In various aspects, systems and methods are provided for integrating molten carbonate fuel cells with a fired heater for production of electrical power while also reducing or minimizing the amount of CO.sub.2 present in the flue gas generated by the fired heater. The molten carbonate fuel cells can be integrated for use with fired heater so that at least a portion of the flue gas from fired heater flows through cathodes of the fuel cells and at least a portion of the cathode exhaust is returned to a convection section of the fired heater.

A capture device for capturing a target gas from a gas flow is disclosed that can be continuously used without requiring consumption of target gas binding salts. To this end, the device is arranged to generate separate acidic and alkaline streams of fluid by electrolyzing water, binding the target gas to the hydroxide ions in the alkaline fluid stream or the hydronium ions in the acidic stream, and recombining the generated streams to release the bound target gas and regenerating part of the electrolyzed water for further electrolysis. Such a capture device may for instance be used in a gas purification system, e.g. an air purification system for controlling target gas levels in a confined space such as a vehicle cabin, domestic dwelling or office space, a target gas generation system or a target gas enrichment system, e.g. for creating target gas-rich air for horticultural purposes. A method for capturing target gas from a gas flow and optionally utilizing the captured target gas is also disclosed.

Techniques for removing sulfur compounds from a sulfur-containing gas stream can include contacting the gas with an absorption solution comprising a metal cation capable of reacting with the sulfur compound to form a metal sulphide precipitate and/or a metal mercaptide precipitate. In addition, the treatment can include controlling a concentration of the precipitates below a threshold to maintain rheological properties; subjecting the precipitate-enriched solution to vitalization; subjecting the precipitate-enriched solution to regeneration including oxidation; and/or other features to enhance the sulfur removal operations.

A carbon dioxide capturing apparatus and process uses a self-generating power means that uses carbon dioxide in combustion exhaust gas through the convergence of a carbon dioxide absorption tower. The capturing apparatus and process also relies on ionic generator associated technology using a concentration difference between seawater and freshwater. The capturing apparatus and process result in increased production efficiency for electric energy and reduced costs for a carbon dioxide capturing process by increasing a concentration difference using an absorbent liquid for absorbing carbon dioxide and, at the same time, electricity is obtained through carbon dioxide which is a greenhouse gas.

A method and device for the desulphurisation of a hydrogen sulphide-containing gas flow, in particular for combustion in a gas turbine, wherein the gas flow is brought into contact with a washing agent containing a catalytically active component for the absorption of the hydrogen sulphide and forming elementary sulphur, wherein the catalytically active component is reduced in the formation of the elementary sulphur, wherein the washing medium containing the reduced catalytically active component is supplied to a regeneration stage, in which the reduced catalytically active component is converted back via oxidation with an oxygen-containing gas supplied to the regeneration stage, and wherein the oxygen-containing gas is supplied to the regeneration stage from a compressor of a gas turbine. Air from the compressor of a gas turbine is used for purifying a washing medium used for the desulphurisation of a gas flow.

An object of the present invention is to provide a carbon dioxide treatment apparatus, a carbon dioxide treatment method, and a method of producing carbon compounds, which have high energy efficiency from carbon dioxide capture to reduction and a high carbon dioxide loss reduction effect. In a carbon dioxide treatment apparatus 100 including: a capturing device 1 that captures carbon dioxide; and an electrochemical reaction device 2 that electrochemically reduces carbon dioxide, an absorption unit 12 of the capturing device 1 brings an electrolytic solution A composed of a strong alkaline aqueous solution and carbon dioxide gas into contact with each other to dissolve carbon dioxide in the electrolytic solution A and absorb the carbon dioxide, supplies an electrolytic solution B that has absorbed carbon dioxide between the cathode and the anode of the electrochemical reaction device 2, and electrochemically reduces the dissolved carbon dioxide in the electrolytic solution at the cathode.

A synthetic fuel production system and related techniques are disclosed. In accordance with some embodiments, the disclosed system may be configured to produce a liquid fuel using carbon dioxide extracted from the air and hydrogen generated from aqueous solutions by electrochemical means (e.g., water electrolysis). In production of the fuel, the disclosed system may be configured, in accordance with some embodiments, to react the carbon dioxide and hydrogen, for example, to form methanol. The disclosed system also may be configured, in accordance with some embodiments, to utilize one or more subsequent reaction steps to produce a given targeted set of hydrocarbons and partially oxidized hydrocarbons. For example, the disclosed system may be used to produce any one (or combination) of: ethanol; dimethyl ether; formic acid; formaldehyde; alkanes of various chain length; olefines; aliphatic and aromatic carbon compounds; and mixtures thereof, such as gasoline fuels, diesel fuels, and jet fuels.

The present disclosure relates to power plants. The teachings thereof may be embodied in power plants which extract and store carbon dioxide from flue gas generated in the power plant, and in methods for operating a power plant of this kind. For example, a method for operating a power plant may include: generating electrical energy from a combustion process, extracting carbon dioxide from a flue gas generated during the combustion process; storing the extracted carbon dioxide; acquiring current electricity price data; comparing the current electricity price data with an electricity price threshold; and if the electricity price falls below the electricity price threshold, operating an electrolysis device to convert stored carbon dioxide into other substances.

An integrated system and method for conversion of carbon oxides to carbon containing products are disclosed. Pre-purification of a carbon oxide gas by electrodialysis, and subsequent electrochemical reduction of the purified gas with a carbon oxide electrolyzer equipped with a polymer electrolyte membrane yields carbon containing products.

A system has an alkaline capture stream as an input, an alkaline depleted stream as an output, a carbon dioxide removal unit operation having a return stream as an output, and a series of electrolyzers, each electrolyzer to receive a CO.sub.2-rich input stream and produce an acidified output stream that is more acidic than the CO.sub.2-rich input stream, and to receive a return stream and produce a basified output stream that is more alkaline than the input return stream. A method of removing carbon dioxide from an atmosphere and generating hydrogen includes capturing carbon dioxide from an atmosphere in an alkaline capture solution, sending the alkaline solution as a CO.sub.2-rich input solution to a series of electrolyzers in a CO.sub.2-rich path, removing carbon dioxide from the acidified CO.sub.2-rich solution at a removal unit to produce a CO.sub.2-poor solution, sending the CO.sub.2-poor solution to the series of electrolyzers in a return path, and returning the return solution to the alkaline capture stream. An electrolyzer is also discussed.