Provided herein are methods of making (meth)acrylate blocked polyurethanes with zirconium catalysts, dual cure resins containing (meth)acrylate blocked polyurethanes and zirconium catalysts, methods of using the same in additive manufacturing, and products made therefrom.

An improved pipe liner and associated methods, including a method of manufacturing the improved pipe liner and a method of lining a host pipe with such a pipe liner. The invention solves the problem of gas permeation through a polymer liner in hydrocarbon service which can result in corrosion of the host pipe and can also cause liner collapse. Corrosion occurs due to contact between corrosive species and the host pipe itself. Gases (307) can also accumulate in an annulus between or within the liner (305) and the host pipe (303) and expand during operational de-pressurisation of the pipeline, causing collapse of the liner. The improved pipe liner comprises a barrier layer (311), which prevents permeation through the liner, surrounding an inner polymer pipe (305A) and optionally covered by an outer polymer pipe (305B). The inner polymer pipe is porous which permits free movement of gas between the internal bore (302) of a lined pipe and the barrier layer, so as to prevent accumulation of gases anywhere in the lined pipe, while ensuring that gases do not permeate to, and damage, the host pipe. The liner can be inserted using Swagelining, roll-down, or any other suitable close-fit lining techniques, without compromising the effectiveness of the barrier layer.

In order to prevent degradation of appearance, prevent a decrease in flexibility, and improve non-elasticity in a non-stretchable region in an elastic film stretchable structure, the invention is characterized by having an elastic film stretchable structure (20X) formed by stacking an elastic film (30) between a first sheet layer (20A) and a second sheet layer (20B), wherein a region having the elastic film stretchable structure (20X) includes a non-stretchable region (70) and a stretchable region (80) provided at least at one side of the non-stretchable region (70) in a stretching and contracting direction, the stretchable region (80) being stretchable in the stretching and contracting direction, the first sheet layer (20A) and the second sheet layer (20B) are joined via through holes (31) penetrating the elastic film (30) at the large number of sheet bond portions (40) arranged at intervals, and the non-stretchable region (70) does not have a section in which the elastic film (30) linearly continues along the stretching and contracting direction, due to presence of the through holes (31), even though the elastic film (30) continues in the stretching and contracting direction.

The use of PEKK for lowering the CO.sub.2 and H.sub.2S permeability of a part intended to enter into contact with a petroleum effluent. Also, a pipe for transporting a petroleum effluent, including a layer intended to be in contact with the petroleum effluent, wherein the layer intended to be in contact with the petroleum effluent comprises PEKK and has a CO.sub.2 permeability at 130° C. of less than 10.sup.−8 cm.sup.3, for a thickness of 1 cm and a surface area of 1 cm.sup.2 and per second and bar of CO.sub.2 pressure and/or an H.sub.2S permeability at 130° C. of less than 10.sup.−8 cm.sup.3 for a thickness of 1 cm and a surface area of 1 cm.sup.2 and per second and bar of H.sub.2S pressure, the amount of CO.sub.2 and H.sub.2S being measured by GC, respectively. Lastly, a number of methods for manufacturing such a pipe.

A mold for encapsulating an electrical component. The mold includes an encapsulation chamber and an air inlet. The encapsulation chamber is defined by a housing, an open top, and a solid bottom. The housing includes a solid outer wall, a permeable inner wall, and an air chamber between the solid outer wall and the inner wall. The air inlet is configured to introduce a gas into the air chamber. The encapsulation chamber is sized and shaped to receive the electrical component while leaving a gap for the introduction of encapsulant around the electrical component. The encapsulant may be silicone rubber. To remove an encapsulated electrical component, pressurized air may be introduced through the air inlet into the air chamber, passing through the permeable inner wall, separating the outer surface of the encapsulant from the housing, and allowing the combination casting to be removed from the mold.

This invention generally relates to polyethylene or ethylene/α-olefin copolymer based co-extruded, multi-layer films or sheets—rigid or flexible—for thermoforming into shaped containers such as packaging containers. Inter alia, the rigid films have improved barrier properties, toughness, and snapability. Particularly, the films of the present invention comprise one or more stacks of polypropylene layers. In one embodiment, the polypropylene layers in the stack are provided such that any two adjacent layers have different microstructures that provide a interface or interphase between the two layers with likely different microstructures and/or crystallinity. The overall polypropylene stack structure assists in disrupting the transport of oxygen, thereby providing a laminate or structure, for example a rigid film or sheet, with enhanced oxygen-barrier properties. The invention also relates a process for preparing shaped articles such as containers from such films, and to such shaped articles—rigid or flexible—both filled and unfilled.

A composite material for gas capture including CO.sub.2 capture and capture of other gases. The composite material includes solid or liquid reactive material, filler material, and a gas-permeable polymer coating such that the reactive material forms micron-scale domains in the filler material.

A composite material for gas capture including CO.sub.2 capture and capture of other gases. The composite material includes solid or liquid reactive material, filler material, and a gas-permeable polymer coating such that the reactive material forms micron-scale domains in the filler material.

A method of forming a three-dimensional object, is carried out by (a) providing a carrier and a build plate, the build plate comprising a semipermeable member, the semipermeable member comprising a build surface with the build surface and the carrier defining a build region therebetween, and with the build surface in fluid communication by way of the semipermeable member with a source of polymerization inhibitor; (b) filling the build region with a polymerizable liquid, the polymerizable liquid contacting the build surface, (c) irradiating the build region through the build plate to produce a solid polymerized region in the build region, while forming or maintaining a liquid film release layer comprised of the polymerizable liquid formed between the solid polymerized region and the build surface, wherein the polymerization of which liquid film is inhibited by the polymerization inhibitor; and (d) advancing the carrier with the polymerized region adhered thereto away from the build surface on the build plate to create a subsequent build region between the polymerized region and the build surface while concurrently filling the subsequent build region with polymerizable liquid as in step (b). Apparatus for carrying out the method is also described.

A method of making an object on a bottom-up stereolithography apparatus is provided. The apparatus includes a light source, a drive assembly, and a controller operatively associated with the light source and the drive assembly, with the light source and/or the drive assembly having at least one adjustable parameter that is adjustable by the controller. The method includes installing a removable window cassette on the apparatus in a configuration through which the light source projects, the window cassette comprising an optically transparent member having a build surface on which an object can be produced, and with the optically transparent member having and at least one variable property therein; and then modifying the at least one adjustable parameter by the controller based on the at least one variable optical property of the window; and then producing the object on the build surface from a light-polymerizable liquid by bottom-up stereolithography.