An electrochemical cell includes a pair of bipolar plates and a membrane electrode assembly between the bipolar plates. The membrane electrode assembly comprises an anode compartment, a cathode compartment, and a proton exchange membrane disposed therebetween. The cell further includes a sealing surface formed in one of the pair of bipolar plates and a gasket located between the sealing surface and the proton exchange membrane. The gasket is configured to plastically deform to create a seal about one of the cathode compartment or the anode compartment. The sealing surface can include one or more protrusions.

Disclosed herein are methods and systems that relate to electrochemically oxidizing metal halide with a metal ion in a lower oxidation state to a higher oxidation state; halogenating an unsaturated hydrocarbon or a saturated hydrocarbon with the metal halide with the metal ion in the higher oxidation state; and oxyhalogenating the metal halide with the metal ion from a lower oxidation state to a higher oxidation state in presence of an oxidant. In some embodiments, the oxyhalogenation is in series with the electrochemical oxidation, the electrochemical oxidation is in series with the oxyhalogenation, the oxyhalogenation is parallel to the electrochemical oxidation, and/or the oxyhalogenation is simultaneous with the halogenation.

An electrochemical device is provided that includes a stack of a plurality of electrochemical units that succeed one another in a stacking direction and each include an electrochemically active membrane electrode assembly, at least one gas diffusion layer and a bipolar plate having at least one flow field, in which at least one flow field is sealed off simply and reliably and the occurrence of parasitic flows is prevented, wherein at least one bipolar plate has at least one edge web, which borders a flow field of the bipolar plate and is in contact with a gas diffusion layer adjacent to the bipolar plate, and wherein the electrochemical device further includes at least one flow field seal element that seals off the flow field bordered by the edge web and is in contact with the edge web and in contact with the gas diffusion layer.

An assembly comprising a SOEC/SOFC-type solid oxide stack, and a clamping system for the stack, said clamping system comprising at least two clamping rods that can be used to assemble upper and lower clamping plates. The assembly further comprises a heat exchange system formed at least in part by at least two hollow clamping rods of the clamping system, through which a fluid to be superheated or preheated flows.

A water treatment system is disclosed having electrolytic cell for liberating hydrogen from a base solution. The base solution may be a solution of brine for generating sodium hypochlorite, or potable water to be oxidized. The cell has first and second opposing electrode end plates held apart from each other by a pair of supports such that the supports enclose opposing sides of the end plates to form a cell chamber. One or more inner electrode plates are spaced apart from each other in the cell chamber in between the first and second electrode plates. The supports are configured to electrically isolate the first and second electrode plates and the inner electrode plates from each other. The first and second electrode plates are configured to receive opposite polarity charges that passively charge the inner electrode plates via conduction from the base solution to form a chemical reaction in the base solution as the base solution passes through the cell chamber.

An electrochemical device includes at least one electrochemical cell, including a membrane electrode assembly and bipolar plates through which at least one discharge manifold passes, the membrane electrode assembly including an active zone and a connection zone; at least one hydrogen sensor including an anode positioned in the connection zone and including a catalyst suitable for ensuring the oxidation of the hydrogen, and a cathode opposite the anode; a voltage source; a current sensor; and a computing unit, suitable for detecting the presence of hydrogen from the measured value of the electric current.

An interconnector-electrochemical reaction unit cell composite body including an electrochemical reaction unit cell, and an interconnector which has a first through hole defining a fuel gas flow channel and which is disposed on the side toward an anode of the electrochemical reaction unit cell. The interconnector includes a coating forming a first surface of the interconnector opposite the anode. The coating includes a first coating and a second coating a having reduction resistance higher than that of the first coating. The first coating forms a first surface region which is a portion of the first surface of the interconnector and which is located away from the first through hole. The second coating forms a second surface region which is a portion of the first surface of the interconnector, which surrounds the first through hole, and which is located between the first coating and the first through hole.

The present invention relates to an electrode assembly and an electrolyser using said assemblies/structures, wherein the electrode assembly comprises an anode structure and a cathode structure, each of said anode structure and cathode structure comprising an outlet header for evolved gas and spent liquid, wherein each of said anode structure and cathode structure comprising an outlet header for evolved gas and spent liquid, wherein the outlet header on the anode structure has a total internal volume of V.sub.A cm.sup.3 and the outlet header on the cathode structure has a total volume of V.sub.C cm.sup.3 wherein V.sub.A is less than V.sub.C, and/or i) the outlet header on the anode structure has an internal volume, V.sub.A cm.sup.3, an internal cross sectional area at the exit end of the header of A.sub.A cm.sup.2 and an internal length L.sub.A cm, and ii) the outlet header on the cathode structure has an internal volume, V.sub.C cm.sup.3, an internal cross sectional area at the exit end of the header of A.sub.C cm.sup.2 and an internal length L.sub.C cm, and one or both of the ratios V.sub.A/(A.sub.AL.sub.A) and V.sub.C/(A.sub.CL.sub.C) are less than 1.

The present disclosure is directed to a method for tuning the performance of at least one electrochemical cell of an electrochemical cell stack. The method includes supplying power to an electrochemical cell stack. The electrochemical cell stack includes a plurality of electrochemical cells. The method further includes monitoring a parameter of at least one electrochemical cell and determining if an electrochemical cell becomes impaired. The method also includes diverting a fraction of the current flow from the impaired electrochemical cell during operation of the electrochemical cell stack.

A spacer for an electrolyzer cell of substantially annular shape comprises: a peripheral part having two parallel principal faces opposite each other, the distance separating the two principal faces defining a thickness of the spacer, and an internal part having a thickness strictly less than the thickness of the spacer, the peripheral part and the internal part being in one piece and connected to each other forming an internal annular shoulder so that the internal part has a substantially annular intermediate face extending in a plane parallel to the two principal faces of the peripheral part and situated between the two principal faces.