Disclosed in certain embodiments are sorbents for capturing heavy hydrocarbons via thermal swing adsorption processes.

A system for chemical vapor densification includes a reaction chamber having an inlet and outlet; a trap; a conduit fluidly coupled between the outlet of the reaction chamber and the trap; a cryogenic cooler fluidly coupled to the trap though a frustoconical conduit; a first exit path from the cryogenic cooler that vents hydrogen gas to an exhaust; and a second exit path from the cryogenic cooler that recirculates silane and hydrocarbon-rich gas back to the inlet of the reaction chamber—and a related method places a substrate in the reaction chamber; establishes a sub-atmospheric pressure inert gas atmosphere within the reaction chamber; densifies the substrate by inputting virgin gas into the reaction chamber; withdraws effluent gas from the reaction chamber; extracts silane and hydrocarbon-rich gas from the effluent gas; and recirculates the silane and hydrocarbon-rich gas back to the reaction chamber.

The present invention provides a novel method for treating soil-contaminated water, the method using a photocatalytic material capable of efficiently removing, by light irradiation alone, volatile organic compounds and heavy metals that give rise to soil contamination. The present invention provides a method for treating soil-contaminated water that detoxifies volatile organic compounds contained in soil-contaminated water using a photocatalytic material, the method being characterized by including the steps of (1) subjecting the soil-contaminated water to a gas-liquid separation to obtain a gas phase, and (2) decomposing the volatile organic compounds contained in the gas phase obtained in step (1) using the photocatalytic material. The present invention further provides a method for treating soil-contaminated water using a photocatalytic material to remove heavy metals contained in the soil-contaminated water, the method being characterized, by including the steps of (1) subjecting the soil-contaminated water to a gas-liquid separation to obtain a liquid phase, and (2) removing the heavy metals contained in the liquid phase obtained in step (1) using the photocatalytic material.

A process for treating effluent streams in a naphtha complex is described. One or more of the sour water stripping unit for the NHT sour water from the NHT, the amine treatment unit and the caustic treatment unit for the NHT stripper off-gas, the caustic scrubber unit or other chloride treatment unit for the off-gas from the C.sub.5-C.sub.6 isomerization zone and the C.sub.4 isomerization zone, and the caustic scrubber unit or other chloride treatment unit for the regenerator off-gas are replaced with a thermal oxidation system.

A process for treating effluent streams in a naphtha complex is described. One or more of the sour water stripping unit for the NHT sour water from the NHT, the amine treatment unit and the caustic treatment unit for the NHT stripper off-gas, the caustic scrubber unit or other chloride treatment unit for the off-gas from the C.sub.5-C.sub.6 isomerization zone and the C.sub.4 isomerization zone, and the caustic scrubber unit or other chloride treatment unit for the regenerator off-gas are replaced with a thermal oxidation system.

An integrated autonomous air purification device for taking in polluted air, carrying it through the inside of the purification device where it passes through a set of filtering elements (1) that trap the dust particles contained in the air; ultraviolet-light lamps (2) that transform NO.sub.X and CO gases in the air into harmless compounds; an activated carbon filter (4) that traps and eliminates the volatile organic compounds and inorganic acidic gases; second filtering elements (5) that carry out a second filtering; and an extraction hood (6) configured to direct the air coming out of the second filtering elements (5) to at least one nozzle (7) that expels the air to the outside of the purification device.

A device for treating a gas laden with pollutants, includes at least one adsorption module for adsorbing the pollutants, which is utilized in an adsorption apparatus. The adsorption module includes at least one electrically conductive layer of an activated carbon fiber mat, an electric current circuit for heating the activated carbon fiber mat for the desorption of the adsorbed pollutants, and distributing conduit which is routed into the center of the adsorption module and has outlet openings for a flush gas for inertizing and rinsing the activated carbon fiber mat.

A device for treating a gas laden with pollutants, includes at least one adsorption module for adsorbing the pollutants, which is utilized in an adsorption apparatus. The adsorption module includes at least one electrically conductive layer of an activated carbon fiber mat, an electric current circuit for heating the activated carbon fiber mat for the desorption of the adsorbed pollutants, and distributing conduit which is routed into the center of the adsorption module and has outlet openings for a flush gas for inertizing and rinsing the activated carbon fiber mat.

Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.

Disclosed are systems and methods which provide a process stream comprising a gaseous component, capture the gaseous component from the process stream by an ionic liquid solvent of a separator, and recover a captured gaseous component from the ionic liquid solvent in a regenerator. A second gaseous component from the process stream may be captured by the ionic liquid solvent of the separator, and the second gaseous component may be recovered from the ionic liquid solvent in the regenerator. Alternatively, the second gaseous component from the process stream may be uncaptured by the ionic liquid solvent, and the uncaptured second gaseous component may be recovered from a membrane unit.