The present invention belongs to the membrane separation area, which provides an MXene material based composite nanofiltration membrane and corresponding method. The mentioned membrane is flat membrane, which has supporting layer and functional separation layer and supporting layer is under the functional separation layer. The functional separation layer is a kind of dense ultra-thin layer, no more than 50 ?m, prepared with MXene and crosslinking agent. This invention is about a flat composite nanofiltration membrane which has excellent separation performance, thermal resistance and chemical stability because of the novel MXene in the functional separation layer. It can be used in the treatment of the waste water with heavy metal ions, organic solvents or other highly oxidizing solution.

Nanofiltration of aqueous solutions or other water-based fluids in various applications, such as desalination, dialysis, seawater purification, for example, may be enhanced through precisely controlling a filtration cutoff within graphene oxide nanofilters. By initially compressing and constraining the stacked thickness of multiple graphene oxide layers deposited between porous substrates, the interlayer gap size, and thus, the filtration cutoff may be adjusted and optimized.

Described herein is a graphene material based membrane that provides selective resistance for solutes or gas while providing water permeability. A selectively permeable membrane comprising graphene oxide, reduced graphene oxide, and also functionalized or crosslinked between the graphene, that provides enhanced salt separation from water or gas permeability resistance, methods for making such membranes, and methods of using the membranes for dehydrating or removing solutes from water are also described.

A filter membrane includes carbon nanotubes and carbon nitride nanoparticles. Inter-particle atomic interactions between the carbon nanotubes and the carbon nitride nanoparticles bind the carbon nanotubes and the carbon nitride nanoparticles together. A filter cartridge includes such a filter membrane disposed within an outer housing between a fluid inlet and a fluid outlet such that fluid passing through the outer housing between the fluid inlet and the fluid outlet passes through the filter membrane. Such filter membranes may be formed by dispersing carbon nanotubes and carbon nitride nanoparticles in a liquid to form a suspension, and passing the suspension through a filter to deposit the nanotubes and nanoparticles on the filter. Liquid may be filtered by causing the liquid to pass through such a filter membrane.

Nanofiltration of aqueous solutions or other water-based fluids in various applications, such as desalination, dialysis, seawater purification, for example, may be enhanced through precisely controlling a filtration cutoff within graphene oxide nanofilters. By initially compressing and constraining the stacked thickness of multiple graphene oxide layers deposited between porous substrates, the interlayer gap size, and thus, the filtration cutoff may be adjusted and optimized.

A method for increasing the thickness of a sheet of CNTs (146, 147, 246, 346), comprising: providing a wet sheet of CNTs, wherein the sheet of CNTs is either a continuous sheet of CNTs or a portion of sheet of CNTs, wherein the wet sheet of CNTs is the result of applying a process for manufacturing a sheet of CNTs; separating the wet sheet of CNTs from any filter or support element; drying the wet sheet of CNTs (146, 147, 246, 346) by applying heat (15, 25, 35) from a heat source (12, 22, 32). A method for manufacturing a continuous sheet of CNTs, comprising: in a container (41) filled with a liquid solution (42) comprising CNTs at certain concentration, submerging a vacuum tank (43) having a lower surface forming a grillage; moving an elongated filtering membrane (44) along the lower surface of the vacuum tank (43) while vacuum is applied on the elongated filtering membrane (44) in such a way that in the surface of the filtering membrane (44) opposed to the surface in contact with the lower surface of the vacuum tank (43) CNTs are deposited forming a continuous sheet of CNTs (45) of constant thickness; taking the filtering membrane (44) together with the continuous sheet of CNTs (45) out of the container (41); washing the continuous sheet of CNTs (55) disposed on the filtering membrane or on a support element (54) in a second container (51) filled with cleaning solution (52); taking the continuous sheet of CNTs (55) together with the filtering membrane or the support element (54) out of the second container (51); separating the continuous sheet of CNTs (55) from the filtering membrane or the support element (54); drying the continuous sheet of CNTs (55) by applying the method for increasing the thickness of a sheet of CNTs.

The present invention relates to a membrane and a method for manufacturing a membrane for filtering a fluid, said membrane comprising: a substrate having a three-dimensional structure and consisting of an one-piece ceramic porous body; and at least one separating filtering layer having a porosity that is lower than that of the substrate, in which the three-dimensional structure of the substrate is produced by forming elemental layers that are stacked and connected in series with one another, by repeating steps: a) depositing a continuous bed of powder at least partially consisting of a powder intended for forming the ceramic porous body; b) locally consolidating, part of the deposited material such as to create the elemental layer, and simultaneously linking the elemental layer thus formed with the preceding layer such as to gradually grow the desired three-dimensional shape.

The present disclosure provides compositions comprising anisotropic chain-like silica nanoparticles functionalized with hydrophilic groups. The anisotropic chain-like silica nanoparticles comprise linked arrays of charged silica nanoparticles, each linked array have at least one linear dimension of from about 100 nm to about 1200 nm and the anisotropic chain-like silica nanoparticles each in have a diameter of from about 10 nm to about 500 nm. These compositions are superoleophobic in the presence of water, e.g., when submerged in water. Also provided are layered coatings comprising these compositions, substrates comprising the layered coatings, articles comprising the layered coatings, methods of filtering a mixture of water and an oil using the compositions described herein, and methods of preparing a superoleophobic coating on a substrate using the compositions described herein.

The present disclosure provides an activated carbon-based all-carbon membrane (ACM), which is formed by using activated carbon as a base material and graphene as a crosslinking agent for connection, and can stably exist independent of a substrate. The membrane surface pore structure can be adjusted by the addition proportion of graphene, and the membrane surface pore size can be adjusted from micron-scale to nano-scale. The preparation method of ACM comprises uniformly mixing and then filtering an activated carbon dispersion and a graphene dispersion, then the graphene and the activated carbon are assembled on the membrane filter substrate. The membrane can be used in the fields such as water and air purification, chemical catalysis, and energy reservation.

An apparatus for fabricating a graphene membrane includes a first section having a first fluid chamber for housing a suspension of graphene platelets in a fluid. A second section is positionable adjacent the first section. The second section has a second fluid chamber and a porous support housed in the second fluid chamber for supporting a porous substrate. When the first section is positioned adjacent to the second section and the porous substrate is supported by the porous support, the first fluid chamber and the second fluid chamber are in fluid communication via the porous substrate. The apparatus further includes a pressurizer for creating a pressure differential between the first fluid chamber and the second fluid chamber and thereby forcing the fluid through the porous substrate and into the second fluid chamber and lodging the graphene platelets in the pores of the porous substrate.