An apparatus and methods to eliminate PFAS from wastewater biosolids through fluidized bed gasification. The gasifier decomposes the PFAS in the biosolids at temperatures of 900-1800° F. Synthesis gas (syngas) exits the gasifier which is coupled to a thermal oxidizer and is combusted at temperatures of 1600-2600° F. This decomposes PFAS in the syngas and creates flue gas. Heat can be recovered from the flue gas by cooling the flue gas to temperatures of 400-1200° F. in a heat exchanger that is coupled with the thermal oxidizer. Cooled flue gas is mixed with hydrated lime, enhancing PFAS decomposition, with the spent lime filtered from the cooled flue gas using a filter system that may incorporate catalyst impregnated filter elements. The apparatus and methods thereby eliminate PFAS from wastewater biosolids and control emissions in the resulting flue gas.

A desulfurizer material for desulfurizing fuel supplied to a fuel cell system, the desulfurizer material comprising one or more manganese oxide materials having an octahedral molecular sieve (OMS) structure, and the desulfurizer material being resistant to moisture and being capable of removing organic sulfur containing compounds and H.sub.2S. The desulfurizer material is used in a desulfurizer assembly which is used as part of a fuel cell system.

A desulfurizer material for desulfurizing fuel supplied to a fuel cell system, the desulfurizer material comprising one or more manganese oxide materials having an octahedral molecular sieve (OMS) structure, and the desulfurizer material being resistant to moisture and being capable of removing organic sulfur containing compounds and H.sub.2S. The desulfurizer material is used in a desulfurizer assembly which is used as part of a fuel cell system.

The present invention is intended to provide a gas purification apparatus and a gas purification method with an excellent thermal efficiency and capable of degrading COS at a high degradation rate. A gas purification apparatus configured to purify gas at least including COS, H.sub.2O, CO.sub.2, and H.sub.2S includes a COS treatment device which is provided with a COS conversion catalyst and configured to treat and degrade COS in the gas by hydrolysis, and H.sub.2O adjustment means configured to adjust the concentration of H.sub.2O in the gas to be introduced into the COS treatment device.

The present invention is intended to provide a gas purification apparatus and a gas purification method with an excellent thermal efficiency and capable of degrading COS at a high degradation rate. A gas purification apparatus configured to purify gas at least including COS, H.sub.2O, CO.sub.2, and H.sub.2S includes a COS treatment device which is provided with a COS conversion catalyst and configured to treat and degrade COS in the gas by hydrolysis, and H.sub.2O adjustment means configured to adjust the concentration of H.sub.2O in the gas to be introduced into the COS treatment device.

A fossil fuel fired power plant exhaust gas clean-up system is provided to remove detrimental compounds/elements from the exhaust gas emitting from the power plant to protect the environment. This is accomplished primarily by directing the exhaust gas from a fossil fuel fired power plant through both a reaction chamber containing a chemically produced compound and a catalytic converter. The final exhaust gas can now be safely exhausted to the atmosphere and only contains nitrogen gas, oxygen, water and a trace amount of carbon dioxide.

Acid gas compounds are removed from a process gas such as, for example, syngas or natural gas, by flowing a feed gas into a desulfurization unit to remove a substantial fraction of sulfur compounds from the feed gas and flowing the resulting desulfurized gas into a CO.sub.2 removal unit to remove a substantial fraction of CO.sub.2 from the desulfurized gas.

A wastewater treatment plant includes an anaerobic membrane bioreactor, AnMBR, unit configured to receive wastewater and to produce (1) a final permeate and (2) a gas; an oxidation disinfection unit configured to receive the final permeate and to remove biological and chemical contaminants from the final permeate to generate a final effluent; and an energy recovery unit configured to receive the gas from the AnMBR unit and generate electrical energy. The wastewater treatment plant does not use chlorination.

A wastewater treatment plant includes an anaerobic membrane bioreactor, AnMBR, unit configured to receive wastewater and to produce (1) a final permeate and (2) a gas; an oxidation disinfection unit configured to receive the final permeate and to remove biological and chemical contaminants from the final permeate to generate a final effluent; and an energy recovery unit configured to receive the gas from the AnMBR unit and generate electrical energy. The wastewater treatment plant does not use chlorination.

Disclosed herein are methods, systems, and compositions for providing catalysts for tail gas clean up in sulfur recovery operations. Aspects of the disclosure involve obtaining catalyst that was used in a first process, which is not a tailgas treating process and then using the so-obtained catalyst in a tailgas treating process. For example, the catalyst may originally be a hydroprocessing catalyst. A beneficial aspect of the disclosed methods and systems is that the re-use of spent hydroprocessing catalyst reduces hazardous waste generation by operators from spent catalyst disposal. Ultimately, this helps reduce the environmental impact of the catalyst life cycle. The disclosed methods and systems also provide an economically attractive source of high-performance catalyst for tailgas treatment, which benefits the spent catalyst generator, the catalyst provider, and the catalyst consumer.