The inventive concepts disclosed relate to the production of green and blue hydrogen from hydrocarbons using visible light (from a laser, lamp or sun) and defect-engineered boron-rich photocatalysts. We demonstrate that the environment of the B atoms in the lattice can be tuned to favor the dehydrogenation of desired hydrocarbons on reaction sites under visible light. In addition to the hydrogen produced in gas form, carbon atoms are captured by the catalyst and form structures of potential higher value for future applications. Further study of the dark carbonaceous product revealed a graphitic aspect of the material. These findings highlight a new functionality of 2D materials for visible light-assisted capture and conversion of hydrocarbons, with great potential for green hydrogen production—i.e, hydrogen produced from renewable energy and without the release of CO or CO.sub.2.

Catalysts and catalytic methods are provided. The catalysts and methods are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane.

Catalysts and catalytic methods are provided. The catalysts and methods are useful in a variety of catalytic reactions, for example, the oxidative coupling of methane.

A method for producing a three-dimensional porous transition alumina catalyst monolith of stacked catalyst fibers, comprising: a) Preparing a paste in a liquid diluent of hydroxide precursor particles and/or oxyhydroxide precursor particles of transition alumina particles, all particles in the suspension having a number average particle size in the range of from 0.05 to 700 μm, b) extruding the paste nozzle(s) to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor, c) drying the precursor to remove the liquid diluent, d) performing a temperature treatment of the dried porous catalyst monolith precursor to form the transition alumina catalyst monolith, wherein no temperature treatment of the porous catalyst monolith precursor or porous catalyst monolith at temperatures above 1000° C. is performed and wherein no further catalytically active metals, metal oxides or metal compounds are applied to the surface.

A method for producing a three-dimensional porous transition alumina catalyst monolith of stacked catalyst fibers, comprising: a) Preparing a paste in a liquid diluent of hydroxide precursor particles and/or oxyhydroxide precursor particles of transition alumina particles, all particles in the suspension having a number average particle size in the range of from 0.05 to 700 μm, b) extruding the paste nozzle(s) to form fibers, and depositing the extruded fibers to form a three-dimensional porous catalyst monolith precursor, c) drying the precursor to remove the liquid diluent, d) performing a temperature treatment of the dried porous catalyst monolith precursor to form the transition alumina catalyst monolith, wherein no temperature treatment of the porous catalyst monolith precursor or porous catalyst monolith at temperatures above 1000° C. is performed and wherein no further catalytically active metals, metal oxides or metal compounds are applied to the surface.

Metal oxide nanoarrays, such as titanium oxide nanoarrays, having a platinum group metal dispersed thereon and methods of making such nanoarrays are described. The platinum group metal can be dispersed on the metal oxide nanoarray as single atoms. The nanoarrays can be used to catalyze oxidation of combustion exhaust.

Metal oxide nanoarrays, such as titanium oxide nanoarrays, having a platinum group metal dispersed thereon and methods of making such nanoarrays are described. The platinum group metal can be dispersed on the metal oxide nanoarray as single atoms. The nanoarrays can be used to catalyze oxidation of combustion exhaust.

Embodiments of the present invention include a filter element for decomposing contaminants including a substrate, and a photocatalytic composition comprising at least a photocatalyst and a co-catalyst. The embodiments of the present invention also includes a system for decomposing contaminants including a substrate, and a photocatalytic composition comprising at least a photocatalyst and a co-catalyst; and a method using the system.

Embodiments of the present invention include a filter element for decomposing contaminants including a substrate, and a photocatalytic composition comprising at least a photocatalyst and a co-catalyst. The embodiments of the present invention also includes a system for decomposing contaminants including a substrate, and a photocatalytic composition comprising at least a photocatalyst and a co-catalyst; and a method using the system.

To provide an ion exchange membrane with a catalyst layer, an ion exchange membrane and an electrolytic hydrogenation apparatus, which can lower electrolysis voltage and increase current efficiency at the time of electrolytic hydrogenation of an aromatic compound.

The ion exchange membrane with a catalyst layer of the present invention has an inorganic particle layer containing inorganic particles and a binder, a layer (Sa) containing a first fluorinated polymer having sulfonic acid type functional groups, and a layer (Sb) containing a second fluorinated polymer having sulfonic acid type functional groups, and a catalyst layer, in this order, wherein the ion exchange capacity of the above first fluorinated polymer is lower than the ion exchange capacity of the above second fluorinated polymer.