One aspect of the invention relates to a method comprising a single-stage conversion of an atmospheric pollutant, such as NO, NO.sub.2 and/or SO.sub.x in a first stream to one or more mineral acids and/or salts thereof by reacting with nonionic gas phase chlorine dioxide (ClO.sub.2.sup.0), wherein the reaction is carried out in the gas phase. Another aspect of the invention relates to a method comprising first adjusting the atmospheric pollutant concentrations in a first stream to a molar ratio of about 1:1, and then reacting with an aqueous metal hydroxide solution (MOH). Another aspect of the invention relates to an apparatus that can be used to carry out the methods disclosed herein. The methods disclosed herein are unexpectedly efficient and cost effective, and can be applied to a stream comprising high concentration and large volume of atmospheric pollutants.

One aspect of the invention relates to a method comprising a single-stage conversion of an atmospheric pollutant, such as NO, NO.sub.2 and/or SO.sub.x in a first stream to one or more mineral acids and/or salts thereof by reacting with nonionic gas phase chlorine dioxide (ClO.sub.2.sup.0), wherein the reaction is carried out in the gas phase. Another aspect of the invention relates to a method comprising first adjusting the atmospheric pollutant concentrations in a first stream to a molar ratio of about 1:1, and then reacting with an aqueous metal hydroxide solution (MOH). Another aspect of the invention relates to an apparatus that can be used to carry out the methods disclosed herein. The methods disclosed herein are unexpectedly efficient and cost effective, and can be applied to a stream comprising high concentration and large volume of atmospheric pollutants.

Atmospheric pollutants are efficiently separated from exhaust gas with low operating cost. The exhaust gas cleaning method forms a fine mist of aqueous alkaline solution with an atomizer in an atomizing step; mixes the aqueous alkaline solution mist with exhaust gas to absorb atmospheric pollutants contained in the exhaust gas into the mist in a mixing step; and separates mist that absorbed atmospheric pollutants from the exhaust gas in a separating step.

There is provided a photoreactor for the remediation of gaseous emissions and/or contaminated water using ultraviolet (UV) or vacuum ultraviolet (VUV). There is also provided an emission source for generating UV and/or VUV, the source comprising: a microwave generator; a chamber arranged to receive microwaves generated by the microwave generator, the chamber comprising: a gas comprising species for forming excimers; a resonator arranged to receive the microwaves in the chamber and generate a plasma; a first electrode spaced apart from the resonator; and a voltage source configured to generate an electric field between the resonator and the first electrode, wherein, on application of the electric field, the electric field drives electrons and/or ions from the plasma to generate excimers and produce vacuum ultraviolet or ultraviolet emission. There are also provided methods of generating UV and/or VUV, and methods of remediating fluids.

There is provided a photoreactor for the remediation of gaseous emissions and/or contaminated water using ultraviolet (UV) or vacuum ultraviolet (VUV). There is also provided an emission source for generating UV and/or VUV, the source comprising: a microwave generator; a chamber arranged to receive microwaves generated by the microwave generator, the chamber comprising: a gas comprising species for forming excimers; a resonator arranged to receive the microwaves in the chamber and generate a plasma; a first electrode spaced apart from the resonator; and a voltage source configured to generate an electric field between the resonator and the first electrode, wherein, on application of the electric field, the electric field drives electrons and/or ions from the plasma to generate excimers and produce vacuum ultraviolet or ultraviolet emission. There are also provided methods of generating UV and/or VUV, and methods of remediating fluids.

A purification composition, comprising 50-60% by weight of ash and 40-50% by weight of liquid. A method for producing the purification composition, comprising: measuring an amount of ash, combining the ash and liquid, wherein an amount of the liquid is based on the amount of the ash, adjusting a temperature of the combination of the ash and the liquid by adjusting a temperature of the liquid and mixing the ash and the liquid. A method for purifying a flue gas by the purification composition, comprising: combining the purification composition and vapour to form a chute, adding the chute to the flue gas, adding the purification composition to the flue gas and over-pressuring the flue gas and adding more of the purification composition to the flue gas and under-pressuring the flue gas.

One aspect of the invention relates to a method comprising a single-stage conversion of an atmospheric pollutant, such as NO, NO.sub.2 and/or SOX in a first stream to one or more mineral acids and/or salts thereof by reacting with nonionic gas phase chlorine dioxide (ClO.sub.2.sup.0), wherein the reaction is carried out in the gas phase. Another aspect of the invention relates to a method comprising first adjusting the atmospheric pollutant concentrations in a first stream to a molar ratio of about 1:1, and then reacting with an aqueous metal hydroxide solution (MOH). Another aspect of the invention relates to an apparatus that can be used to carry out the methods disclosed herein. The methods disclosed herein are unexpectedly efficient and cost effective, and can be applied to a stream comprising high concentration and large volume of atmospheric pollutants.

One aspect of the invention relates to a method comprising a single-stage conversion of an atmospheric pollutant, such as NO, NO.sub.2 and/or SOX in a first stream to one or more mineral acids and/or salts thereof by reacting with nonionic gas phase chlorine dioxide (ClO.sub.2.sup.0), wherein the reaction is carried out in the gas phase. Another aspect of the invention relates to a method comprising first adjusting the atmospheric pollutant concentrations in a first stream to a molar ratio of about 1:1, and then reacting with an aqueous metal hydroxide solution (MOH). Another aspect of the invention relates to an apparatus that can be used to carry out the methods disclosed herein. The methods disclosed herein are unexpectedly efficient and cost effective, and can be applied to a stream comprising high concentration and large volume of atmospheric pollutants.

A purification composition, comprising 50-60% by weight of ash and 40-50% by weight of liquid. A method for producing the purification composition, comprising: measuring an amount of ash, combining the ash and liquid, wherein an amount of the liquid is based on the amount of the ash, adjusting a temperature of the combination of the ash and the liquid by adjusting a temperature of the liquid and mixing the ash and the liquid. A method for purifying a flue gas by the purification composition, comprising: combining the purification composition and vapour to form a chute, adding the chute to the flue gas, adding the purification composition to the flue gas and over-pressuring the flue gas and adding more of the purification composition to the flue gas and under-pressuring the flue gas.

The disclosure provides seven integrated methods for the chemical sequestration of carbon dioxide (CO.sub.2), nitric oxide (NO), nitrogen dioxide (NO.sub.2) (collectively NOR, where x=1, 2) and sulfur dioxide (SO.sub.2) using closed loop technology. The methods recycle process reagents and mass balance consumable reagents that can be made using electrochemical separation of sodium chloride (NaCl) or potassium chloride (KCl). The technology applies to marine and terrestrial exhaust gas sources for CO.sub.2, NOx and SO.sub.2. The integrated technology combines compatible and green processes that capture and/or convert CO.sub.2, NOx and SO.sub.2 into compounds that enhance the environment, many with commercial value.