A sintered material exhibiting the following chemical composition, as percentages by weight: iron oxide(s), expressed in the Fe.sub.2O.sub.3 form, ≥85%, CaO: 0.1%-6%, SiO.sub.2: 0.1%-6%, 0.05% ≤TiO.sub.2, 0≤Al.sub.2O.sub.3, TiO.sub.2+Al.sub.2O.sub.3≤3%, and constituents other than iron oxides, CaO, SiO.sub.2, TiO.sub.2 and Al.sub.2O.sub.3: ≤5%. The CaO/SiO.sub.2 ratio by weight is between 0.2 and 7. The TiO.sub.2/CaO ratio by weight is between 0.2 and 1.5.

Organosilicon chemistry, polymer derived ceramic materials, and methods. Such materials and methods for making polysilocarb (SiOC) and Silicon Carbide (SiC) materials having 3-nines, 4-nines, 6-nines and greater purity. Processes and articles utilizing such high purity SiOC and SiC.