A method of fighting a fire, the method includes aerating a firefighting foam composition to form an areated firefighting foam; administering the aerated firefighting foam to a fire or applying the aerated firefighting foam to a surface of a volatile flammable liquid; wherein the firefighting foam composition includes a surfactant component comprising an anionic surfactant, a zwitterionic surfactant, optionally a nonionic surfactant, or a mixture of any two or more thereof; an aliphatic alcohol-based component comprising at least two compounds selected from C.sub.8-C.sub.14-aliphatic alcohols and ethoxylates of C.sub.10-C.sub.14-aliphatic alcohols having an average of no more than about 6 ethylene oxide units; and at least about 30 wt. % water.

A method of fighting a fire, the method includes aerating a firefighting foam composition to form an areated firefighting foam; administering the aerated firefighting foam to a fire or applying the aerated firefighting foam to a surface of a volatile flammable liquid; wherein the firefighting foam composition includes a surfactant component comprising an anionic surfactant, a zwitterionic surfactant, optionally a nonionic surfactant, or a mixture of any two or more thereof; an aliphatic alcohol-based component comprising at least two compounds selected from C.sub.8-C.sub.14-aliphatic alcohols and ethoxylates of C.sub.10-C.sub.14-aliphatic alcohols having an average of no more than about 6 ethylene oxide units; and at least about 30 wt. % water.

An alternative to aqueous film forming foams containing fluorine for firefighting foams for flammable liquid fires is a mist of aqueous ethyleneamine polyphosphate solution or fumed silica doped ethyleneamine polyphosphate solution. The method consists of spraying a mist of such solutions into a flammable liquid fire to suppress the flames and cool the fire. The mist approach also suppresses flames of wood fires. An alternate approach is to add ethyleneamine polyphosphate or fumed silica doped ethyleneamine polyphosphate to a fluorine free foam to form a flame retarded foam that is able to smother a flammable liquid fire.

A foam stabilizing composition is disclosed. The composition comprises (A) a siloxane cationic surfactant comprising a cationic moiety having the formula Z.sup.1-D.sup.1-N(Y).sub.a(R).sub.2−a, wherein Z.sup.1 is a siloxane moiety, D.sup.1 is a divalent linking group, R is H or an unsubstituted hydrocarbyl group having from 1 to 4 carbon atoms, subscript a is 1 or 2, and each Y has formula -D-NR.sup.1.sub.3+, where D is a divalent linking group and each R.sup.1 is independently an unsubstituted hydrocarbyl group having from 1 to 4 carbon atoms. The composition also comprises (B) an organic cationic surfactant comprising a cationic moiety having the formula Z.sup.2-D.sup.2-N(Y).sub.b(R).sub.2−b, wherein Z.sup.2 is an unsubstituted hydrocarbyl group, D.sup.2 is a covalent bond or a divalent linking group, subscript b is 1 or 2, and R, Y, and subscript a, are defined above. An aqueous film-forming foam comprising the composition and method of using the same are also disclosed

An aqueous composition, which can be diluted with an aqueous diluent to provide a foam precursor composition, is provided. The foam precursor composition can be aerated to form a firefighting foam. The present aqueous firefighting compositions include a surfactant mixture containing a siloxane-based surfactant together with one or more of a nonionic surfactant, an anionic surfactant, and a zwitterionic surfactant. The aqueous firefighting compositions also include a polysaccharide thickener and an organic solvent, such as an alkylene glycol, glycerol and/or a glycol ether.

The present invention provides a foam fire extinguishing agent that can fulfill predetermined performances without containing any fluorine-based compounds. The foam fire extinguishing agent of die present invention is characterized by containing 0.2 to 3.0% by mass of cationic surfactant, 0.2 to 5.0 by mass of anionic surfactant and water for a total of 100% by mass.

A proportioner having a body portion that defines a foam passage and a fluid passage. The proportioner also includes a restrictor assembly having a restrictor disk and an orifice plate having an opening for receiving the restrictor disk. The proportioner can further include a rod member connected to the restrictor disk and a clapper assembly connected to the rod member via a sliding interface. The clapper assembly can be configured to control a flow of the foam concentrate through the foam passage in proportion to a flow of the fire protection fluid through the fluid passage by moving the rod member to vary the distance between the restrictor disk and the orifice plate. The sliding interface can be disposed between a first guide and a second guide, and at least a portion of the restrictor disk is disposed in the opening.

Systems and compositions for suppressing and extinguishing several classes of fire, e.g. Class D, fires are disclosed. The composition includes some form of powdered Aloe vera, a bio-surfactant, a thickening agent, and a diol. The composition may be mixed with paint to coat a structure thus protecting the structure from fire. The composition may also be mixed with epoxy resin for coating a structure also for fire protection. The composition may also be in the form of a gel in canisters for extinguishing fire.

The invention comprises a fire extinguisher and method, wherein the fire extinguisher has a sealable high-pressure container that forms a hollow interior connected by a valve to an environment external to the said container. The said container holds at a high pressure at room temperature a composition of liquid carbon dioxide and a non-hydrate, hydrophobic, cyclic organo-siloxane compound, the said compound further having a freezing point of at least −20° C. at one atmosphere. Upon release of the combination to the environment external to the container, the compound further produces a clathrate. In at least one embodiment of the invention, both the clathrate and the non-hydrate, hydrophobic, cyclic organo-siloxane compound have firefighting conductive properties.

A dispensing unit that consists of two or more dispensing solutions, at least one being a fluorine-free foam solution, and at least one hydrogel-based solution, and which involves the dispensing of each solution through one or more compressed air foam system (CAFS), where the CAFS may use compressed air, nitrogen, or other inert gas. The individual solutions may be mixed prior to the CAFS, or one or more solutions mixed after the CAFS, or they may be mixed in separate CAFS chambers. The resulting foam may be dispensed through a single line or through multiple lines, applied simultaneously and/or at different times, and may be controlled manually and/or through automatic controls, or through a combination of the above.