A method of forming a three-dimensional object of polyurethane, polyurea, or copolymer thereof is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including at least one of: (i) a blocked or reactive blocked prepolymer, (ii) a blocked or reactive blocked diisocyante, or (iii) a blocked or reactive blocked diisocyanate chain extender; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the chain extender; and then (d) heating or microwave irradiating the three-dimensional intermediate sufficiently to form from the three-dimensional intermediate the three-dimensional object of polyurethane, polyurea, or copolymer thereof.

A method of forming a component of a vehicle heating, ventilation, and air-conditioning system from polymeric material includes providing a molding system including at least one mold cavity defining the component. A base resin is introduced to the mold system via an inlet. A chemical foaming agent is blended with the base resin to form a composition. The composition is then further heated and blended under pressure, wherein the chemical foaming agent decomposes within the composition. The composition is introduced to the mold cavity, wherein a reduced minimized pressure of the mold cavity facilitates initiation of a nucleation of the composition, wherein the composition expands to fill the mold cavity.

A method of forming a three-dimensional object of polyurethane, polyurea, or copolymer thereof is carried out by: (a) providing a carrier and an optically transparent member having a build surface, the carrier and the build surface defining a build region therebetween; (b) filling the build region with a polymerizable liquid, the polymerizable liquid including at least one of: (i) a blocked or reactive blocked prepolymer, (ii) a blocked or reactive blocked diisocyanate, or (iii) a blocked or reactive blocked diisocyanate chain extender; (c) irradiating the build region with light through the optically transparent member to form a solid blocked polymer scaffold and advancing the carrier away from the build surface to form a three-dimensional intermediate having the same shape as, or a shape to be imparted to, the three-dimensional object, with the intermediate containing the chain extender; and then (d) heating or microwave irradiating the three-dimensional intermediate sufficiently to form from the three-dimensional intermediate the three-dimensional object of polyurethane, polyurea, or copolymer thereof.

Insulating unit are disclosed which are prepared by a cavity-filling, fast-gelling rigid polyurethane foam based on a formulation comprising a polyol component which contains at least 5 weight percent of an amine-initiated polyols and 1.4 to 4 parts by weight of a catalyst package whereby the catalyst package contains at least one amine catalyst and the weight percent nitrogen present in the amine-initiated polyol to weight percent nitrogen present in the catalyst system is from 2 to 8. The formulation is injected into the cavity and the pressure in the cavity is subjected to reduced atmospheric pressure to achieve the rigid foam having a thermal conductivity of less than about 19 mW/mK at 10 C. average plate temperature.

An ultra-light polyurethane artificial leather composition comprises a one-component type blocked polyurethane high solid resin of 100 parts per weight, a capsule-type hollow microsphere of 1 to 10 parts per weight, a curing agent of 1 to 10 parts per weight, and a high solid type toner of 1 to 20 parts per weight.

A formulation for producing a polymeric material including polypropylene, a chemical blowing agent, and optional components as described.

A method of forming a composite vehicle components (e.g. walls, floor, roof) having interleaved foam core members and pre-pultruded reinforcing pillars by pultruding the cores and pillars into a vehicle component (e.g. bus sidewall formed as integral component front to rear) and cutting apertures therein for insertion of vehicle accessories (e.g. windows). Also, vehicle components can be formed having interlocking profiled edges where a first component is inserted into a second component, and rotated to bring the two components into locking engagement. A plurality of components can be formed with the same geometry, and oriented 180 degrees offset from each other to bring their profiled edges adjacent to each other.

Methods, systems, and apparatuses of manufacturing an automotive interior trim panel are provided. The method includes providing a mold having a negative side and a positive side, heating the mold using a first heater and a second heater, coupling the mold to a first powder box containing a first polymeric powder, molding a first polymer layer on the first side of the mold by rotating the mold, coupling the mold to a second powder box containing a second polymeric powder, and molding a second polymer layer on the first polymer layer by rotating the mold. The method further includes heating the second polymer layer during which the second polymer layer expands, compressing the thickness of the second polymer layer, cooling the positive side of the mold to reduce the temperature of the first polymer layer and the second polymer layer, and removing the part from the mold.

A steering wheel includes a core and a foamed polyurethane coating that covers a ring section of the core. The foamed polyurethane coating is formed by foam molding of a polyurethane material containing 91 parts by mass of a base polyol, 10 to 25 parts by mass of a pigment, 1 to 3 parts by mass of a benzotriazole ultraviolet absorber, 0.8 to 2.5 parts by mass of a hindered amine photostabilizer, and a polyisocyanate. A total amount of the ultraviolet absorber and the photostabilizer is 2.7 parts by mass or more. The foamed polyurethane coating is in the form of an integral skin foam including a highly foamed core foam and a lowly foamed skin layer. The surface of the skin layer is not provided with a coating film formed from a coating material, and serves as a product surface that assumes a color of the pigment.

A method of forming a three-dimensional object is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.