Provided are a micro-porous hybrid film and a method for preparing the same, and more particularly, a micro-porous hybrid film capable of improving reliability of a battery by simultaneously improving thermal stability at a high temperature and water properties, and a method for preparing the same. In addition, the present invention relates to a micro-porous hybrid film suitable for a separator of a high capacity/high output lithium secondary battery capable of increasing production stability, long term stability, and performance of the battery by improving adhesive force between a micro-porous film and a coating layer and permeability and minimizing a water content by the coating layer.

A battery according to the invention includes, as a separator, a first separator and a second separator having mutually different characteristics. The first separator and the second separator are disposed inside an electrode assembly in a state where the separators are not in contact with each other in a stacking direction of the electrode assembly. The first separator and the second separator have the following characteristic: when the battery is constructed including an electrode assembly formed by stacking the positive electrode, the first separator and the negative electrode, a resistance increase rate X=Delta X/Delta P satisfies X>0 (positive value), X being evaluated from a change amount Delta P of surface pressure applied in the stacking direction of the electrode assembly and a resistance increment Delta X of the battery upon application of the surface pressure change amount Delta P, and when the battery is constructed including an electrode assembly formed by stacking the positive electrode, the second separator and the negative electrode, a resistance increase rate Y=Delta Y/Delta P satisfies Y<0 (negative value), Y being evaluated from a change amount Delta P of surface pressure applied in the stacking direction of the electrode assembly and a resistance increment Delta Y of the battery upon application of the surface pressure change amount Delta P.

An energy storage device (battery) includes an electrode assembly having current collecting tabs, each of which is formed of a plurality of projecting portions, projecting from a first straight line portion on one side in a stacking direction of electrode sheets. The electrode assembly is housed in a case (exterior body). The energy storage device further includes current collectors, which are electrically connected to the external terminals, disposed on the case. The current collectors, are connected to the current collecting tabs, arranged in a stacking direction of the electrode sheets, on a second straight line portion side where the projecting portions, are not formed.

The present disclosure provides a heat-diffusible separator including a separator, and a porous heat transfer film formed on at least one surface of the separator.

An electrochemical compressor utilizes a working fluid having a proton associable component, such as ammonia. Water may be reacted on a anode to form protons that are transported through an ion conducting membrane to the cathode side of the electrochemical compressor. The proton associable component of the working fluid will be pulled through the ion conducting membrane along with the proton. The ion conducting membrane may include perfluorosulfonic acid ionomer, polystyrene sufonic acid ionomer and/or carboxymethyl cellulose.

A lithium ion battery includes a positive and a negative electrode, and a nanoporous or microporous polymer separator soaked in electrolyte solution and disposed between the electrodes. At least two different chelating agents are included and selected to complex with: i) two or more different transition metal ions; ii) a transition metal ion in two or more different oxidation states; or iii) both i) and ii). The at least two different selected chelating agents are to complex with transition metal ions in a manner sufficient to not affect movement of lithium ions across the separator during operation of the battery. The chelating agents are: dissolved or dispersed in the electrolyte solution; grafted onto the polymer of the separator; attached to the binder material of the negative and/or positive electrode; disposed within pores of the separator; coated on a surface of the separator; and/or coated on a surface of an electrode.

A lithium ion battery includes positive and negative electrodes, and a nanoporous or microporous polymer separator soaked in an electrolyte solution, between the positive electrode and the negative electrode. Chelating agent(s) are included to complex with transition metal ions while not affecting movement of lithium ions across the separator during operation of the lithium ion battery. The chelating agents are: dissolved in the electrolyte solution; grafted onto the polymer of the separator; attached to the binder material of the negative and/or positive electrode; coated on a surface of the separator; and/or coated on a surface of the negative and/or positive electrode. The chelating agents are selected from: ion traps in molecular form selected from polyamines, thiols and alkali metal salts of organic acids; polymers functionalized with alkali metal salts of organic acids; polymers functionalized with nitrogen-containing functional groups; and polymers functionalized with two or more functional groups.

A nonaqueous electrolyte secondary battery separator having a laminated body which is not easily curled is provided. The laminated body includes a porous base material containing a polyolefin-based resin as a main component and a porous layer which is disposed on at least one surface of the porous base material and which contains a polyvinylidene fluoride-based resin. The porous base material has a piercing strength of not less than 26.0 gf/g/m.sup.2. The polyvinylidene fluoride-based resin contains crystal form α in an amount of not less than 36 mol % with respect to 100 mol % of a total amount of the crystal form α and crystal form β contained in the polyvinylidene fluoride-based resin.

A laminated body includes: a porous base material containing a polyolefin-based resin as a main component, the porous base material having a predetermined phase difference and porosity; and a porous layer disposed on at least one surface of the porous base material, the porous layer containing a polyvinylidene fluoride-based resin, the polyvinylidene fluoride-based resin containing crystal form α in an amount of not less than 34 mol % with respect to 100 mol % of a total amount of the crystal form α and crystal form β contained in the polyvinylidene fluoride-based resin.

To afford a laminated body that is usable as a nonaqueous electrolyte secondary battery separator and that is not easily curled, a laminated body includes: a porous base material containing a polyolefin-based resin as a main component; and a porous layer containing a polyvinylidene fluoride-based resin, the porous base material having a temperature rise ending period of a particular value with respect to the amount of resin per unit area, the polyvinylidene fluoride-based resin containing crystal form α in an amount of not less than 36 mol % with respect to 100 mol % of a total amount of the crystal form α and crystal form β contained in the polyvinylidene fluoride-based resin.