An LED lighting fixture powered by a Metal-Organic Framework heat battery. The heat battery is formed of a canister, a MOF container comprised of a plurality of MOF tunnels, each MOF tunnel containing a powdered MOF material, a gate, and a plurality of thermoelectric devices. Below a certain adsorption activation temperature, the MOF material adsorbs a gas from the atmosphere. Above a certain desorption activation temperature, the MOF desorbs the gas. The heat from the adsorption is used to generate electrical current. The desorbed gas is captured to remove it from the atmosphere.

An LED lighting fixture powered by a Metal-Organic Framework heat battery. The heat battery is formed of a canister, a MOF container comprised of a plurality of MOF tunnels, each MOF tunnel containing a powdered MOF material, a gate, and a plurality of thermoelectric devices. Below a certain adsorption activation temperature, the MOF material adsorbs a gas from the atmosphere. Above a certain desorption activation temperature, the MOF desorbs the gas. The heat from the adsorption is used to generate electrical current. The desorbed gas is captured to remove it from the atmosphere.

An emitter apparatus is mounted on a marine structure powered by wind or marine hydrokinetic energy to disperse a carbon dioxide sorbent such as sodium hydroxide. The sorbent can be generated by reverse osmosis of seawater with electrolysis of the brine, or delivered from an external supply. Suitable marine structures include offshore wind turbines, marine hydrokinetic generators, offshore oil platforms, merchant vessels, and other fixed and mobile structures. Effective capture is made by dispersing a fine mist or fog of aqueous sorbent from nozzles with a particle size from a nozzle of less than 100 microns. The sorbent reacts with atmospheric carbon dioxide forming carbonates and bicarbonates, which drift and fall to the ocean surface, reducing surface acidity and capturing additional atmospheric carbon dioxide via absorption at the local ocean surface. The resulting carbonates sink to the ocean floor and are there sequestered.

A gas separation method includes supplying a mixed gas to a zeolite membrane complex and permeating a high permeability gas through the zeolite membrane complex to separate the high permeability gas from other gases. The mixed gas includes a high permeability gas and a trace gas that is lower in concentration than the high permeability gas. The trace gas contains an organic substance whose molar concentration in the mixed gas is higher than or equal to 1.0 mol %. The adsorption equilibrium constant of the organic substance on the zeolite membrane is less than 150 times the adsorption equilibrium constant of the high permeability gas.

A gas separation method includes supplying a mixed gas to a zeolite membrane complex and permeating a high permeability gas through the zeolite membrane complex to separate the high permeability gas from other gases. The mixed gas includes a high permeability gas and a trace gas that is lower in concentration than the high permeability gas. The trace gas contains an organic substance whose molar concentration in the mixed gas is higher than or equal to 1.0 mol %. The adsorption equilibrium constant of the organic substance on the zeolite membrane is less than 150 times the adsorption equilibrium constant of the high permeability gas.

The present invention relates to a systems and methods for improved removal of one or more species in a process stream, such as combustion product stream formed in a power production process. The systems and methods particularly can include contacting the process stream with an advanced oxidant and with water.

The present invention relates to a systems and methods for improved removal of one or more species in a process stream, such as combustion product stream formed in a power production process. The systems and methods particularly can include contacting the process stream with an advanced oxidant and with water.

A plant and a method for the production of hydrogen and bicarbonate. The plant includes a gasifier, a reformer, a direct contact exchanger and an apparatus for the production of bicarbonate. The plant is suitable for receiving fuel, oxygen, water, carbonate, brine at the inlet and for producing hydrogen, bicarbonate and calcium chloride at the outlet. The plant uses a self-cleaning direct contact heat exchanger to cool the syngas downstream of the reformer and to produce the superheated steam that feeds the gasifier: this heat exchanger allows the production of hydrogen at low costs and in modular plants.

A system may include a chamber with a main sub-chamber and a first porous membrane separating a first sub-chamber from the main sub-chamber. The system may include a fluid in the chamber and an input directing inflow into main sub-chamber proximate an entry end of the chamber. The system may include a first output permitting outflow from the first sub-chamber proximate an exit end of the chamber wherein a molecule entering at the entry end must traverse a length of the chamber to exit at the exit end.

An ink for three dimensional printing a ceramic material includes metal oxide nanoparticles and a polymer resin, where a concentration of the metal oxide nanoparticles is at least about 50 wt % of a total mass of the ink. A method of forming a porous ceramic material includes obtaining an ink, where the ink comprises a mixture of metal oxide nanoparticles and a polymer, forming a body from the ink, curing the formed body, heating the formed body for removing the polymer and for forming a porous ceramic material from the metal oxide nanoparticles. The forming the body includes an additive manufacturing process with the ink.