A method of processing thin stillage in an ethanol refining operation is provided. The method comprises treating thin stillage upstream of a concentration or evaporation step with an aid comprising a sorbitan ester of a fatty acid, an ethoxylated sorbitan ester of a fatty acid, or a combination thereof, thereby forming treated thin stillage. The aid may include at least one of sorbitan monooleate, polyoxyethylene sorbitan monostearate, and polyoxyethylene sorbitan monolaurate.

A production stream from a well formed in a subterranean formation is flowed to a gas oil separation unit. The gas oil separation unit includes a separator vessel. The production stream includes an emulsion including an oil phase and an aqueous phase. Steam is mixed with the production stream prior to the production stream entering the separator vessel. Phases of the production stream are separated by the separator vessel to produce a vapor stream, an aqueous stream, and an oil stream.

This invention provides a concentrated demulsifier composition comprising A) at least 50 wt.-% of a demulsifier, selected from the group consisting of a polymeric nonionic oil-soluble demulsifier for mineral oils, and an alkyl aryl sulphonic acid or its salt, and mixtures thereof, B) 0.1 to 20 wt.-% of a surfactant selected form anionic, cationic, zwitterionic and nonionic surfactants, the surfactant being different from the demulsifier, C) less than 20 wt.-% of a water-immiscible organic solvent, D) 3 to 49 wt.-% of a water-miscible organic solvent and E) 0 to 5 wt.-% of water.

The present disclosure relates to demulsifier compositions and methods of resolving emulsions using the compositions. The demulsifiers include modified hydroxy-succinimide copolymers. For example, the demulsifiers may include ethoxylated or propoxylated hydroxy-succinimide copolymers. The demulsifier compositions are useful for resolving oil-in-water, water-in-oil, and complex emulsions of water and oil.

An emulsion separation device including a plurality of inclined plates, a buoyancy device, and an electric field generation system. Also disclosed are systems and methods for the separation of an emulsion into a continuous aqueous phase and a continuous oil phase. The systems may include: a vessel having an emulsion inlet, a continuous aqueous phase outlet, and a continuous oil phase outlet. A separation device may be disposed in the vessel, the separation device including: a plurality of inclined plates and a buoyancy device configured to maintain the plurality of inclined plates between the continuous aqueous phase and the continuous oil phase. An electric field generation system may also be provided and configured to expose the emulsion to an electric field.

Disclosed herein is an oil dispersant composition that contains an acyl amino acid ionic liquid, a dicationic ionic liquid, a fruit acid ionic liquid, a polyacid ionic liquid, and an ethoxylate oleyl ether ionic liquid. The composition may also be diluted with water. The composition is useful for dispersing an oil spill in a body of water, while being less toxic to the aquatic environment and also acting to stimulate bacterial growth in said aquatic environment.

The present disclosure refers to the development of novel random bipolymers, which are comprised of alkyl acrylate and alkoxy alkyl acrylate monomers, as hydrophobic and hydrophilic components, respectively. These bipolymers are synthesized by means of semi-continuous emulsion polymerization, under strict conditions of monomer deficiency, to ensure the randomness and homogeneity of the chains. The application in dissolution of these random bipolymers has shown a dehydrating capacity superior to that of polyethers and phenolic resins, with the additional advantage of being soluble in crude oil. The random bipolymers show excellent performance as breakers of water-in-crude oil emulsions, coalescers of water droplets and clarifiers of the removed aqueous phase, and are chemically stable under acidic conditions.

A process of dewatering oil sands/coal tailings includes generating nanobubble water, mixing a chemical dispersant into the nanobubble water to form a nanobubble-dispersant mixture, adding tailings to the nanobubble-dispersant mixture to form a nanobubble-dispersant-tailings mixture, and agitating the nanobubble-dispersant-tailings mixture to form an agitated nanobubble-dispersant-tailings mixture having a solid portion and a liquid portion. The solid portion is thereafter separated from the liquid portion. The agitation may be a centrifugal motion or shaking motion to agitate the nanobubble-dispersant-tailings mixture The chemical dispersant may be sodium hydroxide dispersant for asphaltenes and the volume of the tailings added may be substantially equal to the volume of the nanobubble water generated. An oil layer may further be skimmed off the liquid portion a polymer clarifier may also be added to the liquid portion. The process may be applied to achieve accelerated tailings processing for rapid and economic environmental remediation.

Methods and devices for obtaining approximate property data from the aqueous liquid phase of a multiphase fluid produced from a well. The method includes introducing a discrete sample of the multiphase fluid to a separation vessel; mixing a demulsifier with the discrete sample of the multiphase fluid; allowing the multiphase fluid to separate into separate liquid phases; drawing a measured sample of the aqueous liquid phase from the separation vessel, and diluting it with a measured amount of fresh water; analyzing the diluted aqueous liquid phase sample in a water analysis unit to measure a property of the diluted aqueous liquid phase sample and obtain diluted aqueous liquid phase sample data; and calculating the approximate aqueous liquid phase property data using the diluted aqueous liquid phase sample data and accounting for the amount of fresh water used to dilute the measured sample of the aqueous liquid phase.

A system and method for a gas oil separation plant (GOSP) that receives crude oil from a wellhead. The GOSP has a sand filter associated with a water-oil separator vessel that removes crude oil from oily water in the GOSP. The sand filter is a filter having sand as filter media.