A three-dimensional (3D) printing method and apparatus are disclosed for freeform fabrication of metal articles. 3D printed articles are formed from a build material comprising metal powder(s), polymer(s), and solvent(s). A coagulation agent, such as a nebulized non-solvent, is disposed onto/about the build material during 3D printing to cause at least partial solidification of the build material to form a green body structure. Multiple build materials can be mixed at a variable ratio to achieve a composition gradient through the green body structure. The 3D printed green body structure can be heated to remove some or all of the polymer, solvent, and/or for debinding. The debinded green body structure can be sintered at a specific sintering temperature or over a temperature gradient, for a period of time, in accordance with the sintering properties of the particular metal powder in the debinded green body structure, to form a finished metal part.

The present disclosure relates to systems and methods for treating a printed model. The methods may include placing at least a portion of the printed model into a heat treatment medium. The methods may further include performing a heat treatment on the printed model based at least in part on the heat treatment medium. The heat treatment medium may provide a constraint force to prevent a deformation of the printed model during the heat treatment. And the methods may also include obtaining a printed object based at least in part on the heat treatment performed on the printed model.

A heat-resistant alloy contains at least one element selected from a group consisting of Al, Ti, Ni, Cr, and Mo, O, and Y, and a ratio of a content of Y in terms of mass to a content of O in terms of mass is 0.5 or greater and 100 or less.

A heat-resistant alloy contains at least one element selected from a group consisting of Al, Ti, Ni, Cr, and Mo, O, and Y, and a ratio of a content of Y in terms of mass to a content of O in terms of mass is 0.5 or greater and 100 or less.

The present disclosure describes multi-fluid kits for printing three-dimensional green body objects, three-dimensional printing kits, and methods of three-dimensional printing. In one example, a multi-fluid kit for printing a three-dimensional green body object can include an adhesion promoter agent and a binder agent. The adhesion promoter agent can include water and a dihydrazide compound. The binder agent can include water, an organic co-solvent, a glycidyl compound having two or more glycidyl groups per molecule, and latex particles. The latex particles can include polymerized monomers. The polymerized monomers can include a first monomer having an acid group and a second monomer having a vinyl group and without an acid group.

The present disclosure describes multi-fluid kits for printing three-dimensional green body objects, three-dimensional printing kits, and methods of three-dimensional printing. In one example, a multi-fluid kit for printing a three-dimensional green body object can include an adhesion promoter agent and a binder agent. The adhesion promoter agent can include water and a dihydrazide compound. The binder agent can include water, an organic co-solvent, a glycidyl compound having two or more glycidyl groups per molecule, and latex particles. The latex particles can include polymerized monomers. The polymerized monomers can include a first monomer having an acid group and a second monomer having a vinyl group and without an acid group.

According to examples, an apparatus may include a processor and a memory on which are stored machine-readable instructions that when executed by the processor, cause the processor to access a 3D model of a 3D object to be fabricated and apply a deformation model to the 3D model. In some examples, the processor may generate a modified 3D model that compensates for a determined deformation of the 3D object during a sintering process for the 3D object. In some examples, the deformation model may include a densification component associated with a density of the 3D object and a deformation component associated with mechanical loads on the 3D object. The densification component may have initial state values associated with the density of the 3D object during the sintering process.

A 3D-printed reflective optic providing very high specific stiffness through the utilization of a hollow shelled design, with closed back, filled with high-stiffness internal volumetric space-filling open-cell lattice structures. High-stiffness, structurally-integrated, sacrificial structures are also included for the purposes of reduction or elimination of tooling during post-processing operations.

A 3D-printed reflective optic providing very high specific stiffness through the utilization of a hollow shelled design, with closed back, filled with high-stiffness internal volumetric space-filling open-cell lattice structures. High-stiffness, structurally-integrated, sacrificial structures are also included for the purposes of reduction or elimination of tooling during post-processing operations.

A 3D-printed reflective optic providing very high specific stiffness through the utilization of a hollow shelled design, with closed back, filled with high-stiffness internal volumetric space-filling open-cell lattice structures. High-stiffness, structurally-integrated, sacrificial structures are also included for the purposes of reduction or elimination of tooling during post-processing operations.