An epoxy dual cure resin useful for additive manufacturing of three-dimensional objects includes: (i) a photoinitiator; (ii) monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light; (iii) optionally, a light absorbing pigment or dye; (iv) an epoxy resin; (v) optionally, but in some embodiments preferably, an organic hardener co-polymerizable with the epoxy resin; (vi) optionally but preferably a dual reactive compound having substituted thereon a first reactive group reactive with said monomers and/or prepolymers that are polymerizable by exposure to actinic radiation or light, and a second reactive group reactive with said epoxy resin (e.g., an epoxy acrylate); (vii) optionally a diluent; (viii) optionally a filler; and (ix) optionally, a co-monomer and/or a co-prepolymer. Methods of using the same in additive manufacturing are also described.

Embodiments herein include compositions, extruded articles, and methods of making the same. In an embodiment, an extruded article is included. The extruded article can include an extruded segment comprising a first composition. The first composition can include a polymer resin, an impact modifier and fibers. In some embodiments, the extruded segment can have a surface exhibiting an average depression depth of less than 0.0045 inches (0.1143 mm). Other embodiments are also included herein.

Disclosed are reinforced structures. The structures are comprised of reinforced elements that have continuous fibers embedded in a matrix material. The reinforced elements are combined in a matrix material to form a desired shape of reinforced structure.

A photocurable resin composition is provided that is suitable for use in stereolithography, comprising from about 2 weight percent to about 75 weight percent of a fluoropolymer, particularly poly(1,1-difluoroethylene), or an aromatic engineering thermoplastic polymer, a sulfur-based engineering thermoplastic polymer, a fluorine-based engineering thermoplastic polymer, or a commodity thermoplastic polymer. Also provided is a process for making three dimensional objects from successive layers of the photocurable resin composition described herein.

A method of layerwise fabrication of a three-dimensional object is disclosed. The method comprises, for each of at least a few of the layers: dispensing at least a first modeling formulation and a second modeling formulation to form a core region using both the first and the second modeling formulations, and at least one envelope region at least partially surrounding the core region using one of the first and the second modeling formulations but not the other one of the first and the second modeling formulations. The method can also comprise exposing the layer to curing energy. The first modeling formulation is characterized, when hardened, by heat deflection temperature (HDT) of at least 90° C., and the second modeling formulation is characterized, when hardened, by Izod impact resistance (IR) value of at least 45 J/m.

Described herein are resilient floor coverings produced by using digitally printed UV-cured inks and exhibiting high adhesion properties between an ink layer and a wear layer. Also described herein are methods for manufacturing same. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.

Disclosed is a friction-reducing and anti-wear composite material for a wading kinematic pair and a method of preparing the same. The friction-reducing and anti-wear composite material is prepared from carbon fiber (CF) among inorganic fillers, polyimide (PI) and polyether ether ketone (PEEK). These three materials are wet-mixed, dried and placed in a mold followed by curing by a heat press. The cured product is cooled and demolded to obtain the CF/PI/PEEK friction-reducing and anti-wear composite material for a wading kinematic pair. Tribological properties of the PEEK material are enhanced due to synergistic effect arising from hybrid organic-inorganic filling. The friction-reducing and anti-wear composite material provided in the invention has significantly reduced friction coefficient and wear volume loss under the seawater environment.

The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer including a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.01 to about 0.5 equivalent of at least one polyol having at least 3 hydroxyl groups; and (b) about 0.1 to about 1.0 equivalent of at least one polyol having at least 3 hydroxyl groups; compositions, coatings and articles made therefrom and methods of making the same.

The present invention provides an impact-absorbing member having a hollow-structured impact-absorbing section comprising an outer cylinder section and a hollow section, wherein the outer cylinder section includes a thermoplastic resin and carbon fibers having a weight-average fiber length of 1 mm to 100 mm, and throughout the entire periphery of the outer cylinder part, there is an annular region where the carbon fibers are dispersed in an in-plane direction and there is no bonding portion such as a welded surface; therefore, there is no breaking starting point when impact is borne and the impact absorption ability is stable.

The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer including a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.01 to about 0.5 equivalent of at least one polyol having at least 3 hydroxyl groups; and (b) about 0.1 to about 1.0 equivalent of at least one polyol having at least 3 hydroxyl groups; compositions, coatings and articles made therefrom and methods of making the same.