B29C48/0018

BIAXIALLY ORIENTED POLYESTER FILM AND PRODUCTION METHOD THEREFOR
20230001619 · 2023-01-05 · ·

[Problem] To provide: a biaxially oriented polyester film that exhibits excellent transparency, enables easy secondary processing such as coating and vapor deposition, provides excellent post-secondary-processing properties, and is environmentally friendly in that the film is made from polyester resins recycled from the market and society, including those from PET bottles; and a production method for such a film. [Solution] A biaxially oriented polyester film comprising a polyester resin composition containing particles and polyester resins recycled from the market and society, including those from PET bottles, the film having at least one surface that satisfies all requirements (1)-(3). (1) The number of fine projections having a height less than 3 nm per an area of 4×10-12m2 is 250-600. (2) The number of fine projections having a height not less than 3 nm per an area of 4×10-12m2 is 300-600. (3) The arithmetic average height Sa is 0.01-0.025 μm.

Co-extruded, biaxially oriented, matte HDPE films

Disclosed are compositions and methods for multilayer films, which, in one embodiment may comprise a core layer comprising at least 50 wt. % of high-density polyethylene. Further, the multilayer film may include a first skin layer comprising at least 80 wt. % of high-density polyethylene, and a second skin layer comprising either: (i) one or more low-density polyethylenes; or (ii) one or more polypropylene-based copolymers. The multilayer film may be oriented in at least one direction.

Machine Direction Oriented Polyethylene Films

This invention relates to an oriented polyethylene film comprising polyethylene having: (A) a melt flow index of 1.0 g/10 min or more, (B) a density of 0.90 g/cm.sup.3 to less than 0.940 g/cm.sup.3, (C) a g′.sub.LCB of greater than 0.8, (D) ratio of comonomer content at Mz to comonomer content at Mw is greater than 1.0, (E) ratio of comonomer content at Mn to comonomer content at Mw is greater than 1.0, and (F) a ratio of the g′.sub.LCB to the g′.sub.Zave is greater than 1.0, where the film has a 1% secant in the transverse direction of 70,000 psi or more and Dart Drop of 350 g/mil or more.

Method of making a microporous material

A method for producing a microporous material comprising the steps of: providing an ultrahigh molecular weight polyethylene (UHMWPE); providing a filler; providing a processing plasticizer; adding the filler to the UHMWPE in a mixture being in the range of from about 1:9 to about 15:1 filler to UHMWPE by weight; adding the processing plasticizer to the mixture; extruding the mixture to form a sheet from the mixture; calendering the sheet; extracting the processing plasticizer from the sheet to produce a matrix comprising UHMWPE and the filler distributed throughout the matrix; stretching the microporous material in at least one direction to a stretch ratio of at least about 1.5 to produce a stretched microporous matrix; and subsequently calendering the stretched microporous matrix to produce a microporous material which exhibits improved physical and dimensional stability properties over the stretched microporous matrix.

Polyester films and devices containing them

A thermoformable biaxially oriented coextruded polyester film comprising a copolyester base layer B, a first polyester outer layer A1 and a second polyester outer layer A2, wherein said outer layers are disposed on opposite surfaces of said base layer, and wherein: (i) said base layer B comprises a copolyester derived from terephthalic acid (TA) and a second aromatic dicarboxylic acid and one or more diol(s), wherein said second aromatic dicarboxylic acid is present in the copolyester in an amount of from about to 5 about 20 mol % of the acid fraction of the copolyester; (ii) the polyester of each of said outer layers A1 and A2 is selected from polyethylene terephthalate (PET); and (iii) the thickness of the base layer constitutes at least 90% of the total thickness of the coextruded multi-layer polyester film.

Fluorine-containing mixture material and fluorine-containing super-oleophobic microporous membrane using same as raw material, and preparation method therefor and use thereof

This disclosure provides a fluorine-containing mixture and a fluorine-containing super-oleophobic microporous membrane using the fluorine-containing mixture as a raw material, as well as preparation methods and applications for the fluorine-containing mixture and the fluorine-containing super-oleophobic microporous membrane. The fluorine-containing mixture of the present disclosure comprises, by weight percentage, the following components: Component A: 50%˜90%; Component B: 3%˜25%; Component C: 0%˜35%; Component D: 0%˜3%; wherein Component A comprises high molecular weight polytetrafluoroethylene homopolymer or copolymer dispersion resin; Component B comprises one or more fluorine-containing alkyl acrylate monomers; Component C comprises one or more fluorine-free acrylates; Component D comprises high temperature free radical initiator. There's no need to add inflammable or explosive lubricating oil, making the process highly safe; and the obtained fluorine-containing super-oleophobic microporous membrane has high waterproof, air-permeable, oil-resistant and washable performance, in line with the needs of a new generation of waterproof and air-permeable protective clothing.

