A method for forming an amine-functionalized solid CO.sub.2 sorbent for carbon capture may include providing a support material and applying at least one cycle of molecular layer deposition (MLD) with an amine precursor onto the surface of the support material. An amine layer formed on the support material contains amine groups/amine-containing ligands to adsorb CO.sub.2 onto the support material in a low temperature operating window for adsorption and desorption without the loss of active sites.

Disclosed are an activated carbon adsorption tower and a gas purification device. An activated carbon adsorption tower comprises an adsorption tower body (1), a gas inlet (2) and a gas outlet (3) arranged on the adsorption tower body (1); the adsorption tower body (1) is provided with an activated carbon passage (11), a swash plate (12) and a gas passage in communication with the gas inlet (2) and the gas outlet (3); the gas passage is separated by the swash plate (12) into a U shape or serpentine shape, making the gas passage pass through the same activated carbon passage (11) from the opposite direction at least once; and the activated carbon passage (11) is provided with flowing activated carbon inside and gas holes on the passage wall for communicating with the gas passages on both sides.

Disclosed are an activated carbon adsorption tower and a gas purification device. An activated carbon adsorption tower comprises an adsorption tower body (1), a gas inlet (2) and a gas outlet (3) arranged on the adsorption tower body (1); the adsorption tower body (1) is provided with an activated carbon passage (11), a swash plate (12) and a gas passage in communication with the gas inlet (2) and the gas outlet (3); the gas passage is separated by the swash plate (12) into a U shape or serpentine shape, making the gas passage pass through the same activated carbon passage (11) from the opposite direction at least once; and the activated carbon passage (11) is provided with flowing activated carbon inside and gas holes on the passage wall for communicating with the gas passages on both sides.

One or more embodiments relates to method for generating CHEFS having the steps of generating the CHEFS from a dope. One or more embodiments relates to a method for generating CHEFS having amine functional groups having the steps of generating a dope containing a BIAS with amine groups, at least one polymer, and at least one solvent; and forming CHEFS from the dope, wherein the generated CHEFS have no more than 30% amine loss compared to the BIAS.

One or more embodiments relates to method for generating CHEFS having the steps of generating the CHEFS from a dope. One or more embodiments relates to a method for generating CHEFS having amine functional groups having the steps of generating a dope containing a BIAS with amine groups, at least one polymer, and at least one solvent; and forming CHEFS from the dope, wherein the generated CHEFS have no more than 30% amine loss compared to the BIAS.

A preparation method for the carrier, includes: 1) mixing hydrated alumina with an organic acid to obtain a mixture A; and 2) adding tetraalkylsiloxane to the mixture A, thus obtaining a mixture B; stirring the mixture B in a closed condition; spraying atomized water into the mixture B; and stirring to yield the carrier.

A plurality of carbonation plots are positioned in communication with atmospheric carbon dioxide to facilitate sequestration thereof via ambient weathering. The carbonation plots include a composition rich in metal oxides, which are positioned within the environment, such as on non-arable land, and exposed to the environment to react with carbon dioxide in the air and form metal carbonates. After about one year of exposure, the composition is recollected and calcined to produce a carbon dioxide stream and replenish the metal oxides, which can be redistributed in the carbonation plots to sequester additional carbon dioxide. The systems and methods of the present disclosure enable capture and redistribution of carbon dioxide for industrial-scale uses for very abundant quarry minerals and enable large-scale low-cost carbon capture projects for municipalities or corporations. CO.sub.2 removal from air via these methods and systems have a similar or lower cost than CO.sub.2 removal using DAC with synthetic sorbents or solvents.

A plurality of carbonation plots are positioned in communication with atmospheric carbon dioxide to facilitate sequestration thereof via ambient weathering. The carbonation plots include a composition rich in metal oxides, which are positioned within the environment, such as on non-arable land, and exposed to the environment to react with carbon dioxide in the air and form metal carbonates. After about one year of exposure, the composition is recollected and calcined to produce a carbon dioxide stream and replenish the metal oxides, which can be redistributed in the carbonation plots to sequester additional carbon dioxide. The systems and methods of the present disclosure enable capture and redistribution of carbon dioxide for industrial-scale uses for very abundant quarry minerals and enable large-scale low-cost carbon capture projects for municipalities or corporations. CO.sub.2 removal from air via these methods and systems have a similar or lower cost than CO.sub.2 removal using DAC with synthetic sorbents or solvents.

A pyrazole metal complex for absorption of carbon dioxide, a method for preparing the pyrazole metal complex, and a method for absorbing carbon dioxide are provided; wherein the product produced by reacting pyrazole metal complex and carbon dioxide may be transformed into several economically valuable compounds.

A pyrazole metal complex for absorption of carbon dioxide, a method for preparing the pyrazole metal complex, and a method for absorbing carbon dioxide are provided; wherein the product produced by reacting pyrazole metal complex and carbon dioxide may be transformed into several economically valuable compounds.