This patent document discloses physical documents including metameric ink pairs. One claim recites a document comprising: a first surface; a second surface, in which the first surface comprises a first set of print structures and a second set of print structures, in which the first set of print structures and the second set of print structures collective convey an encoded signal discernable from optical scan data representing at least a first portion of the first surface, in which the first set of print structures is provided on the first surface with a first ink and the second set of print structures is provided on the first surface with a second, different ink, and in which the first ink and the second, different ink comprise a metameric pair. Of course, other claims and combinations are described as well.

A security element for manufacturing value documents has a structure including first and second motifs which change their appearance when the security element is tilted over a tilting angle range. The structure has first micro-elements, which are arranged with a first pattern and a first motif, and second micro-elements, which are arranged with a second pattern and a second motif. The first and second patterns are nested within each other on an areal region of the security element and have different visual appearances according to the tilting of the securing element.

A security element for manufacturing value documents has a structure including first and second motifs which change their appearance when the security element is tilted over a tilting angle range. The structure has first micro-elements, which are arranged with a first pattern and a first motif, and second micro-elements, which are arranged with a second pattern and a second motif. The first and second patterns are nested within each other on an areal region of the security element and have different visual appearances according to the tilting of the securing element.

A method for forming an optical device and an optical device, wherein upon illumination, exhibits diffractive images dependent upon viewing angle, the device having a diffractive structure including grating regions, each region corresponding to a component of a respective diffractive image, wherein: each region of the diffractive structure includes grating elements along a first direction having a principal orientation component within the device plane that is substantially orthogonal to the first direction; wherein, the grating elements within each grating region have a constant pitch and the same orientation wherein each grating region, upon illumination, exhibits a diffractive color wherein the corresponding diffractive image is exhibited; wherein, the diffractive structure includes first and second grating regions elongated along a common first direction, the regions being adjacent along the first direction, and wherein the pitch and/or orientation of the grating elements of the first and second grating regions are different.

A method for forming an optical device and an optical device, wherein upon illumination, exhibits diffractive images dependent upon viewing angle, the device having a diffractive structure including grating regions, each region corresponding to a component of a respective diffractive image, wherein: each region of the diffractive structure includes grating elements along a first direction having a principal orientation component within the device plane that is substantially orthogonal to the first direction; wherein, the grating elements within each grating region have a constant pitch and the same orientation wherein each grating region, upon illumination, exhibits a diffractive color wherein the corresponding diffractive image is exhibited; wherein, the diffractive structure includes first and second grating regions elongated along a common first direction, the regions being adjacent along the first direction, and wherein the pitch and/or orientation of the grating elements of the first and second grating regions are different.

A micro-optic device, including: a substrate; a plurality of image elements; and a plurality of focusing elements, each focusing element focuses light towards, or causes light to be diverged from or constructively interfere at a real or imaginary focal point, the focusing elements causing the image elements to be sampled so as to project imagery which is observable to a user from at least a first viewing angle, wherein a first focusing structure including at least a first group of the focusing elements and a first imagery structure including at least a first group of the image elements are integrated into a first unitary structure on a first side of the substrate.

A micro-optic device, including: a substrate; a plurality of image elements; and a plurality of focusing elements, each focusing element focuses light towards, or causes light to be diverged from or constructively interfere at a real or imaginary focal point, the focusing elements causing the image elements to be sampled so as to project imagery which is observable to a user from at least a first viewing angle, wherein a first focusing structure including at least a first group of the focusing elements and a first imagery structure including at least a first group of the image elements are integrated into a first unitary structure on a first side of the substrate.

A security device includes a diffractive structure, including grating elements and having a first area, the grating elements within a region have a constant pitch or spacing; the first area regions pitches or spacings increase from one region to the next between a first region having a grating element pitch or spacing of less than or equal to 0.6 microns and an end region having a grating element pitch or spacing of greater than or equal to 5 microns; upon illumination and viewing along a first viewing direction substantially orthogonal to the first axis, the device exhibits a first optical effect in that at least one region exhibits a diffractive colour; each region has at least first and second sub-regions having different grating element orientations within the plane of the device such that the first optical effect is exhibited at more than one angle of tilt about the second axis.

A security device includes a diffractive structure, including grating elements and having a first area, the grating elements within a region have a constant pitch or spacing; the first area regions pitches or spacings increase from one region to the next between a first region having a grating element pitch or spacing of less than or equal to 0.6 microns and an end region having a grating element pitch or spacing of greater than or equal to 5 microns; upon illumination and viewing along a first viewing direction substantially orthogonal to the first axis, the device exhibits a first optical effect in that at least one region exhibits a diffractive colour; each region has at least first and second sub-regions having different grating element orientations within the plane of the device such that the first optical effect is exhibited at more than one angle of tilt about the second axis.

The present invention relates to metal oxide nanoparticles, a method for their production, a coating, or printing composition, comprising the metal oxide nanoparticles and the use of the composition for coating of surface relief micro- and nanostructures (e.g. holograms), manufacturing of optical waveguides, solar panels, light outcoupling layers for display and lighting devices and anti-reflection coatings. Holograms are bright and visible from any angle, when coated, or printed with the composition, comprising the metal oxide nanoparticles.