A catalyst adapted for generating hydrogen peroxide induced by a temperature difference and a method for environmental disinfection using the same are provided. The catalyst includes a thermoelectric material distributed on a substrate. The thermoelectric material induces a reaction between water vapor and oxygen contained in the air through a temperature difference to generate hydrogen peroxide, to serve a sterilization function through the hydrogen peroxide generated. The method for environmental disinfection using the catalyst includes the following. The catalyst is placed in an environment with a temperature difference. The catalyst is caused to induce a reaction between water vapor and oxygen contained in air through the temperature difference to generate hydrogen peroxide without applying power, and serve a sterilization function through the hydrogen peroxide generated.

Claimed herein is a method of applying amorphous Co—SiOx to activate PMS and produce SO.sub.4..sup.− due to the formation of Co(II)-O.sub.v, pairs via the substitution of Si by Co. The inherent Co significantly change the electronic structure of O and Si atoms in the Co—SiOx via final state effects and increase the conductivity in terms of more effective electron transfers. The claimed method using Co—SiOx functions as a more effective oxidative catalyst for the faster degradation of pollutants. The simplicity of the synthetic procedures indicates that the conductive Co—SiOx could be used for the activation of PMS and other electrochemical applications on a wider scale.

A method is disclosed in which a gas of hydrogen and nitrogen, or hydrogen and ammonia, or hydrogen, nitrogen, and ammonia, is introduced to a fluidized bed. The gas flows through the fluidized bed, and titanium dioxide particles are introduced to the fluidized bed to form a fluid mixture of the particles and gas in the fluidized bed. The particles are reacted with the gas in the fluid mixture to form particles including titanium dioxide and nitrogen. The particles can be disposed along an air flow path in operative communication with a light source for air treatment.

The present invention relates to methods and catalysts for producing methylbenzyl alcohol from ethanol by catalytic conversion, and belongs to the field of chemical engineering and technology. The present invention develops a route of producing methylbenzyl alcohol starting from green and sustainable ethanol and provide corresponding catalysts used for the catalytic conversion route. This innovative reaction route has several advantages, such as, simple process, eco-friendly property, and easy separation of products, as compared with a traditional petroleum-based route. This present route has a reaction temperature of 150-450° C. and total selectivity of 72% for methylbenzyl alcohol, and has good industrial application prospect. The innovation of this patent comprises the catalysts synthesis and the reaction route.

The present disclosure provides an exhaust gas purification catalyst having an improved Rh activation, which comprises a substrate and a catalyst coat layer formed on the substrate, the catalyst coat layer having a two-layer structure, wherein the catalyst coat layer includes an upstream portion on an upstream side and a downstream portion on a downstream side in an exhaust gas flow direction, and a part or all of the upstream portion is formed on a part of the downstream portion, wherein the upstream portion contains Rh fine particles and Pt, wherein the Rh fine particles have an average particle size measured by a transmission electron microscope observation of 1.0 nm or more to 2.0 nm or less, and a standard deviation σ of the particle size of 0.8 nm or less, and wherein the downstream portion contains Rh.

The present invention relates to a molding catalyst and a method for producing the same, wherein the molding catalyst is used in the Deacon process for commercial production of chlorine using hydrogen chloride oxidation reaction, exhibits only a small reduction in catalytic activity even when exposed to harsh reaction conditions to thus be durable, and has superb mechanical strength to be suitable for use in a fixed bed catalytic reactor.

Catalysts for oxidative esterification can be used, for example, fro converting (meth)acrolein to methyl (meth)acrylate. The catalysts are especially notable for high mechanical and chemical stability even over very long time periods, including activity and/or selectivity relatively in continuous operation in media having even a small water content.

The present invention relates to a catalyst system for oxidation of o-xylene and/or naphthalene to phthalic anhydride (PA) comprising at least four catalyst zones arranged in succession in the reaction tube and filled with catalysts of different chemical composition wherein the active material of the catalysts comprise vanadium and titanium dioxide and the active material of the catalyst in the last catalyst zone towards the reactor outlet has an antimony content (calculated as antimony trioxide) between 0.7 to 3.0 wt. %. The present invention further relates to a process for gas phase oxidation in which a gas stream comprising at least one hydrocarbon and molecular oxygen is passed through a catalyst system which comprises at least four catalyst zones arranged in succession in the reaction tube and filled with catalysts of different chemical composition wherein the active materials of the catalysts comprise vanadium and titanium dioxide and the active material of the catalyst in the last catalyst zone towards the reactor outlet has an antimony content (calculated as antimony trioxide) between 0.7 to 3.0 wt. %.

Some embodiments are directed to a new methodology aimed at preparing highly N-doped mesoporous carbon macroscopic composites, and their use as highly efficient heterogeneous metal-free catalysts in a number of industrially relevant catalytic transformations.

The invention relates to a catalyst which comprises: a) a mixed metal oxide of molybdenum, vanadium, niobium and optionally tellurium; and b) ceria particles having a crystallite size greater than 15 nanometers (nm); wherein the amount of the ceria particles, based on the total amount of the catalyst, is of from 1 to 60 wt. %. Further, the invention relates to a process for preparing a catalyst, which comprises mixing a mixed metal oxide of molybdenum, vanadium, niobium and optionally tellurium with ceria particles having a crystallite size greater than 15 nanometers (nm), wherein the amount of the ceria particles, based on the total amount of the catalyst, is of from 1 to 60 wt. %. Still further, the invention relates to an alkane oxidative dehydrogenation and/or alkene oxidation process wherein such catalyst is used.