Separators, batteries, systems, vehicles, and related methods

Improved battery separators, base films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of making and/or using such separators, films or membranes, batteries, cells, devices, systems, vehicles, and/or methods of enhancing battery or cell charge rates, charge capacity, and/or discharge rates, and/or methods of improving batteries, systems including such batteries, vehicles including such batteries and/or systems, and/or the like; biaxially oriented porous membranes, composites including biaxially oriented porous membranes, biaxially oriented microporous membranes, biaxially oriented macroporous membranes, battery separators with improved charge capacities and the related methods and methods of manufacture, methods of use, and the like; flat sheet membranes, liquid retention media; dry process separators; biaxially stretched separators; dry process biaxially stretched separators having a thickness range between about 5 μm and 50 μm, preferably between about 10 μm and 25 μm, having improved strength, high porosity, and unexpectedly and/or surprisingly high charge capacity, such as, for example, high 10 C rate charge capacity; separators or membranes with high charge capacity and high porosity, excellent charge rate and/or charge capacity performance in a rechargeable and/or secondary lithium battery, such as a lithium ion battery, for high power and/or high energy applications, cells, devices, systems, and/or vehicles, and/or the like; single or multiple ply or layer separators, monolayer separators, trilayer separators, composite separators, laminated separators, co-extruded separators, coated separators, 1 C or higher separators, at least 1 C separators, batteries, cells, systems, devices, vehicles, and/or the like; improved microporous battery separators for secondary lithium batteries, improved microporous battery separators with enhanced or high charge (C) rates, discharge (C) rates, and/or enhanced or high charge capacities in or for secondary lithium batteries, and/or related methods of manufacture, use, and/or the like, and/or combinations thereof are disclosed or provided.

Low Haze Fluoropolymer Film and Method of Making

An ETFE film that has a haze value of 2% or less, and preferably 1% or less, which advantageously may have a thickness greater than 150 pm, and preferably In the range of 200 pm to 300 pm, A film of ETFE, as received from the manufacturer, is stretched under special processing conditions to produce a processed (or final) film having an area stretch factor (Ax) greater than about 1.6. Ax —Initial film thickness/film thickness after stretching. However, it is important that the initial film thickness has a starting thickness of at least 400 pm, and preferably at least 500 pm. Processing conditions Include, in some embodiments, pre-beating and heating during stretching, and post-stretching annealing If the film is stretched in a 2.5×1 or a 4×1 ratio, at a processing temperature in THV range of 130° C. to 150° C., the haze of the resulting film can be reliably brought down to less than 2%. We have also found that this low haze value is not dependent on whether the larger stretch {e.g., 2,5× or 4×) is in the machine direction (MD) or the transverse direction (TD) of the extruded film. Annealing the stretched film decreases the film shrinkage to almost 0%.

METHODS AND SYSTEMS FOR MEASUREMENT AND CONTROL OF CIRCUMFERENTIAL LAYER DISTRIBUTION IN BLOWN FILMS

A sensing system for measurement of a multilayered blown polymeric film. A feedblock supplies polymeric material streams to an annular blown film die to form a plurality of layers of different polymeric materials. A sensing system is positioned adjacent to a film bubble extruded from the blown film die, wherein the blown film bubble includes annular layers of at least two different polymeric materials. The sensing system emits a signal toward selected circumferential positions around the film bubble and receives a plurality of reflected signals at each circumferential position. Each reflected signal in the plurality of reflected signals is generated at an interface between annular layers that includes a refractive index change detectable by the sensing system. A processor processes the reflected signals from the sensing system, and for each circumferential position determines a layer thickness profile for each polymeric material in the film.

Thermoplastic polyurethane fiber and method for producing the same

The present invention relates to a thermoplastic polyurethane fiber and a method for producing the same. A thermoplastic polyurethane material is firstly provided and subjected to a molten extruding process to form a fiber material. Next, an extension process is performed to the fiber material to obtain the thermoplastic polyurethane fiber of the present invention. The thermoplastic polyurethane fiber has a lower thermal shrinking property, thereby meeting requirements of the application.