A composite film having a high dielectric permittivity engineered particles dispersed in a high breakdown strength polymer material to achieve high energy density.

A moisture vapor permeable, water impermeable composite sheet material is provided which is suitable for use as a housewrap material, and is also useful for other applications such as tarpaulins, or as covers for automobile, boats, patio furniture or the like. The composite sheet material includes a nonwoven substrate and an extrusion-coated polyolefin film layer overlying one surface of the substrate. The nonwoven substrate is comprised of polymeric fibers randomly disposed and bonded to one another to form a high tenacity nonwoven web. The nonwoven substrate has a grab tensile strength of at least 178 Newtons (40 pounds) in at least one of the machine direction (MD) or the cross-machine direction (CD). The extrusion coated polyolefin film layer is intimately bonded to the nonwoven substrate. The film layer has micropores formed therein to impart to the composite sheet material a moisture vapor transmission rate (MVTR) of at least 35 g/m.sup.2/24 hr. at 50% relative humidity and 23° C. and a hydrostatic head of at least 55 cm. In one embodiment, the nonwoven substrate comprises a spunbonded nonwoven fabric formed of randomly disposed substantially continuous polypropylene filaments. The spunbonded nonwoven fabric is an area bonded fabric in which the filaments are bonded to one another throughout the fabric at locations where the randomly disposed filaments overlie or cross one another.

Provided is a molded article comprising a resin, wherein the resin comprises a methacrylic resin comprising a structural unit derived from a methacrylic acid ester and a structural unit derived from a silica particle having an average primary particle diameter of 1 nm or more and 50 nm or less and comprising at least one polymerizable functional group, and the molded article has an absolute value of degree of orientation in the thickness direction of 0.02 or more and satisfies the requirement (I): (I) When the free induction decay curve (X) obtained by measuring the molded article by a solid echo method at 150° C. using a pulse nuclear magnetic resonance measurement apparatus is approximated by the least square method using the formula (F1), the sum (B+C) of the component fractions of two components having different spin-spin relaxation times in the free induction decay curve (X) is 4% or more.

The invention relates to a shrink label. According to an embodiment the shrink label comprises an uniaxially oriented multilayer face film comprising skin layers including polyethylene polymer(s) and at least two cyclic polymers comprising different glass transition temperatures between 30 and 100° C. and the difference between the glass transition temperatures being between 5 and 60° C., and wherein the multilayer face film is seamed by a solvent. The invention further relates to a method for providing a shrink label, use of the shrink label, method for providing a shrink label and method for labelling.

The invention relates to a shrink label. According to an embodiment the shrink label comprises an uniaxially oriented multilayer face film comprising skin layers including polyethylene polymer(s) and at least two cyclic polymers comprising different glass transition temperatures between 30 and 100° C. and the difference between the glass transition temperatures being between 5 and 60° C., and wherein the multilayer face film is seamed by a solvent. The invention further relates to a method for providing a shrink label, use of the shrink label, method for providing a shrink label and method for labelling.

The invention relates to thermoforming plant and their transport chains. Various aspects of the chain and chain rails are proposed. Overall the chain operates such that less wear occurs; it can also be cooled symmetrically and the film can be better heated up to the edges.

PLA polymers that can be expanded into microporous articles having a node and fibril microstructure are provided. The fibrils contain PLA polymer chains oriented with the fibril axis. Additionally, the PLA polymers have an inherent viscosity greater than about 3.8 dL/g and a calculated molecular weight greater than about 150,000 g/mol. The PLA polymer article may be formed by bulk polymerization where the PLA bulk polymer is made into a preform that is subsequently expanded at temperatures above the glass transition temperature and below the melting point of the PLA polymer. In an alternate embodiment, a PLA polymer powder is lubricated, the lubricated polymer is subjected to pressure and compression to form a preform, and the preform is expanded to form a microporous article. Both the preform and the microporous article are formed at temperatures above the glass transition temperature and below the melting point of the PLA polymer.

Provided are oriented biodegradable thermoplastic polyurethane films. The films may be prepared by extruding and drawing biodegradable polyurethane films. The polyurethanes may be prepared from biodegradable polyols and/or biodegradable chain extenders. The films possess high tensile strength yet are degradable under biological conditions. The films may be utilized in the fabrication of devices, particularly implantable medical devices.

A stretch-modified elastomeric multilayer film comprising a core layer comprising a first ethylene-α-olefin block copolymer, wherein the first ethylene-α-olefin block copolymer comprises at least 50 mol. % ethylene, has a melt index (12) from 0.5 g/10 min to 5 g/10 min, and has a density of 0.850 g/cc to 0.890 g/cc, and at least one outer layer independently comprising a second ethylene-α-olefin block copolymer and from 2.5 to 30 wt. % of an antiblock agent, wherein the second ethylene-α-olefin block copolymer comprises at least 50 mol. % ethylene, has a melt index (12) from 0.5 g/10 min to 25 g/10 min, and has a density of 0.850 g/cc to 0.890 g/cc, wherein the density of the first ethylene-α-olefin block copolymer is equal to or greater than the density of the second ethylene-α-olefin block copolymer.

A stretch-modified elastomeric multilayer film comprising a core layer comprising a first ethylene-α-olefin block copolymer, wherein the first ethylene-α-olefin block copolymer comprises at least 50 mol. % ethylene, has a melt index (12) from 0.5 g/10 min to 5 g/10 min, and has a density of 0.850 g/cc to 0.890 g/cc, and at least one outer layer independently comprising a second ethylene-α-olefin block copolymer and from 2.5 to 30 wt. % of an antiblock agent, wherein the second ethylene-α-olefin block copolymer comprises at least 50 mol. % ethylene, has a melt index (12) from 0.5 g/10 min to 25 g/10 min, and has a density of 0.850 g/cc to 0.890 g/cc, wherein the density of the first ethylene-α-olefin block copolymer is equal to or greater than the density of the second ethylene-α-olefin block copolymer.