evenly mixing the FeCoCu medium-entropy alloy powders with ultra-fine WC powders and a binder to obtain mixed powders and pressing the mixed powders into a shaped green body; 4) preparing a WC-FeCoCu cemented carbide by microwave sintering after removing the binder from the shaped green body. The preparation method reduces sintering temperature and time and obtains a new-type cemented carbide with fine grains, high hardness and good toughness while reducing the cost.

The present invention relates to compositions, comprising platelet-shaped transition metal particles, wherein the number mean diameter of the platelet-shaped transition metal particles, present in the composition, is in the range of 15 nm to 1000 nm and the number mean thickness of the platelet-shaped transition metal particles, present in the composition, is in the range of 2 to 40 nm, the transition metal is selected from silver, copper, gold and palladium and the platelet-shaped transition metal particles bear a surface modifying agent of formula A-(CHR.sup.9).sub.r—R.sup.10 (V), wherein if r is 1, A is a C.sub.1-C.sub.25alkyl group substituted with one, or more fluorine atoms; a C.sub.2-C.sub.25alkenyl substituted with one, or more fluorine atoms; a C.sub.2-C.sub.25alkynyl group substituted with one, or more fluorine atoms; a C.sub.3-C.sub.20cycloalkyl group substituted with one, or more fluorine atoms; or a C.sub.6-C.sub.24aryl group substituted with one, or more fluorine atoms, CF.sub.3 or —O—CF.sub.3 groups; if r is 0, A is a C.sub.6-C.sub.24aryl group substituted with one, or more fluorine atoms, CF.sub.3 or —O—CF.sub.3 groups; or a C.sub.7-C.sub.24aralkyl group substituted with one, or more fluorine atoms, CF.sub.3 or —O—CF.sub.3 groups;

R.sup.9 is H, or a C.sub.1-C.sub.4alkyl group; and R.sup.10 is a thiol group, or an amino group.

Surface modification with fluorinated thiols/amines allows to tune the surface properties of silver nanoplatelets in such a way, as to, on the one hand, make them dispersible and colloidally stable in the finished printing ink system, and on the other hand, allow them to migrate to the substrate and print surfaces upon drying of the solvent in the printed layer.

The present disclosure relates to a binding agent for printing a 3D green body object. The binding agent includes from about 0.3 wt % to about 3 wt % multi-functional carboxylic acid having a weight average molecular weight range from about 100 MW to about 1,000 MW, from about 2 wt % to about 20 wt % a (meth)acrylic latex binder, from about 10 wt % to about 40 wt % solvent package including from about 3 wt % to about 40 wt % of a coalescing solvent, and from about 40 wt % to about 88 wt % water. The weight percentage ranges are based on total content of the binding agent.

Methods for large-scale additive manufacturing of high-strength boron nitride nanotubes (BNNT)/aluminum (Al) (e.g., reinforced Al alloy) metal matrix composites (MMCs) (BNNT/Al MMCs), as well as the BNNT/Al MMCs produced by the large-scale additive manufacturing methods, are provided. A combination of ultrasonication and spray drying techniques can produce good BNNT/Al alloy feedstock powders, which can be used in a cold spraying process.

Methods for large-scale additive manufacturing of high-strength boron nitride nanotubes (BNNT)/aluminum (Al) (e.g., reinforced Al alloy) metal matrix composites (MMCs) (BNNT/Al MMCs), as well as the BNNT/Al MMCs produced by the large-scale additive manufacturing methods, are provided. A combination of ultrasonication and spray drying techniques can produce good BNNT/Al alloy feedstock powders, which can be used in a cold spraying process.