A neodymium-iron-boron permanent magnet, a preparation method and use thereof are disclosed. The neodymium-iron-boron permanent magnet has a composition represented by formula I: [mHR(1-m) (Pr.sub.25Nd.sub.75)].sub.x(Fe.sub.100-a-b-c-dM.sub.aGa.sub.bIn.sub.cSn.sub.d).sub.100-x-yB.sub.y formula I; where a is 0.995-3.493, b is 0.114-0.375, c is 0.028-0.125, d is 0.022-0.100; x is 29.05-30.94, y is 0.866-1.000; m is 0.02-0.05; HR is Dy and/or Tb; M is at least one selected from the group consisting of Co, Cu, Ti, Al, Nb, Zr, Ni, W and Mo.

The present disclosure discloses an yttrium (Y)-added rare-earth permanent magnetic material and a preparation method thereof. A chemical formula of the material expressed in atomic percentage is (YxRE1-x)aFebalMbNc, wherein 0.05≤x≤0.4, 7≤a≤13, 0≤b≤3, 5≤c≤20, and the balance is Fe, namely, bal=100-a-b-c; RE represents a rare-earth element Sm, or a combination of the rare-earth element Sm and any one or more elements of Zr, Nd and Pr; M represents Co and/or Nb; and N represents nitrogen. In the preparation method, the rare-earth element Y is utilized to replace the element Sm of a samarium-iron-nitrogen material. By regulating a ratio of the element Sm to the element Y, viscosity of an alloy liquid can be reduced, and an amorphous forming ability of the material is enhanced.

A polymer-assisted 3D printing method and ink compositions are used to manufacture magnetocaloric devices having many applications including in heat pumps, refrigerators, etc. The ink compositions and printing methods can produce compositionally graded, anisotropically aligned magnetocaloric architectures with designed pores and channels, to bring forth significant improvement in heat exchange efficiency.

The present invention discloses rare earth-bonded magnetic powder and a preparation method therefor. The bonded magnetic powder is of a multilayer core-shell structure, and comprises a core layer and an antioxidant layer (3), wherein the core layer is formed by RFeMB, R is Nd and/or PrNd, and M is one or more of Co, Nb, and Zr; and the core layer is coated with an iron-nitrogen layer (2). In addition, the present invention also discloses the preparation method for the rare earth-bonded magnetic powder and a bonded magnet. The oxidation and corrosion of magnetic raw powder during phosphorization and subsequent treatment process are effectively prevented, thereby further improving the long-term temperature resistance and environmental tolerance of the material.

The current invention discloses a type of micronized powder for manufacturing sintered Neodymium magnetic material, a target type jet mill pulverization method to prepare the micronized powder, and the resulting pulverized powder. The Neodymium magnet powder created under the method is of sphericity of greater than or equal to 90% and of particle adhesion rate of less than or equal to 10%. A is the diameter of the target center, B is the diameter of the side nozzle, and C is the distance between the target center and the nozzle. The relationship amongst A, B and C is A/B=m×(C/A+B), where m ranges from 1 to 7. A velocity of the jet stream from side nozzle is between about 320 m/s to about 580 m/s.

The disclosure relates to the technical field of sintered type NdFeB permanent magnets, in particular to a low-cost rare earth magnet and manufacturing method. There is provided a method of preparing a high-coercivity, sintered NdFeB magnet including cerium comprising the following steps:

(S1) Providing alloy flakes composed of R.sub.xT.sub.(1-x-y-z)B.sub.yM.sub.z;

(S2) Mixing the alloy flakes, a low melting point powder, and a lubricant, then subjecting the mixture to a hydrogen embrittlement process followed in this order by pulverizing the process product to an alloy powder by jet milling, magnetic field orientation molding of the alloy powder to obtain a blank, sintering and aging treatment the blank;

(S3) Coating a film composed of a diffusion source of formula R1.sub.xR2.sub.yH.sub.zM.sub.1-x-y-z on the sintered NdFeB magnet; and

(S4) Performing a diffusion heat treatment, followed by aging the sintered NdFeB magnet to obtain the low-cost rare earth magnet.

The disclosure relates to a method of preparing a low-heavy rare earth magnet comprising the following steps: S1, smelting and strip casting of the raw materials of a NdFeB alloy to obtain a NdFeB alloy sheets, and mechanically crushing the NdFeB alloy sheets into flaky alloy sheets; S2, mechanically mixing the flaky alloy sheets, a low melting point powder and a lubricant to obtain a mixture, followed by hydrogen absorption and dehydrogenation treatment of the mixture and jet milling of the product to obtain a NdFeB magnet powder; S3, pressing, forming and sintering the NdFeB magnet powder to obtain a sintered NdFeB magnet; S4, mechanically processing the sintered NdFeB magnet to a desired shape, and then forming a diffusion source film on the surface of the sintered NdFeB magnet; and S5, performing a diffusion process and aging to obtain the low-heavy rare earth magnet.

Disclosed in the present invention are a heavy rare earth alloy, neodymium-iron-boron permanent magnet material, a raw material, and a preparation method. The heavy rare earth alloy comprises the following components: RH: 30-100 mas %, not including 100 mas %; X, 0-20 mas %, not including 0; B: 0-1.1 mas %; and Fe and/or Co: 15-69 mas %, RH comprising one or more heavy rare earth elements in Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu, and Sc, and X being Ti and/or Zr. When the heavy rare earth alloy of the present invention is used as a sub-alloy to prepare the neodymium-iron-boron permanent magnet material, a high utilization rate of heavy rare earth is achieved, so that the coercivity can also be greatly improved while the neodymium-iron-boron permanent magnet material maintains high remanence.

The disclosure refers to a method for preparing NdFeB magnets including at least one of Ce and La. The method includes:

S1) Separately preparing flakes of alloy R1 and flakes of alloy R2 each by a strip casting process, wherein the alloy R1 includes at least one of La and Ce, but the alloy R2 does not include La and Ce;
S2) separately subjecting the flakes of alloy R1 and R2 to a hydrogen embrittlement process followed by pulverizing the process product to alloy powders by jet milling, wherein a ratio of the average particle sizes D50 of the powder of alloy R1 and R2 satisfied formula:

0.32≤R2/R1≤0.66;

S3) mixing the powder of alloy R1 and R2; and
S4) subjecting the mixed powders to molding and magnetic field orientation, cold isostatic pressing, sintering, and an annealing process.

An R-T-B series permanent magnet material, a raw material composition, a preparation method, and an application. The R-T-B series permanent magnet material comprises the following components: R: 29-31.0 wt. %, RH is greater than 1 wt. %, B: 0.905-0.945 wt. %, C: 0.04-0.15 wt. %, N: 0.1-0.4 wt. %, and Fe: 67-69 wt. %, wherein R comprises RL and RH, RL is a light rare earth element, RL comprises Nd, RH is a heavy rare earth element, a (RL.sub.1-yRH.sub.y).sub.2T.sub.17C.sub.x phase is present at the grain boundary of the R-T-B series permanent magnet material, x: 2-3, y: 0.15-0.35, and T must comprise Fe, and also comprises one or more among Co, Ti and N. The permanent magnet material retains relative high Br and Hcj under different heat treatment temperatures.