A method for separating and refining 1-butene with a high purity and a high yield from a raffinate-2 stream. The method includes: feeding raffinate-2 to a first distillation column; obtaining heavy raffinate-3 from a lower part of the first distillation column; recovering an upper part fraction containing 1-butene from an upper part of the first distillation column; feeding the upper part fraction containing 1-butene to a second distillation column; recovering a first lower part fraction rich in 1-butene from a lower part of the second distillation column and light raffinate-3 from an upper part of the second distillation column. Heat of the upper part fraction recovered from the upper part of the first distillation column is fed to the lower part of the second distillation column through a first heat exchanger. Thus, 1-butene is obtained with high purity and high yield while maximizing an energy recovery amount by double-effect distillation.

A bubble-column-humidification apparatus includes a humidifier chamber configured to receive the feed liquid from a feed-liquid source. A bubble distributor is contained in the humidifier chamber; and a humidifier bath of the feed liquid is also contained in the humidifier chamber above the bubble distributor. The feed liquid forms a continuous and majority phase of the humidifier bath and fills a majority of the humidifier chamber, which has a width at least twice as great as its height. A lower gas region is located below the bubble distributor and the humidifier bath in the humidifier chamber and is configured to receive a carrier gas from a carrier-gas source and to disperse the carrier gas through the bubble distributor. The carrier gas in the lower gas region has a pressure greater than the hydrostatic pressure of the humidifier bath.

The separation method separates a polyalcohol compound from water, so as to obtain a purified product stream comprising the polyalcohol compound in output concentration of at least 90 wt %. Thereto, a mixture of the polyalcohol compound and water is provided, said mixture having a polyalcohol concentration. The polyalcohol concentration of mixture is increased in an evaporation stage, at least a portion of which is operated in at first pressure. Subsequently, the mixture is treated in distillation stage to be deliver the stream comprising the polyalcohol compound in the output concentration of at least 90 wt %, which distillation stage is operated at a second pressure. Herein, the distillation stage is operated to produce steam output, that optionally compressed to a third pressure and is coupled to the evaporation stage. The second pressure and/or any third pressure is higher than first pressure. The reactor system is configured for performing the separation method.

A feed liquid flows into a second-stage humidifier chamber to form a second-stage humidifier bath. A first remnant of the feed liquid from the second-stage humidifier chamber then flows into a first-stage humidifier chamber to form a first-stage humidifier bath having a temperature lower than that of the second-stage bath. A second remnant of the feed liquid is then removed from the first-stage humidifier. Meanwhile, a carrier gas is injected into and bubbled through the first-stage humidifier bath, collecting a vaporizable component in vapor form from the first remnant of the feed liquid to partially humidify the carrier gas. The partially humidified carrier gas is then bubbled through the second-stage humidifier bath, where the carrier gas collects more of the vaporizable component in vapor form from the feed liquid to further humidify the carrier gas before the humidified carrier gas is removed from the second-stage humidifier chamber.

An apparatus for a dividing wall column in an isomerization unit is disclosed. The apparatus includes a at least one primary vertical wall located at a first set of predetermined plurality of trays and configured to separate a feed from a first side cut; one or more walls placed at a second set of predetermined plurality of trays and configured to enable a second side cut wherein each of the one or more walls includes at least one predetermined shape, wherein the dividing wall column produces four cuts wherein one is hexane cut, wherein there are two walls in different sections of the column. The at least one primary vertical wall includes one of a straight wall, an ‘L’ shaped wall, an ‘Γ’ shaped wall, or a zig-zag wall. The one or more walls are mechanically coupled to form a second vertical wall.

A method for separating and refining 1-butene with a high purity and a high yield from a raffinate-2 stream. The method includes: feeding raffinate-2 to a first distillation column; obtaining heavy raffinate-3 from a lower part of the first distillation column; recovering an upper part fraction containing 1-butene from an upper part of the first distillation column; feeding the upper part fraction containing 1-butene to a second distillation column; recovering a first lower part fraction rich in 1-butene from a lower part of the second distillation column and light raffinate-3 from an upper part of the second distillation column. Heat of the upper part fraction recovered from the upper part of the first distillation column is fed to the lower part of the second distillation column through a first heat exchanger. Thus, 1-butene is obtained with high purity and high yield while maximizing an energy recovery amount by double-effect distillation.

[Objective] An object is to provide a method for producing a diol by which diols having a favorable color scale and containing a reduced amount of an unsaturated aliphatic hydrocarbon can be produced. [Solution] A method for producing a diol, including a) supplying metaboric acid, a saturated aliphatic hydrocarbon and a reaction gas containing molecular oxygen to a reactor and performing liquid-phase oxidation of the saturated aliphatic hydrocarbon with the reaction gas containing molecular oxygen in the presence of metaboric acid to obtain a reaction liquid containing an oxide, b) esterifying the oxide to obtain a reaction liquid containing a borate compound, c) separating the reaction liquid containing a borate compound into an unreacted saturated aliphatic hydrocarbon and a distillation residue by distillation, d) separating the distillation residue into orthoboric acid and an organic layer by hydrolysis, e) separating the organic layer into an alkali aqueous solution layer and a crude alcohol layer by saponification with an alkali, and f) performing first distillation on the crude alcohol layer to remove a monoalcohol, and then performing second distillation on the residual liquid under conditions of a temperature of lower than 250° C. and a residence time of shorter than 60 minutes.

The present invention relates to a system and method for evaporation and condensation with particular but not exclusive application in distillation of water, waste water treatment and desalination process. The system comprises of plurality of evaporation frame (4), condensation frame (3) and preheat frame (6). Plurality of frames may be combined to form a stack. Plurality of stacks together form a unit, plurality of such units may be combined to form a multistage evaporation and condensation system.

A method for separating CO.sub.2 from C.sub.2 to C.sub.5 alkanes includes introducing a first stream including C.sub.2 to C.sub.5 alkanes and CO.sub.2 into a first separation zone, the first separation zone including a hydrocarbon solvent, and separating the first stream into a recycle stream and a second stream in the first separation zone. The recycle stream including CO.sub.2 and one or more of CO, H.sub.2, and CH.sub.4, and the second stream including C.sub.2 to C.sub.5 alkanes. The method further includes introducing the second stream into a second separation zone, and separating the second stream into a third stream and a fourth stream, wherein the third stream includes C.sub.2 alkanes and the fourth stream includes C.sub.3 to C.sub.5 alkanes.

A method for separating CO.sub.2 from C.sub.2 to C.sub.5 alkanes includes introducing a first stream including C.sub.2 to C.sub.5 alkanes and CO.sub.2 into a first separation zone, the first separation zone including a hydrocarbon solvent, and separating the first stream into a recycle stream and a second stream in the first separation zone. The recycle stream including CO.sub.2 and one or more of CO, H.sub.2, and CH.sub.4, and the second stream including C.sub.2 to C.sub.5 alkanes. The method further includes introducing the second stream into a second separation zone, and separating the second stream into a third stream and a fourth stream, wherein the third stream includes C.sub.2 alkanes and the fourth stream includes C.sub.3 to C.sub.5 alkanes.